Coated article with zinc oxide over IR reflecting layer and corresponding method
View Patent ↗A coated article is provided that may be heat treated in certain example embodiments. A coating of the coated article includes a zinc oxide inclusive layer located over and contacting a contact layer that is in contact with an infrared (IR) reflecting layer of a material such as silver. It has been found that the use of such a zinc oxide inclusive layer results in improved thermal stability upon heat treatment, more neutral and/or desirable coloration, lower sheet resistance (R s ), and/or lower emissivity.
1. A coated article comprising a coating supported by a glass substrate, the coating comprising:
a dielectric layer comprising titanium oxide having a refractive index of at least 2.0 on and directly contacting the glass substrate;
a layer comprising silicon nitride provided over and contacting the dielectric layer;
a first layer comprising zinc oxide located over and contacting the layer comprising silicon nitride;
an infrared (IR) reflecting layer comprising silver located over and contacting the first layer comprising zinc oxide;
a layer comprising an oxide of NiCr located over and contacting the IR reflecting layer;
a second layer comprising zinc oxide located over and contacting the layer comprising the oxide of NiCr;
another dielectric layer comprising silicon nitride located over the second layer comprising zinc oxide; and
wherein a dielectric layer stack between the glass substrate and the IR reflecting layer consists essentially of (a) said dielectric layer comprising titanium oxide having the refractive index of at least 2.0 which contacts the glass substrate, (b) said layer comprising silicon nitride, and (c) said layer comprising zinc oxide which contacts the IR reflecting layer, so that said dielectric layer comprising titanium oxide contacts said layer comprising silicon nitride in said layer stack between the glass substrate and the IR reflecting layer.
2. The coated article of claim 1 , wherein at least one of the first and second layers comprising zinc oxide further comprises aluminum.
3. The coated article of claim 1 , wherein the coated article is heat treated.
4. The coated article of claim 1 , wherein the silicon nitride in the layer comprising silicon nitride located between the substrate and the first layer comprising zinc oxide is Si-rich so as to be represented by Si X N Y , where x/y is from 0.76 to 1.5.
5. The coated article of claim 1 , wherein the silicon nitride in the layer comprising silicon nitride located between the substrate and the first layer comprising zinc oxide is Si-rich so as to be represented by Si X N Y , where x/y is from 0.8 to 1.4.
6. The coated article of claim 1 , wherein the silicon nitride in the layer comprising silicon nitride located between the substrate and the first layer comprising zinc oxide comprises Si 3 N 4 .
7. The coated article of claim 1 , wherein the coating includes only one IR reflecting layer comprising silver.
8. The coated article of claim 1 , wherein the coated article is heat treated, and following heat treatment the coated article measured monolithically is characterized by the following:
transmissive a*:
−1.75 to 0
transmissive b*:
0 to 2.0
R s (ohms/square):
<=5.0.
9. The coated article of claim 1 , wherein the coated article is heat treated, and following heat treatment the coated article measured monolithically is characterized by the following:
visible transmission:
>=85%
transmissive a*:
−1.75 to 0
R s (ohms/square):
<=4.3.
10. The coated article of claim 1 , wherein the glass substrate and the coating are part of an IG window unit, wherein the IG window unit has a U-value of no greater than 1.25 W/(m 2 K).
11. The coated article of claim 1 , wherein the glass substrate and the coating are part of an IG window unit, wherein the IG window unit has a U-value of no greater than 1.15 W/(m 2 K).
12. The coated article of claim 1 , wherein the coated article is heat treated and has a Δa* value (transmissive) of no greater than 1.0 due to heat treatment.
13. The coated article of claim 1 , wherein the coated article is heat treated and has a Δa* value (transmissive) of no greater than 0.7 due to heat treatment.
14. A coated article comprising a coating supported by a glass substrate, the coating comprising:
a dielectric layer comprising titanium oxide having a refractive index of at least 2.0 on and directly contacting the glass substrate;
a layer comprising silicon nitride provided over the dielectric layer;
a first layer comprising zinc oxide located over the layer comprising silicon nitride;
an infrared (IR) reflecting layer comprising silver located over and contacting the first layer comprising zinc oxide;
a layer comprising an oxide of NiCr located over and contacting the IR reflecting layer;
a second layer comprising zinc oxide located over and contacting the layer comprising the oxide of NiCr;
another dielectric layer comprising silicon nitride located over the second layer comprising zinc oxide; and
wherein a dielectric layer stack between the glass substrate and the IR reflecting layer includes (a) said dielectric layer comprising titanium oxide having the refractive index of at least 2.0 which contacts the glass substrate, (b) said layer comprising silicon nitride,and c) said layer comprising zinc oxide which contacts the IR reflecting layer, wherein said dielectric layer comprising titanium oxide contacts said layer comprising silicon nitride in said layer stack between the glass substrate and the IR reflecting layer.
15. The coated article of claim 14 , wherein the coating includes only one IR reflecting layer comprising silver.