Papers for liquid electrophotographic printing and method for making same
The specification discloses papers suitable for liquid electrophotographic printing (“LEP”) and a method for making such papers. According to the method, a papermaking furnish containing cellulosic fibers is formed into a fibrous web on a papermaking machine and at least partially dried. The web is then treated with a sizing composition comprising starch, an acrylic acid polymer, an organic material having an HLB value of from about 2 to about 14 such as a polyglycerol ester, and water. The treated web is dried and calendered to a final desired caliper. Since the sizing composition is an aqueous mixture, it may be applied to the web on-line during production of the paper on the papermaking machine, thereby avoiding the expense and inconvenience of conventional off-line methods used to make existing LEP papers. The resulting paper exhibits at least 80% and preferably above 90% toner adhesion as measured by the tape pull tests used for the assessment of papers printed by LEP.
1. A paper suitable for liquid electrophotographic printing, comprising:
a web of cellulosic fibers; and
a composition comprising from about 40 to about 80 wt % of starch based upon the total weight of solids of the composition, about 20 to about 60 wt % of no more than one sizing agent based upon the total solids of the composition, said sizing agent consisting of an acrylic acid polymer, and from about 0.5 to about 7 wt % of an organic material comprising at least one polyglycerol ester and having an HLB value of from 2 to 14 based upon the total weight of solids of the composition, wherein
from 30 to 150 dry lbs of the composition are located in the web per dry ton of web; or
from 30 to 150 dry lbs of the composition are located on the web and in the web per dry ton of web.
2. The paper according to claim 1 , wherein the starch comprises corn starch.
3. The paper according to claim 1 , wherein the starch comprises anionic starch.
4. The paper according to claim 1 , wherein the composition comprises from about 0.5 to about 1.5 wt % of the organic material having an HLB value of from 2 to 14 based upon the total weight of solids of the composition.
5. The paper according to claim 1 , wherein the acrylic acid polymer comprises ethylene acrylic acid co-polymer.
6. The paper according to claim 1 , wherein the polyglycerol ester is at least one member selected from the group consisting of decaglyceryl hexaoleate, decaglyceryl decaoleate, glyceryl tricaprylate, and glyceryl tricaprate, and a mixture thereof.
7. The paper according to claim 1 , wherein the polyglycerol ester is decaglyceryl hexaoleate.
8. The paper according to claim 1 , wherein the web has a basis weight of from about 75 to about 300 gsm.
9. The paper according to claim 1 , wherein the web has a caliper of from about 5 to about 20 mils.
10. A method of making a paper suitable for liquid electrophotographic printing, comprising
providing a papermaking furnish containing cellulosic fibers, forming a fibrous web from the papermaking furnish,
at least partially drying the web;
treating the web with from about 30 to about 150 lbs/ton of web of a composition comprising from about 40 to about 80 wt % of starch based upon the total weight of solids of the composition; from about 20 to about 60 wt % of no more than one sizing agent based upon the total weight of solids of the composition, said sizing agent consisting of an acrylic acid polymer; from about 0.5 to about 7 wt %, of an organic material comprising at least one polyglycerol ester and having an HLB value of from 2 to 14 based upon the total weight of solids of the composition; and water.
11. The method according to claim 10 , wherein the starch comprises corn starch.
12. The method according to claim 10 , wherein the starch comprises anionic starch.
13. The method according to claim 10 , wherein the composition comprises from about 0.5 to about 1.5 wt % of the organic material having an HLB value of from 2 to 14 based upon the total weight of solids of the composition.
14. The method according to claim 10 , wherein the acrylic acid polymer comprises ethylene acrylic acid co-polymer.
15. The method according to claim 10 , wherein the polyglycerol ester is at least one member selected from the group consisting of decaglyceryl hexaoleate, decaglyceryl decaoleate, glyceryl tricaprylate, and glyceryl tricaprate, and a mixture thereof.
16. The method according to claim 10 , wherein the polyglycerol ester is decaglyceryl hexaoleate.
17. The method according to claim 10 , wherein the composition, as applied to the web, comprises from about 6 to about 10 wt % solids.
18. The method according to claim 10 , wherein the composition, as applied to the web, has a Brookfield viscosity of from about 10 to about 300 cp using a No. 2 spindle operating at 50 rpms and a fluid temperature of 65° C.
19. The method according to claim 10 , further comprising calendering the web.
20. The method according to claim 10 , wherein the web is treated with the composition at a size press.
21. The method according to claim 10 , wherein at least one surface of the web is treated with the composition.
22. A paper suitable for liquid electrophotographic printing, comprising:
a web of cellulosic fibers; and
a composition comprising from about 40 to about 80 wt % of starch based upon the total weight of solids of the composition, no more than one sizing agent, said sizing agent consisting of an acrylic acid polymer, and from about 0.5 to about 7 wt % of an organic material based upon the total weight of solids of the composition wherein the organic material has an HLB value of from 2 to 14 and comprises decaglyceryl hexaoleate, wherein
from 30 to 150 dry lbs of the composition are located in the web per dry ton of web; or
from 30 to 150 dry lbs of the composition are located on the web and in the web per dry ton of web.
23. The paper according to claim 22 , wherein the starch comprises corn starch.
24. The paper according to claim 22 , wherein the starch comprises anionic starch.
25. The paper according to claim 22 , wherein the composition comprises from about 0.5 to about 1.5 wt % of the organic material based upon the total weight of solids of the composition, wherein the organic material has an HLB value of from 2 to 14 and comprises decaglyceryl hexaoleate.
26. The paper according to claim 22 , wherein the acrylic acid polymer comprises ethylene acrylic acid co-polymer.
27. The paper according to claim 22 , wherein the web has a basis weight of from about 75 to about 300 gsm.
28. The paper according to claim 22 , wherein the web has a caliper of from about 5 to about 20 mils.
29. A method of making the paper according to claim 22 , comprising
providing a papermaking furnish containing cellulosic fibers,
forming a fibrous web from the papermaking furnish,
at least partially drying the web;
treating the web with from about 30 to about 150 lbs/ton of web of a composition comprising from about 40 to about 80 wt % of starch based upon the total weight of solids of the composition; no more than one sizing agent, said sizing agent consisting of an acrylic acid polymer; from about 0.5 to about 7 wt %, of a organic material based upon the total weight of solids of the composition wherein the organic material has an HLB value of from 2 to 14 and comprises decaglyceryl hexaoleate; and water.
30. The method according to claim 29 , wherein the starch comprises corn starch.
31. The method according to claim 29 , wherein the starch comprises anionic starch.
32. The method according to claim 29 , wherein the composition comprises from about 0.5 to about 1.5 wt % of the organic material having an HLB value of from 2 to 14 based upon the total weight of solids of the composition, wherein the organic material has an HLB value of from 2 to 14 and comprises decaglyceryl hexaoleate.
33. The method according to claim 29 , wherein the acrylic acid polymer comprises ethylene acrylic acid co-polymer.
34. The method according to claim 29 , wherein the composition, as applied to the web, comprises from about 6 to about 10 wt % solids.
35. The method according to claim 29 , wherein the composition, as applied to the web, has a Brookfield viscosity of from about 10 to about 300 cp using a No. 2 spindle operating at 50 rpms and a fluid temperature of 65° C.
36. The method according to claim 29 , wherein the web is treated with the composition at a size press.
37. The method according to claim 29 , wherein at least one surface of the web is treated with the composition.