Solubility additive for ink compositions
View Patent ↗An additive for improving the solubility of dyes in a dye composition is disclosed. The additive is a zwitterion that has a polarity greater than the polarity of a solvent in which the dye is dispersed or solubilized. In one embodiment, the additive comprises an amino acid or a derivative of an amino acid. Dye compositions formulated according to the present invention are particularly well suited for use in ink-jet printers.
1. An ink composition comprising:
a dye;
a solvent for the dye; and
an additive comprising a sulfonic acid analog of an amino acid, the additive having a polarity greater than the polarity of the solvent, the additive present in an amount that inhibits the dye from coalescing in the solvent thereby increasing the solubility of the dye in the solvent.
2. An ink composition as defined in claim 1 , wherein the amino acid comprises glycine, lysine, taurine, beta-alanine, betaine, or mixtures thereof.
3. An ink composition as defined in claim 1 , wherein the sulfonic acid analog of an amino acid is a zwitterion.
4. An ink composition as defined in claim 1 , wherein the additive is present in the ink composition at a mole fraction of from about 0.004 to about 0.04.
5. An ink composition as defined in claim 1 , wherein the additive is present in the ink composition at a mole fraction of from about 0.01 to about 0.02.
6. An ink composition as defined in claim 1 , wherein the solvent comprises water.
7. An ink composition as defined in claim 1 , wherein the additive has a dipole moment greater than about 4 debye.
8. An ink composition as defined in claim 1 , wherein the additive has a dipole moment greater than about 10 debye.
9. An ink composition as defined in claim 1 , wherein the dye comprises a sulfonated dye.
10. An ink composition as defined in claim 1 , wherein the dye comprises an acid dye.
11. An ink composition as defined in claim 1 , wherein the ink composition further comprises an organic cosolvent and a surfactant.
12. An ink composition as defined in claim 1 , wherein the dielectric constant of the composition increases by at least 20% due to the presence of the additive.
13. An ink composition as defined in claim 1 , wherein the sulfonic acid analog of an amino acid has a molecular weight of less than about 500.
14. An ink composition comprising:
a dye comprising a sulfonated dye or an acid dye;
a solvent for the dye, the solvent comprising water for forming an aqueous medium; and
an additive comprising a sulfonic acid analog of an amino acid, the amino acid or the derivative of the amino acid being a zwitterion, the additive having a polarity greater than the polarity of water, the additive being present in a concentration that prevents the dye from coalescing in the solvent thereby increasing the solubility of the dye in the solvent.
15. An ink composition as defined in claim 14 , wherein the additive is present in the ink composition at a mole fraction greater than about 0.004.
16. An ink composition as defined in claim 14 , wherein the additive has a dipole moment greater than about 4 debye.
17. An ink composition as defined in claim 14 , wherein the additive has a dipole moment greater than about 10 debye.
18. An ink composition as defined in claim 14 , wherein the amino acid comprises glycine, lysine, taurine, beta-alanine, betaine, or mixtures thereof.
19. An ink composition as defined in claim 14 , wherein the ink composition further comprises an organic cosolvent and a surfactant.
20. An ink composition as defined in claim 14 , wherein the dye comprises a sulfonated dye.
21. An ink composition as defined in claim 14 , wherein the dielectric constant of the composition increases by at least 20% due to the presence of the additive.
22. An ink composition as defined in claim 14 , wherein the sulfonic acid analog of an amino acid has a molecular weight of less than about 500.
23. A process for printing on a substrate comprising:
ink-jet printing an ink composition onto a substrate, the ink composition comprising:
(a) a dye comprising a sulfonated dye or an acid dye;
(b) a solvent for the dye, the solvent comprising water for forming an aqueous medium; and
(c) an additive comprising a sulfonic acid analog of an amino acid, the amino acid or the derivative of the amino acid being a zwitterion, the additive having a polarity greater than the polarity of water, the additive being present in an amount that prevents the dye from coalescing in the solvent thereby increasing the solubility of the dye in the solvent.
24. A process as defined in claim 23 , wherein the ink composition is emitted by a printing head onto the substrate in the form of droplets, the printing head not contacting the substrate during the printing process.
25. A process as defined in claim 23 , wherein the amino acid comprises glycine, lysine, taurine, beta-alanine, betaine, or mixtures thereof.
26. A process as defined in claim 23 , wherein the additive is present in the ink composition at a mole fraction of from about 0.004 to about 0.04.
27. A process as defined in claim 23 , wherein the additive has a dipole moment greater than about 10 debye.
28. A process as defined in claim 23 , wherein the ink composition further comprises an organic cosolvent and a surfactant.
29. An ink composition comprising:
a dye;
a solvent for the dye; and
an additive comprising a sulfonic acid analog of an amino acid, the additive being present in the ink composition at a mole fraction of less than about 0.1, the additive having a polarity greater than the polarity of the solvent, the additive present in a concentration that prevents the dye from coalescing in the solvent thereby increasing the solubility of the dye in the solvent.
30. An ink composition as defined in claim 29 , wherein the amino acid comprises glycine, lysine, taurine, beta-alanine, betaine, or mixtures thereof.
31. An ink composition as defined in claim 29 , wherein the additive is present in the ink composition at a mole fraction of from about 0.004 to about 0.04.
32. An ink composition as defined in claim 29 , wherein the additive has a dipole moment greater than about 4 debye.
33. An ink composition as defined in claim 29 , wherein the additive has a dipole moment greater than about 10 debye.
34. An ink composition as defined in claim 29 , wherein the dye comprises a sulfonated dye and the solvent comprises water.