Methods for forming shallow trench isolation structures
View Patent ↗Methods for forming shallow trench isolation structures are disclosed. In a disclosed example, after a trench is formed in a substrate, an oxide layer is formed on sidewalls and a bottom of the trench. Then, a metal or poly-silicon layer is formed on the oxide layer. Next, a portion of the metal or poly-silicon layer is etched such that the oxide layer on the bottom of the trench is exposed, while leaving the metal or poly-silicon layer on the sidewalls of the trench. Finally, a dielectric material layer is deposited to fully fill the trench.
1. A method for forming a shallow trench isolation structure in a semiconductor device comprising:
forming a trench in a substrate;
forming an oxide layer on sidewalls and a bottom of the trench;
forming a metal or poly-silicon layer on the oxide layer;
etching a portion of the metal or poly-silicon layer to expose the oxide layer on the bottom of the trench while leaving the metal or poly-silicon layer on the sidewalls of the trench; and
depositing a dielectric material layer to fill the trench, wherein forming the trench in the substrate comprises:
forming a LP-TEOS (Low Pressure Tetra Ethyl Ortho Silicate) oxide layer on a surface of the substrate;
forming a nitride layer on the LP-TEOS oxide layer;
forming a PR pattern on the nitride layer;
forming a LP-TEOS oxide pattern and a nitride pattern by etching the LP-TEOS oxide layer and the nitride layer using the PR pattern as a mask;
removing the PR pattern; and
etching the substrate to a predetermined depth using the nitride pattern as a mask.
2. A method as defined in claim 1 , wherein the trench is formed in the substrate by an RIE (Reactive Ion Etching) method.
3. A method as defined in claim 1 , wherein the oxide layer contains LP-TEOS oxide or thermal oxide.
4. A method as defined in claim 1 , wherein the metal or poly-silicon layer contains poly-silicon, a laminated metal of Ti, TiN and W, or a laminated metal of Ta, TaN and W.
5. A method as defined in claim 1 , wherein the dielectric material layer contains oxide.
6. A method as defined in claim 1 , wherein the dielectric material layer is deposited by using an HDP CVD (High Density Plasma Chemical Vapor Deposition) method or an O 3 -TEOS CVD (Ozone-Tetra Ethyl Ortho Silicate Chemical Vapor Deposition) method.
7. A method as defined in claim 1 , wherein forming the LP-TEOS oxide layer on the surface of the substrate and forming the nitride layer on the LP-TEOS oxide layer are performed by using a LPCVD (Low Pressure Chemical Vapor Deposition) method.
8. A method as defined in claim 1 , wherein forming the LP-TEOS oxide pattern and the nitride pattern by etching the LP-TEOS oxide layer and the nitride layer is performed by an RIE method.
9. A method for forming a shallow trench isolation structure comprising:
(a) forming a trench in a substrate;
(b) forming a first oxide layer on sidewalls and a bottom of the trench;
(c) forming a second oxide layer on the first oxide layer;
(d) forming a PSG (Phosphor Silicon Glass) layer on the second oxide layer; and
(e) depositing a USG (Undoped Silicon Glass) layer to fill the trench.
10. A method as defined in claim 9 , wherein the trench is formed in the substrate by an RIE method.
11. A method as defined in claim 9 , wherein the first oxide layer contains LP-TEOS oxide or thermal oxide.
12. A method as defined in claim 9 , wherein the second oxide layer contains HDP CVD oxide or O 3 -TEOS oxide.
13. A method as defined in claim 9 , wherein the PSG layer is deposited by an HDP CVD or O 3 -TEOS CVD method.
14. A method as defined in claim 9 , wherein the USG layer is deposited by an HDP CVD or O 3 -TEOS CVD method.
15. A method as defined in claim 9 , wherein forming the trench in the substrate comprises:
forming a LP-TEOS (Low Pressure Tetra Ethyl Ortho Silicate) oxide layer on a surface of the substrate;
forming a nitride layer on the LP-TEOS oxide layer;
forming a PR pattern on the nitride layer;
forming a LP-TEOS oxide pattern and a nitride pattern by etching the LP-TEOS oxide layer and the nitride layer using the PR pattern as a mask;
removing the PR pattern; and
etching the substrate to a predetermined depth using the nitride pattern as a mask.
16. A method as defined in claim 15 , wherein forming the LP-TEOS oxide layer on the surface of the substrate and forming the nitride layer on the LP-TEOS oxide layer are performed by an LPCVD method.
17. A method as defined in claim 15 , wherein forming the LP-TEOS oxide pattern and the nitride pattern by etching the LP-TEOS oxide layer and the nitride layer is performed by an RIE method.