Process for preparing polymeric fibers based on blends of at least two polymers
View Patent ↗Blending of thermoplastic polyester with fiber-forming polyamide in the production of melt-colored melt-spun fibers results in improved color strength and aesthetics, and dimensional stability.
1. Process for producing colored synthetic fibers having improved color strength and dimensional stability, the process comprising:
(1) melt blending:
a) at least one fiber-forming polyamide,
b) at least one unsulfonated thermoplastic polyester, said at least one unsulfonated thermoplastic polyester being present at between about 15% and 35% by weight with respect to the total weight of the composition, and forming a dispersed, non-continuous, minor phase in a matrix of said fiber-forming polyamide,
c) a colorant system comprising at least one colorant selected from the group consisting of inorganic pigments and organic pigments;
d) at least one metal sulfonate polyester compatibilising additive;
(2) forming said melt blend into filaments; and
(3) drawing said filaments into fibers.
2. A process according to claim 1 , wherein said at least one metal sulfonate polyester compatibizing additive is selected from the group consisting of alkali metal salts of poly(ethylene terephthalate-co-sulphoisophthalate), poly(propylene terephthalate-co-sulphoisophthalate) and poly(butylene terephthalate-co-sulphoisophthalate).
3. A process according to claim 1 , wherein said metal sulphonate copolymer is present at between about 1 weight % and about 25 weight % of the melt blend.
4. A process according to claim 1 , wherein said metal sulphonate polyester is added in an amount such that the melt blend has between about 300 and about 3500 ppm sulphur.
5. A process according to claim 1 , wherein said colorant system employed in the step of melt blending includes at least one carrier resin for said colorant selected from the group consisting of polyamides, polyesters and sulphonated polyesters.
6. A process according to claim 1 , comprising the further step of texturing said fibers subsequent to drawing said filaments into fibers.
7. A process according to claim 1 , wherein said at least one fiber-forming polyamide is selected from the group consisting of polyamide 6, polyamide 11, polyamide 12, polyamide 6,6, polyamide 6,10, polyamide 6,12, and copolymers thereof.
8. A process according to claim 1 , wherein said at least one fiber-forming polyamide is selected from the group consisting of polyamide 6 and polyamide 6,6.
9. A process according to claim 1 , wherein said at least one thermoplastic polyester is selected from the group consisting of polyalkylene terephthalates, polyalkylene succinates, polyalkylene adipates, polyhydroxyacids and copolymers thereof.
10. A process according to claim 1 , wherein said at least one thermoplastic polyester is selected from the group consisting of poly(ethylene terephthalate), poly(propylene terephthalate), poly(butylene terephthalate), and copolymers thereof.
11. A process according to claim 1 , wherein said at least one colorant is selected from the group consisting of metal oxides, mixed metal oxides, metal sulphides, zinc ferrites, sodium alumino sulpho-silicate pigments, carbon blacks, phthalocyanines, quinacridones, nickel azo compounds, mono azo colorants, anthraquinones and perylenes.
12. A process according to claim 1 , wherein said at least one colorant is selected from the group consisting of carbon black, titanium dioxide, zinc sulphide, zinc oxide, Ultramarine Blue, cobalt aluminates, iron oxides, Pigment Blue 15, Pigment Blue 60, Pigment Brown 24, Pigment Red 122, Pigment Red 147, Pigment Red 149, Pigment Red 177, Pigment Red 178, Pigment Red 179, Pigment Red 202, Pigment Red 272, Pigment Violet 19, Pigment Violet 29, Pigment Green 7, Pigment Green 36, Pigment Yellow 119, Pigment Yellow 147 and Pigment Yellow 150.
13. A process according to claim 1 , wherein said at least one colorant is present at between about 0.1 weight % and about 8 weight % of the composition.
14. A process according to claim 1 , including the further step of adding at least one adjuvant selected from the group consisting of an antioxidant, stabiliser, processing aid, antimicrobial, flame-retardant, antiozonant, soilproofing agent, stainproofing agent, antistatic additive, lubricant and melt viscosity enhancer.
15. A process according to claim 1 , wherein a draw ratio in said drawing step is from 1.05 to 7.00.
16. A process according to claim 1 , wherein a draw ratio in said drawing step is from 1.10 to 6.00.
17. A process according to claim 1 , wherein a draw ratio in said drawing step is from 1.05 to 7.00.
18. A process according to claim 1 , wherein a draw ratio in said drawing step is from 1.10 to 6.00.
19. A fiber made from the process of claim 1 .
20. A woven, knitted or pile textile article made from the fiber of claim 19 .
21. A carpet of floorcovering made from the fiber of claim 19 .
22. A fiber made from the process of claim 1 , wherein said fiber has a cross-section selected from the group consisting of round, delta and trilobal.