Graft polymer curatives and polyurethanes formed therefrom
View Patent ↗Graft polymer curatives comprise a side chain having an average molecular weight of at least about 500, a main chain having an average molecular weight of less than about 200, and diol functionality on the main chain. The graft polymer curative is formed via free radical polymerization of at least one ethylenically-unsaturated monomer with a chain transfer agent or initiator.
1. A method of manufacturing a graft polymer curative, the method comprising: conducting free radical polymerization of at least one ethylenically unsaturated monomer with at least one chain transfer agent or initiator, wherein the graft polymer curative has aside chain having a number average molecular weight of greater than about 500, a main chain having a number average molecular weight of less than about 200, and diol functionality on the main chain, wherein the at least one ethylenically unsaturated monomer comprises at least one acrylate, wherein the acrylate comprises 3-(tris(trimethylsiloxy)silyl)propyl methacrylate and/or poly(propylene glycol)methyl ether acrylate.
2. The method as recited in claim 1 wherein the chain transfer agent comprises a diol-functional mercaptan.
3. The method as recited in claim 2 wherein the diol-functional mercaptan chain transfer agent comprises a mercapto-substituted alkanediol.
4. The method as recited in claim 2 wherein the dial-functional mercaptan chain transfer agent comprises 3-mercapto-1,2-propanediol.
5. The method as recited in claim 1 wherein the side chain has a number average molecular weight of from greater than about 500 to about 25,000.
6. The method as recited in claim 1 wherein the side chain has a number average molecular weight of from about 1000 to about 10,000.
7. The method as recited in claim 1 wherein the graft polymer curative further comprises side chain functionality of at least one.
8. A graft polymer curative, comprising a side chain having a number average molecular weight of at least about 500, a main chain having an average molecular weight of less than about 200, and diol functionality on the main chain, wherein the graft polymer curative is formed via free radical polymerization of at least one ethylenically-unsaturated monomer with a chain transfer agent or initiator, wherein the at least one ethylenically unsaturated monomer comprises at least one acrylate, wherein the acrylate comprises 3-(tris(trimethylsiloxy)silyl)propyl methacrylate and/or poly(propylene glycol)methyl ether acrylate.
9. The graft polymer curative as recited in claim 8 wherein the chain transfer agent is a diol-functional mercaptan.
10. The graft polymer curative as recited in claim 8 wherein the side chain has a number average molecular weight of from greater than about 500 to about 25,000.
11. The graft polymer curative as recited in claim 8 wherein the side chain has a number average molecular weight of front about 1000 to about 10,000.
12. A method of manufacturing a polyurethane elastomer, the method comprising forming a polyurethane mixture comprising a urethane prepolymer; the graft polymer curative of claim 8 ; and optionally at least one linear polymer curative; and subjecting the mixture to conditions sufficient to effect curing; wherein the graft polymer curative comprises a side chain having a number average molecular weight greater than about 500, a main chain having a number average molecular weight less than about 200, diol functionality of the main chain, and wherein the graft polymer curative is formed via free radical polymerization of at least one ethylenically-unsaturated monomer with a mercaptan diol-functional chain transfer agent or initiator.
13. A polyurethane elastomer comprising a cured polyurethane mixture, the polyurethane mixture comprising urethane prepolymer; the graft polymer curative of claim 8 ; and optionally at least one linear polymer curative; wherein the graft polymer curative comprises a side chain having an average molecular weight greater than about 500, a main chain having an average molecular weight less than about 200, and diol functionality on the main chain, and wherein the graft polymer curative is formed via free radical polymerization of at least one ethylenically-unsaturated monomer with a chain transfer agent or initiator.
14. The polyurethane elastomer recited in claim 13 wherein the chain transfer agent or initiator is a diol-functional mercaptan.
15. The polyurethane elastomer as recited in claim 13 comprising from about 1 to about 30 percent by weight of the graft polymer curative.
16. The polyurethane elastomer as recited in claim 13 comprising from about 8 to about 20 percent by weight of the graft polymer curative.
17. The polyurethane elastomer as recited in claim 13 comprising from about 8 to about 12 percent by weight of the graft polymer curative.
18. A roll comprising the polyurethane elastomer as recited in claim 13 .
19. The roll according to claim 18 , wherein the roll is a developer roll adapted for use in electrophotographic print applications.
20. A graft polymer curative comprising a side chain having a number average molecular weight of at least about 500, a main chain having an average molecular weight of less than about 200, and diol functionality on the main chain, wherein the graft polymer curative is formed via free radical polymerization of two or more ethylenically-unsaturated monomers with a chain transfer agent or initiator, wherein the graft polymer curative comprises a copolymer system comprising poly((3-(tris(trimethylsiloxy)silyl)propylmethacrylate)-co-(poly(propylene glycol)methyl ether acrylate)).