IP Library Granted Patent US 7,314,895
Granted Patent B2
US 7,314,895 · App. 10/794,306 · Granted Jan 1, 2008

Thermoplastic composition comprising a CO

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Quick Facts
Patent No.
US 7,314,895
App. No.
10/794,306
Granted
Jan 1, 2008
Kind
B2
Abstract

A composition comprising a thermoplastic and a CO 2 releasing material; wherein the CO 2 releasing material comprises: a) a carbon and oxygen containing salt of an alkali or alkaline earth metal; and b) an acid; the CO 2 releasing material has a sufficient amount and ratio of the carbon and oxygen containing salt of the alkali or alkaline earth metal and the acid so that, in the presence of water, the CO 2 releasing material reacts to release CO 2 gas through the thermoplastic into a surrounding environment.

Claims (53)

1. A method for releasing CO 2 into a surrounding environment, comprising:

exposing a CO 2 releasing composition to an elevated relative humidity environment; wherein the CO 2 releasing composition comprises: CO 2 releasing material blended with a thermoplastic, wherein the CO 2 releasing material comprises carbon and oxygen containing salt of an alkali or alkaline earth metal, and an acid;

reacting the CO 2 releasing composition with moisture from the elevated relative humidity environment; and

releasing a controlled amount of CO 2 gas through the thermoplastic into the surrounding environment, wherein the CO 2 releasing material has a sufficient amount and ratio of the carbon and oxygen containing salt of the alkali or alkaline earth metal and the acid so that, in the presence of moisture, the CO 2 releasing composition reacts to release CO 2 gas through the thermoplastic into a surrounding environment;

wherein the carbon and oxygen containing salt of an alkali or alkaline earth metal is a carbonate;

wherein the composition is in the form of a film, sheet, insert or liner; and

wherein the CO 2 releasing composition maintains a package environment for baked goods at a sufficient release rate of CO 2 to slow aerobic respiration of organisms that causes the baked good to become stale.

2. The method of claim 1 wherein an absorbing material is incorporated into The composition to absorb detrimental levels of moisture.

3. A method for releasing CO 2 into a surrounding environment, comprising:

exposing a CO 2 releasing composition to an elevated relative humidity environment; wherein the CO 2 releasing composition comprises: CO 2 releasing material blended with a thermoplastic, wherein the CO 2 releasing material comprises carbon and oxygen containing salt of an alkali or alkaline earth metal, and an acid;

reacting the CO 2 releasing composition with moisture from the elevated relative humidity environment; and

releasing a controlled amount of CO 2 gas through the thermoplastic into the surrounding environment, wherein the CO 2 releasing material has a sufficient amount and ratio of the carbon and oxygen containing salt of the alkali or alkaline earth metal and the acid so that, in the presence of moisture, the CO 2 releasing composition reacts to release CO 2 gas through the thermoplastic into a surrounding environment;

wherein the carbon and oxygen containing salt of an alkali or alkaline earth metal is a carbonate;

wherein the composition is in the form of a film, sheet, insert or liner; and

wherein the CO 2 releasing composition maintains a package environment for cut flowers at a sufficient release rate of CO 2 to maintain the green color of flower stems for at least 30 days.

4. A method for releasing CO 2 into a surrounding environment, comprising:

exposing a CO 2 releasing composition to an elevated relative humidity environment; wherein the CO 2 releasing composition comprises: CO 2 releasing material blended with a thermoplastic, wherein the CO 2 releasing material comprises carbon and oxygen containing salt of an alkali or alkaline earth metal, and an acid;

reacting the CO 2 releasing composition with moisture from the elevated relative humidity environment; and

releasing a controlled amount of CO 2 gas through the thermoplastic into the surrounding environment, wherein the CO 2 releasing material has a sufficient amount and ratio of the carbon and oxygen containing salt of the alkali or alkaline earth metal and the acid so that, in the presence of moisture, the CO 2 releasing composition reacts to release CO 2 gas through the thermoplastic into a surrounding environment;

wherein the carbon and oxygen containing salt of an alkali or alkaline earth metal is a carbonate;

wherein the composition is in the form of a film, sheet, insert or liner; and

wherein the CO 2 releasing composition maintains a package environment for fresh or frozen seafood so as to produce sufficient CO 2 to slow aerobic respiration while reducing anaerobic respiration.

