Cycloolefin copolymer heat sealable films
View Patent ↗The present invention relates to a heat-sealable film which consists essentially of a cycloolefin copolymer (COC), the glass transition temperature (Tg) of the COC being within the range from 30 to 55° C. The film or sheet has excellent low temperature heat-sealing properties and processing characteristics. The film may be free standing or laminated to other thermoplastic polymer film or films at low temperatures. Alternatively, a COC polymer with Tg in the range 30 to 55° C. may be coextruded with other thermoplastic polymer or polymer films in a coextrusion process to form a heat sealable film. The film of the invention is suitable for packing foods or other consumable items.
1. A heat sealable film consisting essentially of a film forming norbornene/-ethylene copolymer having a Tg of from about 30C to about 55C, a film of the film forming copolymer exhibiting a hot tack strength of greater than 10N when tested at a heat seal temperature below about 75° C. at a seal pressure of 44 psi, a seal time of 1 second, a cooling time of 0.1 second, a film sample width of 1 inch and a film sample thickness of 2 mil, wherein the peel speed is 200 mm/s, wherein further a film of the film forming copolymer exhibits a hot tack strength of greater than about 5N at all heat seal temperatures between about 75° C. and 150° C. at a seal pressure of 44 psi, a seal time of 1 second, a cooling time of 0.1 second, a film sample width of 1 inch and a film sample thickness of 2 mil, wherein the peel speed is 200 mm/s.
2. A heat sealable film consisting essentially of a film forming norbornene/-ethylene copolymer having a Tg of from about 30° C. to about 55° C., a film of the film forming copolymer exhibiting an ultimate seal strength of greater than 10N when tested at a heat seal temperature below about 90° C. at a seal pressure of 44 psi, a seal time of 1 second, a cooling time of 30 seconds, a film sample width of 1 inch and a film sample thickness of 2 mil, wherein the peel speed is 200 mm/s.
3. The film according to claim 2 , wherein the film exhibits a maximum hot tack strength value at a heat sealing temperature below about 75° C. and exhibits a hot tack strength value of at least about 10% of that maximum value at heat sealing temperatures of from about 90° C. to about 150° C.
4. The film according to claim 2 , wherein the film exhibits a maximum hot tack strength value at a heat sealing temperature below about 75° C. and exhibits a hot tack strength value of at least about 20% of that maximum value at heat sealing temperatures of from about 90° C. to about 150° C.
5. The film according to claim 2 , wherein the film exhibits a maximum hot tack strength value at a heat sealing temperature below about 75° C. and exhibits a hot tack strength value of at least about 30% of that maximum value at heat sealing temperatures of from about 90° C. to about 150° C.
6. The film according to claim 2 , wherein the film exhibits a maximum ultimate strength value at a heat sealing temperature below about 90° C. and exhibits an ultimate strength value of at least bout 25% of that maximum value at heat sealing temperatures of from about 100° C. to about 150° C.
7. The film according to claim 2 , wherein the film exhibits a maximum ultimate strength value at a heat sealing temperature below about 90° C. and exhibits an ultimate strength value of at least bout 50% of that maximum value at heat sealing temperatures of from about 100° C. to about 150° C.
8. The heat sealable film according to claim 2 , wherein a film of the film forming copolymer exhibits a hot tack strength of greater than 10N when tested at a heat seal temperature below about 75° C. at a seal pressure of 44 psi, a seal time of 1 second, a cooling time of 0.1 second, a film sample width of 1 inch and a film sample thickness of 2 mil, wherein the peel speed is 200 mm/s.
9. The heat sealable film according to claim 2 , wherein the norbornene is present in the copolymer in an amount of from about 24 to about 30 mole percent and wherein the ethylene is present in an amount of from about 76 to about 70 mole percent.
10. The heat sealable film of claim 2 , additionally comprising at least one layer comprising a thermoplastic polymer laminated to the at least one layer consisting essentially of the norbornene/ethylene copolymer.
11. The heat selable film of claim 10 , wherein the at least one thermoplastic polymer layer and the at least one layer consisting essentially of norbornene/ethylene copolymer are formed by coextrusion.
12. The film of claim 11 , wherein the coextrusion is performed using a flat-film die.
13. The film of claim 11 , wherein the coextrusion is performed by a blown film process.
14. The film of claim 10 , wherein the at least one thermoplastic polymer layer and the at least one layer consisting essentially of norbornene/ethylene copolymer are laminated by adhesive bonding.
15. The film of claim 10 , wherein the at least one thermoplastic polymer is selected from the group consisting of polyester, polycarbonate, polyolefin, polyacrylate, polyestercarbonate, polyamide, polyketone, polyether, polyvinyl, cyclic olefin homopolymer and cyclic olefin copolymer, wherein the at least one thermoplastic layer has a Tg greater than that of the at least one layer consisting essentially of norbornene/ethylene copolymer.
16. The film of claim 15 , wherein the thermoplastic is a polyester, polypropylene, polyethylene or nylon.
17. The film of claim 16 , wherein the thermoplastic is selected from the group consisting of polyethylene terephthalate and polybutylene terephthalate.
18. The film according to claim 15 , wherein the at least one thermoplastic polymer is a norbornene/ethylene copolymer having a Tg of from about 30° C. to about 55° C.
19. The film of claim 10 , wherein the laminate is further heat sealed to another layer via the heat sealable norbornene/ethylene polymer layer.
20. A heat sealed package comprising a film of claim 10 .
21. The package according to claim 20 , wherein the heat seal is effected at a sealing temperature of from about 50 to about 80° C.
22. A heat sealable film consisting essentially of a film forming norbornene/-ethylene copolymer having a Tg of from about 30° C. to about 55° C., a film of the film forming copolymer exhibiting an ultimate seal strength of greater than 10N when tested at a heat seal temperature below about 90° C. at a seal pressure of 44 psi, a seal time of 1 second, a cooling time of 30 seconds, a film sample width of 1 inch and a film sample thickness of 2 mil, wherein the peel speed is 200 mm/s, wherein further a film of the film forming copolymer exhibits an ultimate seal strength of greater than about 20N at all heat seal temperatures between about 90° C. and 150° C. at a seal pressure of 44 psi, a seal time of 1 second, a cooling time of 0.1 second, a film sample width of 1 inch and a film sample thickness of 2 mil, wherein the peel speed is 200 mm/s.