Ink-jet recording ink and image forming method
View Patent ↗The present invention relates to an ink-jet recording ink, containing a pigment and a compound represented by the General formula (I): R—X Y n H General formula (I) wherein R represents a hydrophobic group, or a group derived from a hydrophobic polymer; X represents a bivalent linking group having a hetero bond; Y may be A, C or D, and (Y) n contains 0 to 40% by mole of a structural unit represented by B; and n=10-3500; R 1 represents H, or an alkyl group; R 2 represents H or an alkyl groups; R 3 represents H or a methyl group; and R 4 represents H, —CH 3 , —CH 2 COOH, or —CN; Z 1 : H, —COOH, or —CONH 2 ; Z 2 : —COOH, —SO 3 H, —OSO 3 H, —CH 2 SO 3 H, —CONHC(CH 3 ) 2 CH 2 SO 3 H, or —CONHCH 2 CH 2 CH 2 N + (CH 3 ) 3 Cl − .
1. An ink-jet recording ink, comprising a pigment and a compound represented by the following General formula (I):
R—X Y n H General formula (I)
wherein in General formula (I), R represents a hydrophobic group, or a group derived from a hydrophobic polymer; X represents a bivalent linking group having a hetero bond; n is an integer from 10 to 3500; and structural units of repeated Y comprise at least one structural unit represented by A, C or D, and further comprise 0 to 40% by mole of structural units represented by B:
wherein in structural units A through D, R 1 represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms; R 2 represents a hydrogen atom or an alkyl group having 1 to 10 carbon atoms; R 3 represents a hydrogen atom or a methyl group; R 4 represents a hydrogen atom, —CH 3 , —CH 2 COOH or an ammonium salt thereof or alkali metal salt thereof, or —CN; Z 1 represents a hydrogen atom, —COOH or an ammonium salt thereof or alkali metal salt thereof, or —CONH 2 ; and Z 2 represents —COOH or an ammonium salt thereof or alkali metal salt thereof, —SO 3 H or an ammonium salt thereof or alkali metal salt thereof, —OSO 3 H or an ammonium salt thereof or alkali metal salt thereof, —CH 2 SO 3 H or an ammonium salt thereof or alkali metal salt thereof, —CONHC(CH 3 ) 2 CH 2 SO 3 H or an ammonium salt thereof or alkali metal salt thereof, or —CONHCH 2 CH 2 CH 2 N + (CH 3 ) 3 Cl − .
2. An ink-jet recording ink according to claim 1 , wherein the hydrophobic group represented by R in General formula (I) is an aliphatic group or an aromatic group.
3. An ink-jet recording ink according to claim 2 , wherein the hydrophobic group represented by R in General formula (I) is an alicyclic group.
4. An ink-jet recording ink according to claim 2 , wherein the hydrophobic group represented by R in General formula (I) is selected from the group consisting of alkyl, alkenyl, alkynyl, phenyl and naphthyl groups.
5. An ink-jet recording ink according to claim 4 , wherein the hydrophobic group represented by R in General formula (I) is an alkyl group having 3 to 70 carbon atoms.
6. An ink-jet recording ink according to claim 1 , wherein R in General formula (I) is a group derived from at least one hydrophobic polymer selected from the group consisting of polystyrene, polymethacrylic acid ester, polyacrylic acid ester, polyvinyl chloride, and derivatives thereof.
7. An ink-jet recording ink according to claim 5 , wherein a polymerization degree of R in the General formula (I) is from 2 to 500.
8. An ink-jet recording ink according to claim 1 , wherein the hetero bond in X in the General formula (I) is selected from the group consisting of an ether bond, an ester bond, a thioether bond, a thioester bond, a sulfonyl bond, an amide bond, an imide bond, a sulfonamide bond, a urethane bond, a urea bond, and a thiourea bond.
9. An ink-jet recording ink according to claim 1 , wherein Y comprises a structural unit represented by A, and the structural unit A is a structural unit derived from vinyl alcohol, α-methylvinyl alcohol, or α-propylvinyl alcohol.
10. An ink-jet recording ink according to claim 1 , wherein the structural unit B is a structural unit derived from vinyl acetate, vinyl formate, vinyl propionate, or an α-substitution product thereof.
11. An ink-jet recording ink according to claim 1 , wherein Y comprises a structural unit C, and the structural unit C is a structural unit derived from acrylic acid, methacrylic acid, itaconic acid, maleic acid, an ammonium salt thereof or a metal salt thereof.
12. An ink-jet recording ink according to claim 1 , wherein Y comprises a structural unit D, and the structural unit D is selected from the group consisting of —CH 2 CH(OH)CH 2 O—, —CH 2 C(CH 3 )(OH)CH 2 O—, and —CH 2 C(C 2 H 5 )(OH)CH 2 O—.
13. An ink-jet recording ink according to claim 1 , wherein a mass ratio of R to (Y) n in General formula (I) is from 0.01 to 2, the mass ratio being calculated using atomic weights of respective atoms in R and (Y) n .
14. An ink-jet recording ink according to claim 1 , wherein (Y) n in General formula (I) comprises, as a structural unit thereof, ethylene, propylene, isobutene, acrylonitrile, acrylamide, methacrylamide, N-vinylpyrrolidone, vinyl chloride or vinyl fluoride.
15. An ink-jet recording ink according to claim 1 , further comprising water.
16. An ink-jet recording ink according to claim 1 , further comprising an water-soluble organic solvent.
17. An ink-jet recording ink according to claim 1 , further comprising a dispersing agent.
18. An ink-jet recording ink according to claim 1 , further comprising a drying inhibitor.
19. An ink-jet recording ink according to claim 1 , further comprising a penetration promoter.
20. An ink-jet recording ink according to claim 1 , further comprising a high-boiling water-soluble solvent and a surface tension adjuster.
21. An ink-jet recording ink according to claim 1 , which has a surface tension of 20 to 60 mN/m.
22. A method, comprising ejecting or discharging an ink-jet recording ink comprising a pigment and a compound represented by the following General formula (I) to form an image:
R—X Y n H General formula (I)
wherein in General formula (I), R represents a hydrophobic group, or a group derived from a hydrophobic polymer; X represents a bivalent linking group having a hetero bond; n is an integer from 10 to 3500; and structural units of repeated Y comprise at least one structural unit represented by A, C or D, and further comprise 0 to 40% by mole of structural units represented by B:
wherein in structural units A through D, R 1 represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms; R 2 represents a hydrogen atom or an alkyl group having 1 to 10 carbon atoms; R 3 represents a hydrogen atom or a methyl group; R 4 represents a hydrogen atom, —CH 3 , —CH 2 COOH or an ammonium salt thereof or alkali metal salt thereof, or —CN; Z 1 represents a hydrogen atom, —COOH or an ammonium salt thereof or alkali metal salt thereof, or —CONH 2 ; and Z 2 represents —COOH or an ammonium salt thereof or alkali metal salt thereof, —SO 3 H or an ammonium salt thereof or alkali metal salt thereof, —OSO 3 H or an ammonium salt thereof or alkali metal salt thereof, —CH 2 SO 3 H or an ammonium salt thereof or alkali metal salt thereof, —CONHC(CH 3 ) 2 CH 2 SO 3 H or an ammonium salt thereof or alkali metal salt thereof, or —CONHCH 2 CH 2 CH 2 N + (CH 3 ) 3 Cl − .
23. An image forming method according to claim 22 , wherein the hydrophobic group represented by R in General formula (I) is an aliphatic group or an aromatic group.