5. The method of claim 4 wherein the CO 2 releasing composition maintains a package environment for fresh or frozen seafood above about 30% CO 2 with an ambient O 2 concentration of about 20% outside the package environment.

6. The method of claim 4 wherein the CO 2 releasing composition maintains a package environment for fresh or frozen seafood at an elevated CO 2 concentration of at least about 20% and the O 2 concentration at about 20%.

7. A method for releasing CO 2 into a surrounding environment, comprising:

exposing a CO 2 releasing composition to an elevated relative humidity environment; wherein the CO 2 releasing composition comprises: CO 2 releasing material blended with a thermoplastic, wherein the CO 2 releasing material comprises carbon and oxygen containing salt of an alkali or alkaline earth metal, and an acid;

reacting the CO 2 releasing composition with moisture from the elevated relative humidity environment; and

releasing a controlled amount of CO 2 gas through the thermoplastic into the surrounding environment, wherein the CO 2 releasing material has a sufficient amount and ratio of the carbon and oxygen containing salt of the alkali or alkaline earth metal and the acid so that, in the presence of moisture, the CO 2 releasing composition reacts to release CO 2 gas through the thermoplastic into a surrounding environment;

wherein the carbon and oxygen containing salt of an alkali or alkaline earth metal is a carbonate;

wherein the composition is in the form of a film, sheet, insert or liner; and

wherein a biologically active ingredient is incorporated into the composition.

8. A method for releasing CO 2 into a surrounding environment, comprising:

exposing a CO 2 releasing composition to an elevated relative humidity environment; wherein the CO 2 releasing composition comprises: CO 2 releasing material incorporated in a thermoplastic, wherein the CO 2 releasing material comprises carbon and oxygen containing salt of an alkali or alkaline earth metal, and an acid;

reacting the CO 2 releasing composition with moisture from the elevated relative humidity environment; and

releasing a controlled amount of CO 2 gas through the thermoplastic into the surrounding environment, wherein the CO 2 releasing material has a sufficient amount and ratio of the carbon and oxygen containing salt of the alkali or alkaline earth metal and the acid so that, in the presence of moisture, the CO 2 releasing composition reacts to release CO 2 gas though the thermoplastic into a surrounding environment;

wherein the carbon and oxygen containing salt of an alkali or alkaline earth metal is a carbonate;

wherein the composition is in the form of a film, sheet, insert or liner;

wherein a biologically active ingredient is incorporated into the composition; and

wherein the biologically active ingredient is chlorine dioxide and added in sufficient amounts with the CO 2 releasing material so as to produce a modified atmosphere of about 30% CO 2 , about 20% O 2 and about 50% N 2 for seafood.

9. A method for releasing CO 2 into a surrounding environment, comprising:

exposing a CO 2 releasing composition to an elevated relative humidity environment; wherein the CO 2 releasing composition comprises: CO 2 releasing material incorporated in a thermoplastic, wherein the CO 2 releasing material comprises carbon and oxygen containing salt of an alkali or alkaline earth metal, and an acid;

reacting the CO 2 releasing composition with moisture from the elevated relative humidity environment; and

releasing a controlled amount of CO 2 gas through the thermoplastic into the surrounding environment, wherein the CO 2 releasing material has a sufficient amount and ratio of the carbon and oxygen containing salt of the alkali or alkaline earth metal and the acid so that, in the presence of moisture, the CO 2 releasing composition reacts to release CO 2 gas through the thermoplastic into a surrounding environment;

wherein the carbon and oxygen containing salt of an alkali or alkaline earth metal is a carbonate;

wherein the composition is in the form of a film, sheet, insert or liner; and

wherein The CO 2 releasing composition is integrated into a CO 2 releasing film into a package with a barrier film having selective permeation to O 2 and CO 2 .

