IP Library Granted Patent US 7,393,592
Granted Patent B2
US 7,393,592 · App. 10/809,259 · Granted Jul 1, 2008

Lamination grade coextruded heat-sealable film

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Quick Facts
Patent No.
US 7,393,592
App. No.
10/809,259
Granted
Jul 1, 2008
Kind
B2
Abstract

A coextruded, heat-sealable film structure includes a core layer of a thermoplastic polymer having a first side and a second side. A functional layer which is printable, sealable, or can be laminated or is treatable for printing, sealing, or laminating is on the first side of the core layer. A heat-sealable layer is on the second side of the core layer. The heat-sealable layer is composed of a thermoplastic polymer and an amount of a slip system, based upon the entire weight of the heat-sealable layer, sufficient to reduce the coefficient of friction and improve the slip performance of the film structure. The slip system is composed of a silicone gum and at least one antiblocking agent. The film structure exhibits the desirable combination of improved converting performance and excellent machinability performance.

Claims (49)

1. A laminate film structure, comprising a first film laminated to a second film, wherein the first film is a heat-sealable film structure comprising:

(a) a core layer comprising a thermoplastic polymer, the core layer having a first side and a second side;

(b) a functional layer on the first side of the core layer, wherein the functional layer is selected from the group consisting of a laminating layer, a printable layer, a laminating and a printable layer, and a sealable layer; and

(c) a heat-sealable layer on the second side of the core layer comprising (i) a thermoplastic polymer and (ii) a slip system comprising a silicone gum having a viscosity in the range of 10 to 20 million centistokes present in amount from about 0.2 wt. % to about 2.0 wt. % of the heat-sealable layer and at least one antiblocking agent present in an amount from about 0.05 wt. % to about 0.5 wt. % of the heat-sealable layer;

(d) wherein the second film is comprised of the same structure as the first film.

2. A laminate film structure, comprising a first film laminated to a second film, wherein the first film is a heat-sealable film structure comprising:

(a) a core layer comprising a thermoplastic polymer, the core layer having a first side and a second side;

(b) a functional layer on the first side of the core layer, wherein the functional layer is selected from the group consisting of a laminating layer, a printable layer, a laminating and a printable layer, and a sealable layer; and

(c) a heat-sealable layer on the second side of the core layer comprising (i) a thermoplastic polymer and (ii) a slip system comprising a silicone gum having a viscosity in the range of 10 to 20 million centistokes present in amount from about 0.2 wt. % to about 2.0 wt. % of the heat-sealable layer and at least one antiblocking agent present in an amount from about 0.05 wt. % to about 0.5 wt. % of the heat-sealable layer,

(d) wherein the antiblocking agent is a particulate antiblocking agent having an avenge particle size of from about 1 to about 5 μm.

3. A coextruded heat-sealable film structure, comprising:

(a) a core layer comprising a thermoplastic polymer, the core layer having a first side and a second side;

(b) a functional layer on the first side of the core layer, wherein the functional layer is selected from the group consisting of a laminating layer, a printable layer, a laminating and a printable layer, and a sealable layer; and

(c) a heat-sealable layer on the second side of the core layer comprising (i) a thermoplastic polymer and (ii) a slip system comprising a silicone gum having a viscosity in the range of 10 to 20 million centistokes present in amount from about 0.2 wt. % to about 2.0 wt. % of the heat-sealable layer and at least one antiblocking agent present in an amount from about 0.05 wt. % to about 0.5 wt. % of the heat-sealable layer;

(d) wherein the core layer has a polymeric matrix selected from the group consisting of a ethylene propylene copolymer, propylene butylene copolymer, and a high density polyethylene; and

(e) wherein the heat-sealable layer is comprised of a material selected from the group consisting of ethylene vinyl acetate, ethylene-methyl acrylate, an ionomer, and blends thereof.

