Coated luminescent material and light-emitting device having such a luminescent material
View Patent ↗A coated luminescent material having a luminescent material powder formed by grains, the luminescent grains being coated, and the coating being at most 5 nm, preferably at most 2 nm.
1. A light-emitting device, having at least one radiation source which emits essentially within the range of from 150 to 600 nm, and a luminescent material which converts the light from the radiation source at least partially into longer-wave radiation, the luminescent material being formed by particles which are coated by a coating layer, wherein a coating material for the coating layer is selected from at least one of the following groups:
alkylsilyl halides of the stoichiometry R 2 SiX 2 , wherein R=alkyl and X=Cl or Br;
arylsilyl halides of the stoichiometry Ar 3 SiX or Ar 2 SiX 2 , wherein Ar=phenyl and X=halogen;
phenyl-substituted silicon alkoxides;
alkyl halides of the type R—X, wherein R=aliphatic residue and X=halogen; and
acyl halides of the type
wherein R=aliphatic residue and X=halogen.
2. The light-emitting device as claimed in claim 1 , wherein the coating layer has a thickness of at most 5 nm.
3. The light-emitting device as claimed in claim 2 , wherein the coating layer has a thickness of less than or equal to 3 nm.
4. The light-emitting device as claimed in claim 1 , wherein the luminescent material is selected from the group: garnets, chlorosilicates, thiogallates and aluminates, nitridosilicates and vanadates.
5. The light-emitting device as claimed in claim 4 , wherein the luminescent material contains rare earth metals as constituents.
6. The light-emitting device as claimed in claim 2 , wherein the coating layer thickness is between 0.1 and 2 nm.
7. The light-emitting device as claimed in claim 2 , wherein a second layer of flame-hydrolytically produced metal oxides is applied to the coating layer.
8. The light-emitting device as claimed in claim 1 , wherein the radiation source is a UV-emitting LED, which emits with a peak wavelength in the range from 300 to 420 nm.
9. The light-emitting device as claimed in claim 1 , wherein the radiation source is a blue-emitting LED, which emits with a peak wavelength in the range of from 425 to 490 nm.
10. The light-emitting device as claimed in claim 1 , wherein the radiation source is a high-pressure discharge lamp, which emits essentially in the range of from 200 to 490 nm.
11. The light-emitting device as claimed in claim 1 , wherein the radiation source is an excimer discharge device, which emits essentially in the range of from 150 to 320 nm.
12. The light-emitting device as claimed in claim 1 , wherein in R—X, X=Cl or Br.
13. The light-emitting device as claimed in claim 1 , wherein in
X=Cl or Br.