Photostructurable body and process for treating a glass and/or a glass-ceramic
View Patent ↗The invention relates to a photostructurable body, in particular glass or glass-ceramic, in which the glass is a multicomponent glass and/or the glass-ceramic is a multicomponent glass-ceramic, in each case having a positive change in refractive index Δn as a result of the action of light.
1. A photostructurable body comprising:
glass , wherein the glass is a multicomponent glass having a positive change in refractive index Δn as a result of exposure to light, and wherein the glass is a lithium-aluminosilicate glass comprising less than 3.5% by weight of B 2 O 3 ; and
a waveguide structure directly written in said glass.
2. The photostructurable body as claimed in claim 1 , wherein the glass comprises a composition from 15 to 90% by weight of SiO 2 , from 1 to 35% by weight of Al 2 O 3 , and from 1 to 20% by weight of Li 2 O.
3. The photostructurable body as claimed in claim 2 , wherein the composition comprises from 20 to 85% by weight of SiO 2 , from 5 to 35% by weight of Al 2 O 3 , from 1 to 18% by weight of Li 2 O.
4. The photostructurable body as claimed in claim 2 , wherein the composition comprises from 25 to 75% by weight of SiO 2 , from 5 to 30% by weight of Al 2 O 3 , and from 2 to 15% by weight of Li 2 O.
5. The photostructurable body as claimed in claim 1 , wherein the glass comprises a sensitizer and/or activator selected from the group consisting of Ce ions, Er ions, Eu ions, and any combinations thereof.
6. The photostructurable body as claimed in claim 1 , wherein the glass comprises a photosensitive element or a mixture of photosensitive elements selected from the group consisting of Cu, Ag, Au, Ce 3+ , Eu 2+ , polyvalent heavy metal and metal cations, and any combinations thereof.
7. The photostructurable body as claimed in claim 1 , wherein the glass comprises a sensitizer and/or activator, and a photosensitive element.
8. The photostructurable body as claimed in claim 1 , wherein the glass comprises halides selected from the group consisting of F, Br, Cl, I, and any combinations thereof.
9. The photostructurable body as claimed in claim 1 , wherein the glass comprises Ag halide crystallites and/or clusters.
10. The photostructurable body as claimed in claim 1 , wherein the glass comprises silver or gold clusters.
11. The photostructurable body as claimed in claim 1 , wherein the glass comprises two-dimensional and/or three-dimensional structures, said two-dimensional and/or three-dimensional structures comprise fs irradiated crystallites.
12. The photostructurable body as claimed in claim 1 , wherein the glass comprises a dopant that provides absorption centers for absorption of light.
13. A photostructure body, as claimed in claim 12 , wherein the absorption centers for the absorption of light can be bleached out and can be used to influence the refractive index of the glass.
14. The photostructurable body as claimed in claim 13 wherein the absorption centers for the absorption of light effect a positive change in the refractive index under the action of light.