High melt flow rate thermoplastic polyolefins produced in-reactor
View Patent ↗A thermoplastic polyolefin having a melt flow rate of 20 dg/min or higher at 230° C. is produced in reactor without visbreaking. By controlling ratio of the weight average molecular weight of the xylene soluble fraction to the weight average molecular weight of the xylene insoluble fraction, a high melt flow thermoplastic polyolefin can be produced having a good balance of impact and stiffness, tensile elongation at break and gloss properties. Optionally, the ratio of the melt flow rate of the homopolymer phase to the melt flow rate of the total thermoplastic polyolefin can also be controlled. By compounding thermoplastic polyolefins according to the current invention with one or more modifiers, additional compositions can be produced having improved resistance to solvents.
1. A composition comprising:
a thermoplastic polyolefin produced by polymerizing propylene and optionally ethylene in a least one first polymerization reactor to form a propylene homopolymer or random copolymer; and
polymerizing ethylene and propylene in the presence of said propylene homopolymer or random copolymer in at least one subsequent polymerization reactor to form an ethylene/propylene rubber,
said thermoplastic polyolefin comprising,
about 60 percent to about 80 percent by weight of a xylene insoluble fraction comprising propylene homopolymer or random copolymer; and
about 20 percent to about 40 percent by weight of a xylene soluble fraction comprising ethylene/propylene rubber, said xylene soluble fraction containing from about 25 percent to about 45 percent by weight of ethylene; and
said thermoplastic polyolefin composition having a melt flow rate of at least 20 dg/min without visbreaking;
wherein the ratio r of the molecular weight of the xylene soluble fraction to the molecular weight of the xylene insoluble fraction is about 1.4 or less as measured by the equation:
r =Mw (XS) /Mw (XIS) where:
Mw (XS) is the weight average molecular weight (Mw) of said xylene soluble fraction, and
MW (XIS) is the weight average molecular weight (Mw) of said xylene insoluble fraction.
2. The composition according to claim 1 , wherein the ratio r of the molecular weight of the xylene soluble fraction to the molecular weight of the xylene insoluble fraction is from about 1 to about 1.4.
3. The composition according to claim 1 , wherein said thermoplastic polyolefin comprises:
about 70 percent to about 80 percent by weight of a xylene insoluble fraction, and about 20 percent to about 30 percent by weight of a xylene soluble fraction.
4. The composition according to claim 1 , wherein the composition is compounded with up to about 10 percent by weight of at least one impact modifier.
5. The composition according to claim 4 , wherein said at least one impact modifier is selected from the group consisting of: linear low density polyethylene, low density polyethylene, high density polyethylene, styrene-butadiene copolymer, styrene-isoprene copolymer, styrene-ethylene-butylene-styrene copolymer, styrene-ethylene-propylene-styrene copolymer and metallocene ethylene propylene copolymer.
6. The composition according to claim 1 , wherein said at least one first polymerization reactor is a liquid phase reactor and said at least one subsequent polymerization reactor is gas phase reactor.
7. The composition according to claim 1 , wherein said at least one first polymerization reactor and said at least one subsequent polymerization reactor are gas phase reactors.
8. The composition according to claim 1 , wherein the ratio, r′, of the melt flow rate of said polypropylene homopolymer or random copolymer to the melt flow rate of said thermoplastic polyolefin is from about 0.5 to about 2.2 as determined using the equation:
r =MFR homo MFR total where:
MFR homo is the melt flow rate of the polypropylene or random copolymer phase, and
MFR total is the melt flow rate of the total thermoplastic polyolefin.
9. The composition according to claim 1 , wherein propylene is polymerized in said at least one first polymerization reactor to form a propylene homopolymer.
10. The composition according to claim 9 , wherein the ratio r of the molecular weight of the xylene soluble fraction to the molecular weight of the xylene insoluble fraction is from about 1 to about 1.4.
11. The composition according to claim 9 , wherein said thermoplastic polyolefin comprises:
about 70 percent to about 80 percent by weight of a xylene insoluble fraction, and about 20 percent to about 30 percent by weight of a xylene soluble fraction.
12. The composition according to claim 9 , wherein the composition is compounded with further oomprising up to about 10 percent by weight of at least one impact modifier.
13. The composition according to claim 12 , wherein said at least one impact modifier is selected from the group consisting of: linear low density polyethylene, low density polyethylene, high density polyethylene, styrene-butadiene copolymer, styrene-isoprene copolymer, styrene-ethylene-butylene-styrene copolymer, styrene-ethylene-propylene-styrene copolymer and metallocene ethylene propylene copolymer.
14. The composition according to claim 9 , wherein said at least one first polymerization reactor is a liquid phase reactor and said at least one subsequent polymerization reactor is gas phase reactor.
15. The composition according to claim 9 , wherein said at least one first polymerization reactor and said at least one subsequent polymerization reactor are gas phase reactors.
16. The composition according to claim 1 , wherein
the ratio, r′, of the melt flow rate of said polypropylene homopolymer to the melt flow rate of said thermoplastic polyolefin is from about 0.5 to about 2.2 as determined using the equation:
r =MFR homo /MFR total where:
MFR homo is the melt flow rate of the polypropylene phase, and
MFRtotai is the melt flow rate of the total thermoplastic polyolefin.