Method for high-speed spinning of bicomponent fibers
View Patent ↗Highly crimped, fully drawn bicomponent fibers, prepared by melt-spinning, followed by gas-flow quenching, heat treatment and high speed windup, are provided, as are fine-decitex and highly uniform polyester bicomponent fibers.
1. A bicomponent fiber of about 0.6-1.7 dtex comprising poly(trimethylene terephthalate) and a polyester selected from the group consisting of poly(ethylene terephthalate) and copolyesters of poly(ethylene terephthalate), having an after-heat-set crimp contraction value above about 30%, a cross-section selected from the group consisting of side-by-side and eccentric sheath core, and a cross-sectional shape selected from the group consisting of snowman, oval, and substantially round.
2. The fiber of claim 1 wherein the weight ratio of the selected polyester to poly(trimethylene terephthalate) is about 30/70 to 70/30, and the fiber has an after-heat-set crimp contraction value of at least about 40% and a substantially round cross-sectional shape.
3. The fiber of claim 1 wherein the selected polyester is a copolyester of poly(ethylene terephthalate) in which a comonomer utilized to make the copolyester is selected from the group consisting of:
linear, cyclic, and branched aliphatic dicarboxylic acids having 4-12 carbon atoms;
aromatic dicarboxylic acids having 8-12 carbon atoms;
linear, cyclic, and branched aliphatic diols having 3-8 carbon atoms; and
aliphatic and araliphatic ether glycols having 4-10 carbon atoms.
4. The fiber of claim 3 wherein the comonomer is selected from the group consisting of isophthalic acid, pentanedioic acid, hexanedioic acid, dodecanedioic acid, 1,4-cyclohexanedicarboxylic acid, 1,3-propane diol, and 1,4-butanediol and is present in the copolyester at a level of about 0.5-15 mole percent.
5. A bicomponent fiber having an after-heat-set crimp contraction value above about 30% and an average decitex spread of less than about 2.5%, the fiber comprising poly(trimethylene terephthalate) and a polyester selected from the group consisting of poly(ethylene terephthalate) and copolyesters of poly(ethylene terephthalate), having a cross-section selected from the group consisting of side-by-side and eccentric sheath core and a cross-sectional shape selected from the group consisting of snowman, oval, and substantially round.
6. The fiber of claim 5 having a crimp contraction value of above 40%, an average decitex spread in the range of about 1.0-2.0%, a side-by-side cross-section, a substantially round cross-sectional shape.
7. The fiber of claim 6 having a weight ratio of the selected copolyester to poly(trimethylene terephthalate) of about 30/70 to 70/30, and a comonomer utilized to make the copolyester is selected from the group consisting of isophthalic acid, pentanedioic acid, hexanedioic acid, dodecanedioic acid, 1,4-cyclohexanedicarboxylic acid, 1,3-propane diol, and 1,4-butanediol, the comonomer being present in the copolyester at a level of about 0.5-15 mole percent.