Method for recovering metal values from metal-containing materials using high temperature pressure leaching
View Patent ↗The present invention relates generally to a process for recovering copper and other metal values from metal-containing materials through pressure leaching operations. In accordance with the various aspects of the present invention, metal-containing pregnant leach solutions from pressure leaching operations need not be significantly diluted to facilitate effective metal recovery using solvent extraction and electrowinning.
1. A process for recovering at least one metal value from a metal-bearing material, comprising the steps of:
a) pressure leaching a metal-bearing material with an acidic solution to yield a residue and a metal-bearing solution;
b) adjusting the pH of said metal-bearing solution using a chemical pH adjustment step in combination with a dilution step to form a pH-adjusted metal-bearing solution, wherein the pH of said pH-adjusted metal-bearing solution is less than about 2.2 and wherein said dilution step is performed using a ratio of said metal-bearing solution to a diluting solution of less than 1:10; and
c) solvent extracting at least one metal value from said pH-adjusted metal-bearing solution.
2. The process of claim 1 , wherein in said diluting step, the ratio by volume of said metal-bearing solution to said diluting solution ranges from about 1:4 to about 1:8.
3. The process of claim 1 , further comprising providing an extraction reagent for use in said step of solvent extracting said at least one metal value from said diluted metal-bearing solution.
4. The process of claim 3 , wherein said step of providing an extraction reagent comprises providing at least one of an aldoxime, a modified aldoxime, and an aldoxime/ketoxime mixture.
5. The process of claim 1 , wherein said pressure leaching step comprises high temperature pressure leaching at a temperature from about 210° C. to about 235° C.
6. The process of claim 1 , wherein said pressure leaching step is at superatmospheric pressure at a temperature of about 225° C. in an oxygen-containing atmosphere.
7. The process of claim 1 , further comprising the step of comminuting said metal-bearing material prior to the step of pressure leaching.
8. The process of claim 7 , wherein said comminuting step comprises comminuting said metal-bearing material to a P80 of less than about 75 microns.
9. The process of claim 1 , further comprising the step of recovering any precious metals contained in said pressure leaching residue.