Magnetic recording medium substrate using thermoplastic allyloxymethylstyrene resin, magnetic recording medium using the substrate, and method of manufacturing the magnetic recording medium
View Patent ↗An injection molded thermoplastic magnetic recording substrate a medium formed therewith, and a method thereof is composed of a thermoplastic or allyloxymethylstyrene type resin.
1. An injection molded plastic magnetic recording medium substrate comprising a thermoplastic allyloxymethylstyrene resin having a cyclization rate of at least 90% and having either or both of a structural unit represented by general formula A and a structural unit represented by general formula B,
where R is a group selected from hydrogen, alkyl groups, cycloalkyl groups, aryl groups and aromatic heterocyclic groups, and m and n each represent 0 or an integer of 1 or higher, with the proviso that m and n are not both 0.
2. The injection molded plastic magnetic recording medium substrate according to claim 1 , wherein the thermoplastic allyloxymethylstyrene resin includes a thermoplastic phenylallyloxymethylstyrene resin having either or both of a structural unit represented by general formula 1 and a structural unit represented by general formula 2,
where m and n each represent 0 or an integer of 1 or higher, with the proviso that m and n are not both 0.
3. The magnetic recording medium substrate according to claim 2 , wherein the thermoplastic phenylallyloxymethylstyrene resin has a glass transition temperature (Tg) in a range of 180° C. to 270° C., a thermal decomposition point of at least 360° C., and a moisture content of not more than 0.01%.
4. The magnetic recording medium substrate according to claim 3 , wherein a substrate flatness shape change after exposure for 500 hours to a high-temperature high-humidity environment of 80° C. and 80% RH is not more than 10%.
5. The magnetic recording medium substrate according to claim 2 , wherein a flatness in a substrate surface radial direction is not more than 12 μm, a straightness is not more than 1.2 μm, a waviness (Wa) is not more than 50 nm, and an average roughness (Ra) is not more than 0.5 nm.
6. The magnetic recording medium substrate according to claim 2 , wherein a substrate flatness shape change after exposure for 500 hours to a high-temperature high-humidity environment of 80° C. and 80% RH is not more than 10%.
7. A magnetic recording medium comprising the substrate according to claim 2 and at least a magnetic layer, a protective layer, and a lubricant layer formed on the substrate.
8. The magnetic recording medium according to claim 7 , wherein a flatness in a substrate surface radial direction is not more than 12 μm, a straightness is not more than 1.2 μm, a waviness (Wa) is not more than 50 nm, and an average roughness (Ra) is not more than 0.5 nm.
9. The magnetic recording medium according to claim 7 , wherein a substrate flatness shape change after exposure for 500 hours to a high-temperature high-humidity environment of 80° C. and 80% RH is not more than 10%.
10. A method of manufacturing a magnetic recording medium comprising the steps of:
forming the injection molded plastic magnetic recording medium substrate according to claim 2 by thoroughly drying the thermoplastic phenylallyloxymethylstyrene resin and then injection molding the thermoplastic phenylallyloxymethylstyrene resin; and
forming at least a magnetic layer, a protective layer, and a lubricant layer in this order on the substrate.
11. The magnetic recoding medium substrate according to claim 2 , wherein the thermoplastic phenylallyloxymethylstyrene resin has a thermal decomposition point of at least 360° C.
12. The magnetic recording medium substrate according to claim 2 , wherein the thermoplastic phenylallyloxymethylstyrene resin has a glass transition temperature (Tg) in a range of 180° C. to 270° C.
13. The magnetic recording medium substrate according to claim 1 , wherein a flatness in a substrate surface radial direction is not more than 12 μm, a straightness is not more than 1.2 μm, a waviness (Wa) is not more than 50 nm, and an average roughness (Ra) is not more than 0.5 nm.
14. The magnetic recording medium according to claim 13 , wherein a substrate flatness shape change after being left for 500 hours in a high-temperature high-humidity environment of 80° C. and 80% RH is not more than 10%.
15. A magnetic recording medium comprising the substrate according to claim 1 and at least a magnetic layer, a protective layer, and a lubricant layer formed on the substrate.
16. The magnetic recording medium according to claim 15 , wherein a flatness in a substrate surface radial direction is not more than 12 μm, a straightness is not more than 1.2 μm, a waviness (Wa) is not more than 50 nm, and an average roughness (Ra) is not more than 0.5 nm.
17. The magnetic recording medium according to claim 15 , wherein a substrate flatness shape change after exposure for 500 hours to a high-temperature high-humidity environment of 80° C. and 80% RH is not more than 10%.
18. A method of manufacturing a magnetic recording medium comprising the steps of:
forming the injection molded plastic magnetic recording medium substrate according to claim 1 by thoroughly drying the thermoplastic allyloxymethylstyrene type resin and then injection molding the thermoplastic allyloxymethylstyrene type resin; and
forming at least a magnetic layer a protective layer, and a lubricant layer in this order on the substrate.
19. An injection molded plastic magnetic recording medium substrate comprising a thermoplastic allyloxymethylstyrene resin having a cyclization rate of at least 80% and having either or both of a structural unit represented by general formula 3 and a structural unit represented by general formula 4,
where m and n each represent 0 or an integer of 1 or higher, with the proviso that m and n are not both 0.
20. The magnetic recording medium substrate according to claim 19 , wherein the thermoplastic allyloxymethylstyrene resin has a glass transition temperature (Tg) of at least 100° C., a thermal decomposition point of at least 350° C., and a moisture content of not more than 0.01%.
21. The magnetic recording medium substrate according to claim 19 , wherein a flatness in a substrate surface radial direction is not more than 12 μm, a straightness is not more than 1.2 μm, a waviness (Wa) is not more than 50 nm, and an average roughness (Ra) is not more than 0.5 nm.
22. A magnetic recording medium comprising the substrate according to claim 19 and at least a magnetic layer, a protective layer, and a lubricant layer formed on the substrate.
23. The magnetic recording medium according to claim 22 , wherein a flatness in a substrate surface radial direction is not more than 12 μm, a straightness is not more than 1.2 μm, a waviness (Wa) is not more than 50 nm, and an average roughness (Ra) is not more than 0.5 nm.
24. A method of manufacturing a magnetic recording medium comprising the steps of:
forming the injection molded plastic magnetic recording medium substrate according to claim 19 by thoroughly drying the thermoplastic allyloxymethylstyrene resin and then injection molding the thermoplastic allyloxymethylstyrene resin; and
forming at least a magnetic layer, a protective layer, and a lubricant layer in this order on the substrate.
25. The magnetic recording medium substrate according to claim 19 , wherein the thermoplastic allyloxymethylstyrene resin has a thermal decomposition point of at least 350° C.
26. The magnetic recording medium substrate according to claim 19 , wherein the thermoplastic allyloxymethylstyrene resin has a glass transition temperature (Tg) of at least 100° C.