4. A coextruded heat-sealable film structure, comprising:

(a) a core layer comprising a thermoplastic polymer, the core layer having a first side and a second side;

(b) a functional layer on the first side of the core layer, wherein the functional layer is selected from the group consisting of a laminating layer, a printable layer, a laminating and a printable layer, and a sealable layer; and

(c) a heat-sealable layer on the second side of the core layer comprising (i) a thermoplastic polymer and (ii) a slip system comprising a silicone gum having a viscosity in the range of 10 to 20 million centistokes present in amount from about 0.2 wt. % to about 2.0 wt. % of the heat-sealable layer and at least one antiblocking agent present in an amount from about 0.05 wt. % to about 0.5 wt. % of the heat-sealable layer;

(d) wherein the core layer has a polymeric matrix selected from the group consisting of a ethylene propylene copolymer, propylene butylene copolymer, and a high density polyethylene; and

(e) wherein the core layer comprises a cavitating agent selected from the group consisting of polybutylene terephthalate, calcium carbonate, and blends thereof.

5. The coextruded heat-sealable film structure of claim 4 , wherein the functional layer comprises a material selected from the group consisting of an ethylene vinyl alcohol copolymer, a propylene-butylene copolymer, an ethylene vinyl acetate, an ethylene-methyl acrylate, and blends thereof.

6. The coextruded heat-sealable film structure of claim 4 , wherein the antiblocking agent is selected from the group consisting of cross linked silicone resin powder, methyl methacrylate resin powder, a spherical silica powder, and blends thereof.

7. A laminate film structure, comprising a first film laminated to a second film, wherein the first film is a heat-sealable film structure comprising:

(a) a core layer comprising a thermoplastic polymer, the core layer having a first side and a second side;

(b) a functional layer on the first side of the core layer, wherein the functional layer is selected from the group consisting of a laminating layer, a printable layer, a laminating and a printable layer, and a sealable layer; and

(c) a heat-sealable layer on the second side of the core layer comprising (i) a thermoplastic polymer and (ii) a slip system comprising a silicone gum having a viscosity in the range of 10 to 20 million centistokes present in amount from about 0.2 wt. % to about 2.0 wt. % of the heat-sealable layer and at least one antiblocking agent present in an amount from about 0.05 wt. % to about 0.5 wt. % of the heat-scalable layer;

(d) wherein the core layer has a polymeric matrix selected from the group consisting of a propylene homopolymer, a propylene copolymer, and a polyethylene.

8. The laminate film structure of claim 7 , wherein the core layer further comprises an additive selected from the group consisting of a natural hydrocarbon additive, a synthetic hydrocarbon additive, a cavitating agent, an antistatic agent, and mixtures thereof.

9. The laminate film structure of claim 7 , wherein the functional layer further comprises at least one antiblock additive.

10. The laminate film structure of claim 7 , wherein the surface of the functional layer is flame treated or corona treated and the surface of the heat-sealable layer is untreated.

11. The laminate film structure of claim 7 , wherein the thermoplastic polymer of the heat-sealable layer is selected from the group consisting of an ethylene-propylene random copolymer, a propylene-butylene random copolymer, an ethylene-propylene-butylene terpolymer, a linear low density polyethylene, a low density polyethylene, a metallocene-catalyzed polyethylene, an ethylene vinyl acetate, an ethylene-methyl acrylate, an ionomer, and blends thereof and the functional layer has a polymeric matrix selected from the group consisting of a propylene polymer, an ethylene-propylene block copolymer, a high density polyethylene, an ethylene vinyl alcohol copolymer, an ethylene-propylene random copolymer, a propylene-butylene copolymer, an ethylene-propylene-butylene terpolymer, a medium density polyethylene, a linear low density polyethylene, an ethylene vinyl acetate, an ethylene-methyl acrylate, and blends thereof.

