Process for the oligomerization of α-olefins having low unsaturation, the resulting polymers, and lubricants containing same
View Patent ↗A poly(α-olefin) copolymer obtained from the polymerization of at least one α-olefin having from 2 to about 20 carbon atoms and at least one bulky olefin, the process comprising polymerizing the monomers in the presence of hydrogen and a catalytically effective amount of a catalyst comprising the product obtained by combining a metallocene procatalyst with a cocatalyst; lubricant compositions comprising such poly(α-olefin) copolymer; and a method for improving the viscosity index of a lubricant composition using such poly(α-olefin) copolymer.
1. A lubricant composition comprising a lubricant and a viscosity-modifyng amount of a poly(α-olefin) copolymer obtained from the polymerization of at least one α-olefin having from 2 to about 20 carbon atoms and at least one bulky olefin, the process comprising polymerizing the monomers in the presence of hydrogen and a catalytically effective amount of a catalyst comprising the product obtained by combining a metallocene procatalyst with a cocatalyst, the metallocene procatalyst being at least one compound of general formula:
(Cp 1 R 1 m )R 3 (Cp 2 R 2 p )MX q
wherein Cp 1 of ligand (Cp 1 R 1 m ) and Cp 2 of ligand (Cp 2 R 2 p ) are the same or different cyclopentadienyl rings, R 1 and R 2 each is, independently, hydrogen or a hydrocarbyl, halocarbyl, hydrocarbyl-substituted organometalloid or halocarbyl-substituted organometalloid group containing up to about 20 carbon atoms, m is 0 to 5, p is 0 to 5 and two R 1 and/or R 2 substituents on adjacent carbon atoms of the cyclopentadienyl ring associated therewith can be joined together to form a ring fused to the cyclopentadienyl ring, the fused ring containing from 4 to about 20 carbon atoms, R 3 is a bridging group bridging Cp 1 and Cp 2 , M is a transition metal having a valence of from 3 to 6, each X is a non-cyclopentadienyl ligand and is, independently, halogen or a hydrocarbyl, oxyhydrocarbyl, halocarbyl, hydrocarbyl-substituted organometalloid, oxyhydrocarbyl-substituted organometalloid or halocarbyl-substituted organometalloid group containing up to about 20 carbon atoms, q is equal to the valence of M minus 2, the cocatalyst being an aluminoxane and it being provided that ligand (Cp 1 R 1 m ) is different from ligand (Cp 2 R 2 p ) and bridging group R 3 contains at least two bulky groups; wherein the poly(α-olefin) possesses a M w of from about 500 to about 80,000, a M w /M n of from about 1.0 to about 10, a KV 100 of from about 10 to about 10,000, an Iodine Number of from about 0.0 to about 10 and a T g of below about −20° C. and wherein the poly(α-olefin) is substantially amorphous.
2. The lubricant composition of claim 1 wherein in the metallocene procatalyst, ligand (Cp 1 R m 1 ) is unsubstituted cyclopentadienyl, ligand (Cp 2 R p 2 ) is substituted or unsubstituted indenyl or fluorenyl, M 1 is zirconium, R 4 and R 5 each is phenyl and each ligand X is chlorine.
3. The lubricant composition of claim 1 wherein the bulky olefin is selected from the group consisting of cyclic and polycyclic olefins of the structural formulae:
wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , and R 8 are identical or different and are selected from the group consisting of hydrogen, C 6 –C 16 aryl moieties, and C 1 –C 8 alkyl moieties, it being possible for identical radicals in the different formulae to have different meanings.
4. The lubricant composition of claim 1 wherein the α-olefin is 1-decene and the bulky olefin is norbornene.
5. The lubricant composition of claim 1 wherein polymerization is carried out under slurry polymerization conditions.
6. The lubricant composition of claim 1 wherein the poly(α-olefin) possesses a M w of from about 750 to about 60,000, a M w /M n of from about 1.5 to about 5, a KV 100 of from about 20 to about 7,500, an Iodine Number of from about 0.1 to about 5 and a T g of below about −30° C.