Two-component silylated polyurethane adhesive, sealant, and coating compositions

1. A two-component kit for preparing an adhesive, sealant, or coating composition comprising:

a first component comprising,

water, combined with

a first portion of an alkoxysilane-functional urethane comprising the reaction product of

a) the reaction product of a hydroxy functional compound and a polyisocyanate, the reaction product containing isocyanate functional groups; with

b) a compound corresponding to formula I:

 wherein

 X represents identical or different groups selected from C 1 -C 10 linear or branched alkyl groups and C 1 -C 10 linear or branched alkoxy groups with the proviso that at least two occurrences of X are alkoxy and if one or two X groups are methoxy, at least one X group must be a C 1 -C 10 linear or branched alkyl group,

 Y represents a C 1 -C 8 linear or branched alkylene group,

 R 2 and R 5 are identical or different and represent organic groups which are inert to isocyanate groups at a temperature of 100° C. or less, and

 R 3 and R 4 are identical or different and represent hydrogen or organic groups which are inert towards isocyanate groups at a temperature of 100° C. or less, ; and

a second component comprising

a second portion of the alkoxysilane-functional urethane, combined with

a catalyst;

with the proviso that the second component does not contain water.

2. The two-component kit for preparing an adhesive, sealant, or coating composition of claim 1 , wherein the hydroxy functional compound in a) is a polyol.

3. The two-component kit for preparing an adhesive, sealant, or coating composition of claim 1 , wherein the hydroxy functional compound in a) is a diol.

4. The two-component kit for preparing an adhesive, sealant, or coating composition of claim 1 , wherein the hydroxy functional compound is selected from the group consisting of polyester monools, diols, polyols and mixtures thereof, (meth)acrylic monools, diols, polyols and mixtures thereof, polyether monools, diols, polyols and mixtures thereof, hydrocarbon monools, diols, polyols and mixtures thereof, and mixtures thereof.

5. The two-component kit for preparing an adhesive, sealant, or coating composition of claim 1 , wherein the compound of formula I is the reaction product of an N-(trialkoxysilylalkyl) amine and a dialkyl maleate.

6. The two-component kit for preparing an adhesive, sealant, or coating composition of claim 5 , wherein the N-(trialkoxysilylalkyl) amine has a structure according to formula (II):

NH 2 —R 1 —Si(—O—R 6 ) 3   (II)

wherein R 1 is a C 1 -C 8 linear or branched alkylene group; and R 6 is independently selected from C 2 -C 10 linear or branched alkyls.

7. The two-component kit for preparing an adhesive, sealant, or coating composition of claim 1 , wherein the polyisocyanate contains from 2 to 6 isocyanate groups.

8. The two-component kit for preparing an adhesive, sealant, or coating composition of claim 1 , wherein the polyisocyanate has a structure according to formula (III):

OCN—R 7 —NCO  (III)

wherein R 7 is selected from C 2 to C 24 linear, branched, and cyclic alkylene, arylene, and aralkylene, which may optionally contain one or more isocyanate groups.

9. The two-component kit for preparing an adhesive, sealant, or coating composition of claim 1 , wherein the polyisocyanate is selected from the group consisting of 1,4-tetramethylene diisocyanate, 1,6-hexamethylene diisocyanate, 2,2,4-trimethyl-1,6-hexamethylene diisocyanate, 1,12-dodecamethylene diisocyanate, cyclohexane-1,3- and -1,4-diisocyanate, 1-isocyanato-2-isocyanatomethyl cyclopentane, 1-isocyanato-3-isocyanatomethyl -3,5,5-trimethyl-cyclohexane, bis-(4-isocyanatocyclohexyl)-methane, 2,4′-dicyclohexyl-methane diisocyanate, 1,3- and 1,4-bis-(isocyanatomethyl)-cyclohexane, bis-(4-isocyanato-3-methyl-cyclohexyl)-methane, α,α,α′,α′-tetramethyl-1,3-diisocyanate, α,α,α′,α′-1,4-xylylene diisocyanate, 1-isocyanato-1 -methyl-4(3)-isocyanatomethyl cyclohexane, 2,4-hexahydrotoluylene diisocyanate, 2,6-hexahydrotoluylene diisocyanate, 1,3-phenylene diisocyanate, 1,4-phenylene diisocyanate, 2,4-toluytene diisocyanate, 2,6-toluylene diisocyanate, 2,4-diphenyl-methane diisocyanate, 4,4′-diphenyl-methane diisocyanate, 1,5-diisocyanato naphthalene and mixtures thereof.

