Apparatus for preparing polyolefin products and methodology for using the same
View Patent ↗Apparatus for olefin polymerization includes a plurality of shell and tube olefin polymerization reactors, each of which has an olefin polymerization reaction mixture inlet connection and a crude polyolefin product outlet connection. Each reactor is equipped with a recirculation system including a pump arranged to circulate a reaction mixture through the tube side of the reactor independently of the introduction of olefin polymerization reaction mixture into the reactor. The apparatus also includes an inlet reaction mixture distribution manifold and an outlet polymerization reaction mixture collection manifold interconnecting the reactors for operation in parallel. The apparatus also includes catalyst composition and catalyst modifier inlets for each reactor arranged such that a catalyst modifier to may be introduced into each reactor at a rate which is independent of the introduction of catalyst composition. The apparatus further incorporates a crude polyolefin product catalyst removal and wash system including a plurality of settler vessels, associated piping and an inlet for a catalyst killing agent. This crude polyolefin product catalyst removal and wash system operates to receive crude polyolefin product from the crude polyolefin product outlet and remove residual catalyst therefrom.
1. A method for olefin polymerization comprising:
providing a reactor system including a plurality of reactors arranged for parallel flow, each said reactor defining an internal reaction zone;
supplying an olefin containing feedstock and dividing the same into a plurality of separate feedstock streams;
introducing each of said separate olefin containing feedstock streams into the reaction zone of a respective one of said reactors;
conducting an exothermic olefin polymerization reaction on an olefin polymerization reaction mixture in each reaction zone;
separately circulating the reaction mixture in each reactor at a flow rate that is independent of the rate of introduction of the respective stream of feedstock into the reaction zone while said exothermic olefin polymerization reaction is ongoing;
removing a crude polyolefin product stream from each of said reactors; and
combining said crude polyolefin product streams to form a single crude product stream.
2. A method as set forth in claim 1 , wherein said system includes two of said reactors and said olefin polymerization reaction mixture is divided into two separate streams.
3. A method as set forth in claim 1 , wherein said system includes at least three of said olefin polymerization reaction mixture is divided into at least three separate streams.