IP Library Granted Patent US 7,157,156
Granted Patent B2
US 7,157,156 · App. 10/804,960 · Granted Jan 2, 2007

Organic light emitting device having improved stability

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Quick Facts
Patent No.
US 7,157,156
App. No.
10/804,960
Granted
Jan 2, 2007
Kind
B2
Abstract

In an OLED device, the improvement including a reflective and conductive bilayer anode including a metal or metal alloy or both; a hole-injecting structure over the reflective and conductive bilayer anode; at least one organic layer formed over the hole-injecting structure; and the reflective and conductive bilayer anode being configured to improve the stability of drive voltage.

Claims (36)

1. In an OLED device, the improvement comprising:

(a) a reflective and conductive bilayer anode including a metal or metal alloy or both;

(b) a hole-injecting structure over the reflective and conductive bilayer anode;

(c) at least one organic layer formed over the hole-injecting structure;

(d) the reflective and conductive bilayer anode being configured to improve the stability of drive voltage; and

(e) wherein the reflective and conductive bilayer anode includes a base layer of a highly reflective metal and a thin surface layer including an alloy of the base layer or an alloy of a different highly reflective metal in contact with the hole-injecting structure, and the metals alloyed with the highly reflective metals in the thin surface layer are Ag, Au, Cu, Al, Mg, Zn, Rh, Ru, Ir, Pd, Ni, Cr, Pt, Co, Te, or Mo or combinations thereof.

2. The OLED device of claim 1 wherein the at least one organic layer includes an emissive layer and an electron transport layer.

3. The OLED device of claim 1 further including a reflective and conductive cathode and wherein the reflectance and the transmittance of the reflective and conductive bilayer anode, and the thickness of the at least one organic layer and the cathode are selected to change the internal reflection of light to thereby improve emission.

4. The OLED device of claim 3 further including an electron transport layer and the reflective and conductive cathode including a metal or metal alloy or both provided over the electron transport layer.

5. The OLED device of claim 1 wherein the highly reflective metal is Ag, Au, Cu, Al, Mg, Zn, Rh, Ru, or Ir or combinations thereof.

6. The OLED device of claim 1 wherein the hole-injecting structure includes one or more hole-injection layers.

7. The OLED device of claim 1 wherein the hole injection structure includes CF x , ITO, IZO, Pr 2 O 3 , TeO 2 , CuPc, SiO 2 , VO x , MoO x , or mixtures thereof.

8. The OLED device of claim 3 wherein the reflective and conductive cathode includes metal or metal alloys having a work function selected to be about 4.0 eV or less.

9. The OLED device of claim 8 wherein the metal or metal alloys include alloys of Ag or Al with Mg, alkali metals, alkali earth metals, or Mn.

10. The OLED device of claim 1 wherein the device emits light through the reflective and conductive bilayer anode.

11. The OLED device of claim 3 further including a transmissive cathode and wherein the device emits light through the transmissive cathode.

12. The OLED device of claim 1 wherein the reflective and conducting bilayer anode is semitransparent.

13. The OLED device of claim 3 wherein the reflective and conductive cathode is opaque.

14. The OLED device of claim 12 further includes a transparent substrate having a transmission enhancement layer between the transparent substrate and the reflective conductive and semitransparent bilayer anode.

15. The OLED device of claim 11 further includes a transmission enhancement layer over the transmissive cathode.

16. The OLED device of claim 14 wherein the transmission enhancement layer includes lTO, MgO, MoO x , SnO 2 , TiO 2 , Al 2 O 3 , SiO 2 , ZnO, ZrO 2 , Alq, NPB, SiN, AlN, TiN, SiC, Al 4 C 3 , or mixtures thereof.

17. The OLED device of claim 15 wherein the transmission enhancement layer includes ITO, MgO, MoO x , SnO 2 , TiO 2 , Al 2 O 3 , SiO 2 , ZnO, ZrO 2 , Alq, NPB, SiN, AlN, TiN, SiC, Al 4 C 3 , or mixtures thereof.

18. The OLED device claim 14 wherein the thickness of the transmission enhancement layer is a range from 20 nm to 150 nm.

19. The OLED device claim 15 wherein the thickness of the transmission enhancement layer is a range from 20 nm to 150 nm.

20. In an OLED device, the improvement comprising:

(a) a reflective and conductive bilayer anode including a metal or metal alloy or both;

(b) a hole-injecting structure over the reflective and conductive bilayer anode;

(c) at least one organic layer formed over the hole-injecting structure;

(d) the reflective and conductive bilayer anode being configured to improve the stability of drive voltage; and

(e) a reflective and conductive opaque cathode and wherein the reflectance and the transmittance of the reflective and conductive bilayer anode, and the thickness of the at least one organic layer and the cathode are selected to change the internal reflection of light to thereby improve emission.

21. In an OLED device, the improvement comprising:

(a) a reflective and conductive bilayer semi-transparent anode including a metal or metal alloy or both;

(b) a hole-injecting structure over the reflective and conductive bilayer anode;

(c) at least one organic layer formed over the hole-injecting structure;

(d) the reflective and conductive bilayer anode being configured to improve the stability of drive voltage; and

(e) a transparent substrate having a transmission enhancement layer between the transparent substrate and the reflective conductive and semitransparent bilayer anode and wherein the transmission enhancement layer includes ITO, MgO, MoO x , SnO 2 , TiO 2 , Al 2 O 3 , SiO 2 , ZnO, ZrO 2 , Alq, NPB, SiN, AIN, TiN, SiC, Al 4 C 3 , or mixtures thereof.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 26, 2010
From: EASTMAN KODAK COMPANY
To: GLOBAL OLED TECHNOLOGY LLC
Reel/Frame 023998/0368 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 19, 2004
From: RAYCHAUDHURI, PRANAB K.; MADATHIL, JOSEPH K.; LIAO, LIANG-SHENG
To: EASTMAN KODAK COMPANY
Reel/Frame 015124/0066 →