IP Library Granted Patent US 7,537,800
Granted Patent B2
US 7,537,800 · App. 10/743,437 · Granted May 26, 2009

Method for producing light-transmitting electromagnetic wave-shielding film, light-transmitting electromagnetic wave-shielding film and plasma display panel using the shielding film

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Quick Facts
Patent No.
US 7,537,800
App. No.
10/743,437
Granted
May 26, 2009
Kind
B2
Abstract

A silver salt-containing layer containing a silver salt and provided on a support is exposed and developed to form a metal silver portion and a light-transmitting portion, and then the metal silver portion is further subjected to physical development and/or plating to form a conductive metal portion consisting of the metal silver portion carrying conductive metal particles. A method for producing a light-transmitting electromagnetic wave-shielding film which enables production of an electromagnetic wave-shielding material simultaneously having high EMI-shielding property and high transparency in a fine line pattern and also enables mass production of such films at a low cost, and a light-transmitting electromagnetic wave-shielding film obtained by the production method and free from the problem of moire are provided.

Claims (28)

1. A method for producing a light-transmitting electromagnetic wave-shielding film having a conductive metal portion and a light transmitting portion, which comprises

exposing a silver salt-containing layer to an electromagnetic wave, wherein the silver salt-containing layer contains a silver salt and the silver salt-containing layer is provided on a support,

developing said exposed silver salt-containing layer with a development technique used for a silver salt photographic film so as to form a metal silver portion, and

subjecting the metal silver portion to physical development and/or plating to form the conductive metal portion consisting of the metal silver portion carrying conductive metal particles;

wherein the silver salt-containing layer contains Ag and a binder and has an Ag/binder volume ratio of 1/1 or higher.

2. The method for producing a light-transmitting electromagnetic wave-shielding film according to claim 1 , wherein the silver salt in the silver salt-containing layer is a silver halide.

3. The method for producing a light-transmitting electromagnetic wave-shielding film according to claim 2 , wherein the silver halide consists mainly of silver bromide.

4. The method for producing a light-transmitting electromagnetic wave-shielding film according to claim 2 , wherein the silver halide contains a rhodium compound and/or an iridium compound.

5. The method for producing a light-transmitting electromagnetic wave-shielding film according to claim 2 , wherein the silver halide contains Pd(II) ions and/or Pd metal.

6. A method for producing a light-transmitting electromagnetic wave-shielding film according to claim 2 , wherein the silver halide functions as an optical sensor.

7. The method for producing a light-transmitting electromagnetic wave-shielding film according to claim 1 , wherein the silver salt in the silver salt-containing layer has a diameter as sphere of 0.1 to 100 nm.

8. The method for producing a light-transmitting electromagnetic wave-shielding film according to claim 1 , wherein the developer used for the development of the silver salt-containing layer is a lith developer.

9. The method for producing a light-transmitting electromagnetic wave-shielding film according to claim 1 , wherein an exposed portion after the development contains the metal silver at a content of 50% by weight or more based on the weight of silver contained in the exposed portion before the exposure.

10. The method for producing a light-transmitting electromagnetic wave-shielding film according to claim 1 , wherein the plating is performed by electroless plating.

11. The method for producing a light-transmitting electromagnetic wave-shielding film according to claim 1 , wherein the surface of the conductive metal portion is further subjected to a blackening treatment.

12. The method for producing a light-transmitting electromagnetic wave-shielding film according to claim 1 , wherein the light-transmitting electromagnetic wave-shielding film has a surface resistance of 2.5 Ω/sq or lower after the physical development and/or plating, and/or the light-transmitting portion has a transmittance of 95% or higher.

13. A method for producing a light-transmitting electromagnetic wave-shielding film according to claim 1 , wherein the support is a plastic film, a plastic plate or a glass plate.

14. A method for producing a light-transmitting electromagnetic wave-shielding film according to claim 1 , additionally comprising removing silver-salt from unexposed regions of the silver-salt containing layer.

15. A method for producing a light-transmitting electromagnetic wave-shielding film according to claim 1 , wherein the binder includes water-soluble polymers.

16. A method for producing a light-transmitting electromagnetic wave-shielding film according to claim 1 , wherein the binder includes gelatin.

17. A method for producing a light-transmitting electromagnetic wave-shielding film according to claim 1 , additionally comprising fixing the developed and exposed silver salt-containing layer.

18. The method for producing a light-transmitting electromagnetic wave-shielding film according to claim 1 , wherein the light-transmitting electromagnetic wave-shielding film has an aperture ratio of 85% or higher.

19. A method for producing a light-transmitting electromagnetic wave-shielding film having a conductive metal portion and a light transmitting portion, which comprises

exposing a silver salt-containing layer to an electromagnetic wave, wherein the silver salt-containing layer contains a silver salt and the silver salt-containing layer is provided on a support,

developing said exposed silver salt-containing layer with a development technique used for a silver salt photographic film so as to form a metal silver portion, and

subjecting the metal silver portion to physical development and/or plating to form the conductive metal portion consisting of the metal silver portion carrying conductive metal particles;

wherein the silver salt-containing layer contains Ag and a binder and has an Ag/binder volume ratio of 1/1 or higher, and

wherein the light transmitting portion does not substantially contain physical development nuclei.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 15, 2007
From: FUJIFILM HOLDINGS CORPORATION (FORMERLY FUJI PHOTO FILM CO., LTD.)
To: FUJIFILM CORPORATION
Reel/Frame 018904/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 6, 2004
From: SASAKI, HIROTOMO; NISHIZAKURA, RYOU; MORIMOTO, KIYOSHI; TAKADA, SHUNJI
To: FUJI PHOTO FILM CO., LTD.
Reel/Frame 015550/0680 →