10. A method for releasing CO 2 into a surrounding environment, comprising:

exposing a CO 2 releasing composition to an elevated relative humidity environment; wherein the CO 2 releasing composition comprises: CO 2 releasing material incorporated in a thermoplastic, wherein the CO 2 releasing material comprises carbon and oxygen containing salt of an alkali or alkaline earth metal, and an acid;

reacting the CO 2 releasing composition with moisture from the elevated relative humidity environment; and

releasing a controlled amount of CO 2 gas through the thermoplastic into the surrounding environment, wherein the CO 2 releasing material has a sufficient amount and ratio of the carbon and oxygen containing salt of the alkali or alkaline earth metal and The acid so that, in the presence of moisture, the CO 2 releasing composition reacts to release CO 2 gas through the thermoplastic into a surrounding environment;

wherein the carbon and oxygen containing salt of an alkali or alkaline earth metal is a carbonate;

wherein the composition is in the form of a film, sheet, insert or liner; and

wherein the CO 2 releasing composition produces a sufficient amount of CO 2 in a film form so as to maintain a gas environment in the package of about 40% CO 2 , 40% nitrogen and 20% oxygen.

Assignments (8)
RELEASE OF SECURITY INTEREST Recorded Aug 31, 2018
From: BARCLAYS BANK PLC, AS ADMINISTRATIVE AGENT
To: CSP TECHNOLOGIES NORTH AMERICA, LLC (F/K/A CV HOLDINGS, L.L.C.); TOTAL INNOVATIVE PACKAGING, INC.; CAPITOL PLASTIC PRODUCTS, L.L.C.; CSP TECHNOLOGIES, INC.; CAPITOL CUPS, INC.; CV PARTNERS
Reel/Frame 046991/0095 →
SECURITY INTEREST Recorded Apr 13, 2015
From: CAPITOL CUPS, INC.; TOTAL INNOVATIVE PACKAGING, INC.; CSP TECHNOLOGIES NORTH AMERICA, LLC (F/K/A CV HOLDINGS, LLC); CAPITOL PLASTIC PRODUCTS, L.L.C.; CV PARTNERS
To: BARCLAYS BANK PLC, AS ADMINISTRATIVE AGENT
Reel/Frame 035421/0366 →
CHANGE OF NAME Recorded Mar 19, 2015
From: CV HOLDINGS, L.L.C.
To: CSP TECHNOLOGIES NORTH AMERICA, LLC
Reel/Frame 035225/0593 →
RELEASE OF SECURITY INTEREST Recorded Feb 26, 2015
From: CYPRIUM INVESTORS IV LP
To: CV HOLDINGS, L.L.C; CAPITOL CUPS, INC.; CAPITOL MEDICAL DEVICES, INC.; CAPITOL PLASTIC PRODUCTS, L.L.C.; CSP TECHNOLOGIES, INC.; CV PARTNERS; TOTAL INNOVATIVE PACKAGING, INC.
Reel/Frame 035105/0796 →
RELEASE OF SECURITY INTEREST Recorded Feb 26, 2015
From: GENERAL ELECTRIC CAPITAL CORPORATION
To: CV HOLDINGS, L.L.C; CAPITOL CUPS, INC.; CAPITOL MEDICAL DEVICES, INC.; CAPITOL PLASTIC PRODUCTS, L.L.C.; CSP TECHNOLOGIES, INC.; CV PARTNERS; TOTAL INNOVATIVE PACKAGING, INC.
Reel/Frame 035104/0430 →
SECURITY AGREEMENT Recorded Jan 10, 2014
From: CSP TECHNOLOGIES, INC.
To: CYPRIUM INVESTORS IV LP, AS ADMINISTRATIVE AGENT
Reel/Frame 031968/0321 →
RELEASE OF SECURITY INTERESTS IN PATENTS Recorded Sep 12, 2012
From: WELLS FARGO BANK, NATIONAL ASSOCIATION
To: CV HOLDINGS, L.L.C.; CAPITOL PLASTIC PRODUCTS, L.L.C.; CSP TECHNOLOGIES, INC.; CAPITOL MEDICAL DEVICES, INC. (F/K/A CAPITOL INSULATED PRODUCTS, INC.); CAPITOL CUPS, INC.; TOTAL INNOVATIVE PACKAGING, INC.
Reel/Frame 028948/0746 →
PATENT SECURITY AGREEMENT Recorded Sep 7, 2012
From: CSP TECHNOLOGIES, INC.
To: GENERAL ELECTRIC CAPITAL CORPORATION, AS AGENT
Reel/Frame 028912/0316 →