10. The two-component kit for preparing an adhesive, sealant, or coating composition of claim 1 , further comprising, in either or both of I) and ii), one or more materials selected from the group consisting of leveling agents, wetting agents, flow control agents, antiskinning agents, antifoaming agents, fillers, adhesion promoters, viscosity regulators, plasticizers, pigments, dyes, UV absorbers, thermal stabilizers, antioxidants, and mixtures thereof.

11. The two-component kit for preparing an adhesive, sealant, or coating composition of claim 1 , wherein the reactive silane groups of the compound corresponding to formula I are incorporated as the reaction product of an isocyanate group and the —NH— group of formula I.

12. The two-component kit for preparing an adhesive, sealant, or coating composition of claim 1 , wherein the catalyst in ii) is one or more selected from the group consisting of paratoluene sulfonic acid, dibutyl tin dilaurate, dibutyltin acetoacetonate, triethylamine, and triethylene diamine.

13. The two-component kit for preparing an adhesive, sealant, or coating composition of claim 1 , wherein component i) and component ii) are both stable at 50° C.

14. The two-component kit for preparing an adhesive, sealant, or coating composition of claim 1 , wherein the equivalent ratio of hydroxyl groups in the hydroxy functional compound to isocyanate groups in the polyisocyanate in a) is from 1:10 to 1:1.

15. The two-component kit for preparing an adhesive, sealant, or coating composition of claim 1 , wherein the reaction product a) is present at from 50 to 99 percent by weight and the amine functional aspartate b) is present at from 1 to 50 percent by weight of the alkoxysilane-functional urethane.

16. The two-component kit for preparing an adhesive, sealant, or coating composition of claim 1 , wherein the component i) is present at from 10 to 90 percent by weight and component ii) is present at from 10 to 90 percent by weight of the composition.

17. The two-component kit for preparing an adhesive, sealant, or coating composition of claim 4 , wherein the polyether has a number average molecular weight of from 500 to 15,000.

18. A method of applying a two-component kit for preparing an adhesive, sealant, or coating composition to a substrate comprising mixing component i) and component ii) of claim 1 .

19. A method of bonding a first substrate to a second substrate comprising

combining the first component and the second component of claim 1 to form a mixture,

applying a coating of the mixture to at least one surface of the first substrate or the second substrate, and

contacting a surface of the first substrate with a surface of the second substrate, wherein at least on of the contacting surfaces has the coating applied thereto.

20. The method of claim 19 , wherein one or both of the first substrate and the second substrate comprises a substrate selected from the group consisting of wood, metals, plastics, paper, canvas, ceramics, stone, glass, and concrete.

21. The method of claim 20 , wherein the metal comprises iron or aluminum.

22. The method of claim 20 , wherein the plastic is selected from the group consisting of poly(ethylene), poly(propylene), poly(ethylene terephthalate), and mixtures thereof.

23. The method of claim 20 , wherein the canvas comprises one or more fibers selected from the group consisting of cotton fibers, nylon fibers, poly(ethylene) fibers, poly(propylene) fibers, poly(ethylene terephthalate) fibers, and mixtures thereof.

24. The method of claim 19 , wherein the first substrate and the second substrate are contacted at a temperature of from 0° C. to 150° C.

25. The method of claim 19 , wherein the first substrate and the second substrate are contacted at a pressure of from atmospheric pressure to 500 psi.