12. A laminate film structure, comprising a first film laminated to a second film, wherein the first film is a heat-sealable film structure comprising:

(a) a core layer comprising a thermoplastic polymer, the core layer having a first side and a second side;

(b) a functional layer on the first side of the core layer, wherein the functional layer is selected from the group consisting of a laminating layer, a printable layer, a laminating and a printable layer, and a sealable layer; and

(c) a heat-sealable layer on the second side of the core layer comprising (i) a thermoplastic polymer and (ii) a slip system comprising a silicone gum having a viscosity in the range of 10 to 20 million centistokes present in amount from about 0.2 wt. % to about 2.0 wt. % of the heat-sealable layer and at least one antiblocking agent present in an amount from about 0.05 wt. % to about 0.5 wt. % of the heat-sealable layer

(d) wherein the core layer has a polymeric matrix selected from the group consisting of an ethylene propylene copolymer, propylene butylene copolymer, and a high density polyethylene.

13. The laminate film structure of claim 12 , wherein the thermoplastic polymer of the heat-sealable layer is selected from the group consisting of a propylene-butylene random copolymer, a metallocene catalyzed polyethylene, an ethylene vinyl acetate, and an ethylene-methyl acrylate, an ionomer, and blends thereof.

14. The laminate film structure of claim 12 , wherein the core layer comprises a cavitating agent selected from the group consisting of polybutylene terephtalate, calcium carbonate, and blends thereof.

15. The laminate film structure of claim 12 , wherein the care layer is from about 5 to about 50 μm thick, the functional layer is from about 0.25 to about 3.0 μm thick, and the heat-sealable layer is from about 0.5 to about 7 μm thick.

16. The laminate film structure of claim 12 , wherein the core layer is free of an antistatic agent and a fatty acid amide slip additive.

17. A coextruded heat-sealable film structure, comprising:

(a) a core layer comprising a thermoplastic polymer, the core layer having a first side and a second side;

(b) a functional layer on the first side of the core layer, wherein the functional layer is selected from the group consisting of a laminating layer, a printable layer, a laminating and a printable layer, and a sealable layer; and

(c) a heat-sealable layer on the second side of the core layer comprising (i) a thermoplastic polymer and (ii) a slip system comprising a silicone gum having a viscosity in the range of 10 to 20 million centistokes present in amount from about 0.2 wt. % to about 2.0 wt. % of the heat-sealable layer and at least one antiblocking agent present in an amount from about 0.05 wt. % to about 0.5 wt. % of the heat-sealable layer;

(d) wherein the core layer has a polymeric matrix selected from the group consisting of a ethylene propylene copolymer, propylene butylene copolymer, and a high density polyethylene; and

(e) wherein the functional layer is comprised of a material selected from the group consisting of ethylene vinyl acetate, ethylene-methyl acrylate, ethylene vinyl alcohol copolymer, propylene-butylene copolyrner, and blends thereof.

18. The coextruded heat-sealable film structure of claim 17 , wherein the heat-sealable layer is comprised of a material selected from the group consisting of ethylene vinyl acetate, ethylene-methyl acrylate, an ionomer, and blends thereof.

Assignments (6)
RELEASE OF SECURITY INTEREST Recorded Jun 17, 2021
From: BANK OF AMERICA, N.A., AS AGENT
To: JINDAL FILMS AMERICAS LLC
Reel/Frame 056616/0092 →
SECURITY INTEREST Recorded Sep 4, 2018
From: JINDAL FILMS AMERICAS LLC
To: BANK OF AMERICA, N.A., AS AGENT
Reel/Frame 047570/0731 →
CHANGE OF NAME Recorded Feb 12, 2014
From: FILMS AMERICAS, LLC
To: JINDAL FILMS AMERICAS LLC
Reel/Frame 032200/0782 →
PURCHASE OF FILMS AMERICAS, LLC Recorded Jan 16, 2014
From: EXXONMOBIL OIL CORPORATION
To: JPF USA LLC
Reel/Frame 032070/0888 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 2, 2014
From: EXXONMOBIL OIL CORPORATION
To: FILMS AMERICAS, LLC
Reel/Frame 031881/0351 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 4, 2004
From: SHEPPARD, KAREN A.; MIGLIORINI, ROBERT A.
To: EXXONMOBIL OIL CORPORATION
Reel/Frame 014596/0148 →