Process for the preparation of pink light-emitting diode with high brightness
View Patent ↗The subject invention relates to yttrium aluminum garnet fluorescent powders with formula (Y 3-x-y Z x Eu y )Al 5 O 12 or (Y 3 Z x Eu y )Al 5 O 12 , wherein 0<x≦0.8, 0<y≦1.5, and Z is selected from a group consisting of rare earth metals other than europium (Eu). The subject invention also relates to a pink light-emitting device, which comprises a light-emitting diodes as a luminescent element and a fluorescent body containing yttrium aluminum garnet fluorescent powders, wherein the diode emits a light with a wavelength ranging from 370 to 410 nm, which then excites the yttrium aluminum garnet fluorescent powders in the fluorescent body to emit another light with a wavelength ranging from 585 nm to 700 nm, so the two lights combine to produce a pink light. The subject invention also relates to the preparation of the yttrium aluminum garnet fluorescent powders.
1. A gelation process for the preparation of a yttrium aluminum garnet fluorescent powder with formula (Y 3-x-y Z x Eu y )Al 5 O 12 , wherein 0<x≦0.8, 0<y≦1.5, and Z is at least one rare earth metal selected from the group consisting of rare earth metals other than europium (Eu), said process comprises the steps of (1) grinding and homogeneously mixing water soluble compounds containing desired metals in ratios as those of the metals in the fluorescent powder to provide a powder mixture, (2) dissolving the powder mixture in water to form an aqueous solution, (3) adding an appropriate amount of a chelating agent into the aqueous solution to chelate the metals in the aqueous solution, (4) adjusting the pH value of the aqueous solution to equal to or greater than 7 and converting the aqueous solution into a viscous liquid thereby, (5) pyrolyzing the viscous liquid to an ash, (6) calcining the ash, and (7) sintering the calcined ash to form the fluorescent powder.
2. A gelation process according to claim 1 , wherein the compound used in step (1) is a salt or an organic compound.
3. A gelation process according to claim 1 , wherein the water used in step (2) is de-ionized water.
4. A gelation process according to claim 1 , wherein the chelating agent used in step (3) is an organic or inorganic compound which can form a chelate with the selected metals.
5. A gelation process according to claim 1 , wherein an organic base or inorganic base is used in step (4) to adjust the pH value of the aqueous solution.
6. A gelation process according to claim 1 , wherein the sintered powder is further reduced after step (7).
7. A co-precipitation process for the preparation of a yttrium aluminum garnet fluorescent powder with formula (Y 3-x-y Z x Eu y )Al 5 O 12 , wherein 0<x≦0.8, 0<y≦1.5, and Z is at least one rare earth metal selected from the group consisting of rare earth metals other than europium (Eu), said process comprises the steps of (1) grinding and homogeneously mixing water soluble compounds containing desired metals in ratios as those of the metals in the fluorescent powder to provide a powder mixture, (2) dissolving the powder mixture in water to form an aqueous solution, (3) adjusting the pH value of the aqueous solution to equal to or greater than 7 and converting the aqueous solution into a gel thereby, (4) pyrolyzing the gel to an ash, (5) calcining the ash, and (6) sintering the calcined ash to form the fluorescent powder.
8. A co-precipitation process according to claim 7 , wherein the compound used in step (1) is a salt or an organic compound.
9. A co-precipitation process according to claim 7 , wherein the water used in step (2) is de-ionized water.
10. A co-precipitation process according to claim 7 , wherein an organic base or inorganic base is used in step (3) to adjust the pH value of the aqueous solution.
11. A co-precipitation process according to claim 7 , wherein the sintered powder is further reduced after step (6).