Polycarbonate resin for optical disk substrate and optical disk substrate
View Patent ↗The present invention relates to a polycarbonate resin that has a viscosity average molecular weight of from 10,000 to 17,000 and has characteristic features in an iron content, a free total phenol content, a content of a releasing agent, a fraction of hydroxyl end groups, a 1 H-NMR spectrum or the like. The polycarbonate resin has less defects due to flash without increase of an addition amount of a releasing agent to an unnecessary level and therefore is suitable for a material of an optical disk substrate.
1. A polycarbonate resin composition, comprising:
a polycarbonate resin; and
150 to 350 ppm of a fatty acid monoester of glycerin;
wherein said polycarbonate resin composition has a viscosity average molecular weight of from 10,000 to 17,000, an iron content of 0.2 ppm or less and a fraction of hydroxyl end groups of less than 7% by mole.
2. An optical disk substrate, comprising:
the polycarbonate resin composition as described in claim 1 .
3. The polycarbonate resin composition as described in claim 1 , wherein said polycarbonate resin is obtained from a purified dihydric phenol,
said purified dihydric phenol being obtained by washing an adduct of the dihydric phenol and phenol with a purified phenol to obtain a washed adduct, and decomposing said washed adduct into phenol and said purified dihydric phenol used to produce the polycarbonate resin.
4. The polycarbonate resin composition as described in claim 1 , further comprising:
20 to 100 ppm of a phosphorous antioxidant.
5. The polycarbonate resin composition as described in claim 3 , wherein said dihydric phenol used for obtaining the polycarbonate resin is bisphenol A.
6. The optical disk substrate as described in claim 2 , wherein said polycarbonate resin composition further comprises
20 to 100 ppm of a phosphorous antioxidant.
7. The optical disk substrate as described in claim 2 , wherein said polycarbonate resin is obtained from a purified dihydric phenol,
said purified dihydric phenol being obtained by washing an adduct of the dihydric phenol and phenol with a purified phenol to obtain a washed adduct, and decomposing said washed adduct into phenol and said purified dihydric phenol used to produce the polycarbonate resin.
8. The optical disk substrate as described in claim 7 , wherein said dihydric phenol used for obtaining the polycarbonate resin is bisphenol A.