Low monomer containing laminating resin compositions
View Patent ↗A laminating resin composition is disclosed which comprises an unsaturated polyester resin, a vinyl ester resin, a polyfunctional acrylate, and up to about 15 percent by weight of a vinyl monomer. Preferably, the vinyl ester resin has a molecular weight ranging from about 450 to 1500.
1. A laminating resin composition comprising an unsaturated polyester resin which is formed from the reaction product of an polybasic acid or anhydride and an alcohol, a vinyl ester resin formed from the reaction product of an unsaturated monocarboxylic acid and an epoxy resin, having more than one vicinal epoxy group per molecule from about 1 to less than 15 percent by weight of a polyfunctional acrylate compound, and less than about 15 percent by weight of a vinyl monomer.
2. The laminating resin composition according to claim 1 wherein said unsaturated polyester resin has a weight average molecular weight ranging from about 300 to 2000.
3. The laminating resin composition according to claim 1 wherein said vinyl ester resin has a weight average molecular weight ranging from about 450 to 1500.
4. The laminating resin composition according to claim 1 wherein said polyfunctional acrylate is selected from the group consisting of ethylene glycol dimethacrylate, butanediol dimethacrylate, trimethylol propane trimethacrylate, and mixtures thereof.
5. The laminating resin composition according to claim 1 wherein said vinyl monomer is selected from the group consisting of styrene and vinyl toluene.
6. The laminating resin composition according to claim 1 further comprising a dicyclopentadiene resin.
7. The laminating resin composition according to claim 1 wherein the vinyl monomer comprises hydroxypropyl methacrylate.
8. The laminating resin composition according to claim 1 wherein said unsaturated polyester resin comprises a component selected from the group consisting of acrylic acid, methacrylic acid, cinnamyl alcohol, crotonic acid, cinnamic acid, sorbic acid, maleic acid, fumaric acid, itaconic acid, benzoic acid, benzyl alcohol, cyclohexanol, 2-ethyl hexanol, trimethylol propane diallyl ether, and mixtures thereof.