Cryomilled aluminum alloys and components extruded and forged therefrom
View Patent ↗High strength aluminum alloy powders, extrusions, and forgings are provided in which the aluminum alloys exhibit high strength at atmospheric temperatures and maintain high strength and ductility at extremely low temperatures. The alloy is produced by blending about 89 atomic % to 99 atomic % aluminum, 1 atomic % to 11 atomic % of a secondary metal selected from the group consisting of magnesium, lithium, silicon, titanium, zirconium, and combinations thereof, and up to about 10 atomic % of a tertiary metal selected from the group consisting of Be, Ca, Sr, Ba, Ra, Sc, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, W, and combinations thereof. The alloy is produced by nanostructure material synthesis, such as cryomilling, in the absence of refractory dispersoids. The synthesized alloy is then canned, degassed, consolidated, extruded, and optionally forged into a solid metallic component. Grain size within the alloy is less than 0.5 μm, and alloys with grain size less than 0.1 μm may be produced.
1. A cryomilled aluminum alloy comprising:
89 atomic % to 99 atomic % aluminum;
1 atomic % to 11 atomic % of a secondary metal selected from the group consisting of magnesium, lithium, silicon, titanium, zirconium, and combinations thereof; and
at least 0.3% nitrogen by weight that is in the form of aluminum nitride and one or more of magnesium nitride, lithium nitride, silicon nitride, titanium nitride, zirconium nitride, and combinations thereof,
wherein the alloy has an average grain size of less than 0.5 μm, and wherein the alloy is cryomilled in a substantially oxygen free atmosphere so that the alloy is substantially free of oxy-nitrides, oxides, and combinations thereof.
2. The aluminum alloy of claim 1 , wherein the secondary metal is magnesium.
3. The aluminum alloy of claim 2 , wherein the magnesium is present in an amount of 4 weight % to 10 weight % of the alloy.
4. The aluminum alloy of claim 3 , and further comprising a tertiary metal selected from the group consisting of zinc, copper, cobalt, zirconium, and nickel.
5. The aluminum alloy of claim 4 , comprising 6 weight % to 9 weight % zinc, less than 2 weight % copper, less than 2 weight % cobalt, less than about 0.2 weight % zirconium, and less than about 0.2 weight % nickel.
6. The aluminum alloy of claim 1 , wherein the alloy has a stable grain structure up to at least 850° F.
7. The aluminum alloy of claim 1 , wherein the alloy is in the form of an extrusion.
8. The aluminum alloy of claim 1 , wherein the alloy is in the form of a forging.
9. The aluminum alloy of claim 1 , wherein the alloy comprises less than about 0.5 volume % refractory material.
10. A cryomilled aluminum alloy consisting essentially of:
89 atomic % to 99 atomic % aluminum;
1 atomic % to 11 atomic % of a secondary metal selected from the group consisting of magnesium, lithium, silicon, titanium, zirconium, and combinations thereof; and
at least 0.3% by weight of nitrogen that is in the form of aluminum nitride and one or more of magnesium nitride, lithium nitride, silicon nitride, titanium nitride, zirconium nitride, and combinations thereof, and wherein the alloy is cryomilled in a substantially oxygen free atmosphere so that the alloy is substantially free of oxy-nitrides, oxides, and combinations thereof, and wherein the alloy is substantially free of refractory materials, and wherein the alloy has an average grain size of less than 0.5 μm.