Method of producing hollow alumina particle
View Patent ↗A method of producing hollow alumina particles in which the grain size of hollow alumina particles is controlled and in which a high formation ratio of hollow particles is obtained while suppressing the formation of solid particles. The method includes irradiating supersonic waves to an aqueous solution containing aluminum nitrate or aluminum acetate, and a surfactant or an organic acid to generate micro-liquid droplets in an atomized state, introducing only minute liquid droplets having a certain grain size or less, which have been classified by an air stream, into a furnace and burning them in air.
1. A method of producing hollow alumina particles comprising the steps of:
generating micro-liquid droplets in an atomized state from an aqueous solution containing one of aluminum nitrate and aluminum acetate and one of a surfactant and an organic acid by irradiating the aqueous solution with supersonic waves;
selecting the generated micro-liquid droplets having a predetermined grain size or less by classification with an air stream;
introducing the selected micro-liquid droplets into the furnace; and
burning the selected micro-liquid droplets in air.
2. A method of producing hollow alumina particles according to claim 1 , wherein the concentration of aluminum nitrate or aluminum acetate is from 0.1 to 1.0 M.
3. A method of producing hollow alumina particles according to claim 1 , wherein one of 0.0005 to 0.05 mol of the surfactant and 0.03 to 0.5 mol of the organic acid is added to one mol of one of aluminum nitrate and aluminum acetate.
4. A method of producing hollow alumina particles according to claim 1 , wherein the organic acid corresponds to one of citric acid, amino acid and maleic acid.
5. A method of producing hollow alumina particles according to claim 1 , wherein the surfactant corresponds to an olefinic polymer having a weight average molecular weight of from 2,500 to 6,000.
6. A method of producing hollow alumina particles according to claim 1 , wherein the resultant hollow alumina particles are further re-burned.