IP Library Granted Patent US 7,169,328
Granted Patent B2
US 7,169,328 · App. 10/759,348 · Granted Jan 30, 2007

Multiphase nanocomposite material and method for its manufacture

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Quick Facts
Patent No.
US 7,169,328
App. No.
10/759,348
Granted
Jan 30, 2007
Kind
B2
Abstract

A multiphase composite material having utility as an electrochemical electrode or catalyst includes a first active phase which is an amorphous, electrochemically active material; and a second, stabilizer phase which includes one or more of: metals, carbon, ceramics, and intermetallic compounds. The stabilizer phase is configured as a plurality of spaced apart regions having the active phase disposed therebetween. The active phase may comprise one or more of: Sn, Sb, Bi, Pb, Ag, In, Si, Ge, and Al. The stabilizer phase may include one or more of: Fe, Zr, Ti, and C. Also disclosed are electrodes and batteries which include the material as well as methods for manufacturing the material by using a mechanical alloying process.

Claims (22)

1. An electrode comprising:

a multiphase composite material, said multiphase composite material comprising: a first, active, phase comprising an amorphous, electrochemically active material including nanophase domains of a material selected from the group consisting of: Sn, Sb, Bi, Pb, Ag, In, Si, Ge, Al, and combinations thereof; and a second, stabilizer, phase comprising a ceramic, said stabilizer phase being configured as a plurality of spaced apart regions having said active phase interspersed therebetween, said stabilizer phase being electrochemically active.

2. The electrode of claim 1 , wherein said stabilizer phase includes at least one element selected from the group consisting of: Fe, Zr, Ti, and C.

3. The electrode of claim 1 , wherein said stabilizer phase comprises a member selected from the group consisting of: metal nitrides, metal carbides, metal oxynitrides, metal oxycarbides, and combinations thereof.

4. The electrode of claim 1 , wherein said spaced apart regions of said stabilizer phase have a size in the range of 10–100 nanometers.

5. A method of making a multiphase composite material, said method comprising the steps of:

providing a plurality of components, said components including the elements of which said multiphase composite material is comprised; and

subjecting said plurality of components to a mechanical alloying process wherein said mechanical alloying process comprises a staged process wherein a first portion of said plurality of components are subjected to a first mechanical alloying process so as to produce a first component of said multiphase composite material, and a second portion of said components are subsequently subjected to a second mechanical alloying process with said component; whereby said multiphase composite material is formed.

6. A method of making a multiphase composite material, said method comprising the steps of:

providing a plurality of components, said components including the elements of which said multiphase composite material is comprised; and

subjecting said plurality of components to a mechanical alloying process which is a substitutional process wherein, in a first step, a first composition which includes a first and second element of said multiphase composite material is subjected to a mechanical alloying process along with a third composition which is comprised of a third element and a fourth element of said multiphase composite material, wherein said third element displaces said second element from said first composition so as to form a second composition which includes said first and third element.

7. A multiphase, composite material comprising:

a first, electrochemically active phase including amorphous, nanophase domains of tin or silicon therein; and

a second, stabilizer phase comprising an electrochemically active material selected from the group consisting of metal nitrides, metal carbides, metal oxynitrides, metal oxycarbides, and combinations thereof, said stabilizer phase comprising a matrix configured as a plurality of spaced apart regions having said first phase interspersed therebetween.

8. The material of claim 7 , wherein said active phase comprises, on a weight basis, 30–60% of said material.

9. The material of claim 7 , wherein said nanophase domains have a size in the range of 10–30 nanometers.

10. The material of claim 7 , wherein said stabilizer phase comprises an amorphous material.

11. The material of claim 7 , wherein said stabilizer phase comprises a crystalline material.

12. The material of claim 7 , wherein said material is prepared by a mechanical alloying process.

13. The material of claim 12 , wherein said mechanical alloying process is a ball milling process.

14. The material of claim 12 , wherein said mechanical alloying process is an attritor milling process.

15. The material of claim 12 , wherein said mechanical alloying process is a grinding process.

Assignments (6)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 18, 2013
From: A123 SYSTEMS, INC.
To: WANXIANG CLEAN ENERGY USA ACQUISITION LLC
Reel/Frame 030639/0213 →
CHANGE OF NAME Recorded Jun 18, 2013
From: WANXIANG CLEAN ENERGY USA ACQUISITION LLC
To: A123 SYSTEMS LLC
Reel/Frame 030639/0244 →
BANKRUPTCY ORDER AUTHORIZING THE SALE OF ASSETS FREE AND CLEAR OF ALL CLAIMS, LIENS, LIABILITIES, RIGHTS, INTERESTS AND ENCUMBRANCES (RELEASES WANXIANG SECURITY INTEREST) Recorded Jun 17, 2013
From: WANXIANG AMERICA CORPORATION
To: A123 SYSTEMS, INC.
Reel/Frame 030628/0494 →
SECURITY AGREEMENT Recorded Aug 17, 2012
From: A123 SYSTEMS, INC.
To: WANXIANG AMERICA CORPORATION
Reel/Frame 028801/0112 →
MERGER Recorded Oct 3, 2008
From: T/J TECHNOLOGIES, INC.
To: A123 SYSTEMS, INC.
Reel/Frame 021628/0917 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 16, 2004
From: MILLER, JOHN; WANG, LIYA
To: T/J TECHNOLOGIES, INC.
Reel/Frame 014907/0238 →