Image recording material
View Patent ↗The infrared laser-compatible positive-type image recording materials according to the present invention include a support and a photo/thermosensitive layer formed on the support; and the photo/thermosensitive layer contains an alkali-soluble resin (A), a photothermal converting substance (B) and an ester compound (C) represented by the following General Formula (I), and increases solubility thereof to an alkaline developer as a result exposure to an infrared laser. In the following formula, R 1 represents a hydrocarbon group having a pKa of R 1 OH in a range of 3 to 10; and R 2 represents a hydrocarbon group or a substituted carbonyl group. The invention provides image recording materials compatible with high-output lasers that enable highly-sensitive direct plate making by using digital data from a computer or the like, and provide images excellent in development latitude, contrast, and resolution
1. An infrared laser-compatible positive-type image recording material comprising:
a support; and
a photo/thermosensitive layer formed on the support, wherein the photo/thermosensitive layer includes an alkali-soluble resin (A), a photothermal converting substance (B), and an ester compound (C) represented by the following Formula (I), and increases solubility thereof to an alkaline developer as a result of exposure to an infrared laser,
wherein, R 1 represents a hydrocarbon group having one or more electron-withdrawing substituents and a pKa of R 1 OH in a range of 3 to 10; and R 2 represents a hydrocarbon group or a substituted carbonyl group.
2. The infrared laser-compatible positive-type image recording material according to claim 1 , wherein the photo/thermosensitive layer comprises multiple layers.
3. The infrared laser-compatible positive-type image recording material according to claim 2 , wherein the ester compound (C) represented by Formula (I) is included in at least one of the multiple layers.
4. The infrared laser-compatible positive-type image recording material according to claim 2 , wherein the multiple photo/thermosensitive layers comprise a layer which is formed on the support and soluble in an alkaline developer, and a layer which is formed on the alkali-soluble layer and which is reactive to an infrared laser, and the ester compound (C) represented by Formula (I) is included in at least the alkali-soluble layer.
5. The infrared laser-compatible positive-type image recording material according to claim 1 , wherein the electron-withdrawing substituent is selected from a halogen atom, and cyano, nitro, carboxyl, substituted carbonyl (R 4 —C(═O)—), and substituted sulfonyl (R 5 —S(═O) 2 —) groups.
6. The infrared laser-compatible positive-type image recording material according to claim 1 , wherein the ester compound (C) represented by Formula (I) is a compound further represented by the following Formula (II),
wherein R 3 R 5 each represent a hydrogen atom or a hydrocarbon group.
7. The infrared laser-compatible positive-type image recording material according to claim 1 , wherein the ester compound (C) represented by Formula (I) is a compound further represented by the following Formula (III),
wherein Q 1 represents a hydrocarbon group, or a substituted oxy, substituted amino, or substituted thio group.
8. The infrared laser-compatible positive-type image recording material according to claim 6 , wherein the ester compound (C) represented by Formula (I) is a compound further represented by the following Formula (IV),
wherein R 3 to R 5 each represent a hydrogen atom or a hydrocarbon group; and Ar 1 represents an aryl group having a pKa of Ar 1 OH in a range of 3 to 10.
9. The infrared laser-compatible positive-type image recording material according to claim 7 , wherein the ester compound (C) represented by Formula (I) is a compound further represented by the following Formula (V),
wherein Q 1 represents a hydrocarbon group, or a substituted oxy, substituted amino, or substituted thio group; and Ar 1 represents an aryl group having a pKa of Ar 1 OH in a range of 3 to 10.
10. The infrared laser-compatible positive-type image recording material according to claim 1 , wherein the ester compound (C) represented by Formula (I) is added in an amount of 0.5 to 30.0% by mass with respect to a total amount of solid contents in the photo/thermosensitive layer.
11. An infrared laser-compatible positive-type image recording material comprising:
a support;
a first layer which is formed on the support and which is soluble in an alkaline developer; and
a second layer which is formed on the first layer and increases solubility thereof to the alkaline developer as a result of exposure to an infrared laser, wherein
at least one of the first and second layers includes an ester compound represented by the Formula (I),
wherein, R 1 represents a hydrocarbon group having one or more electron-withdrawing substituents and a pKa of R 1 OH in a range of 3 to 10; and R 2 represents a hydrocarbon or substituted carbonyl group.
12. The infrared laser-compatible positive-type image recording material according to claim 11 , wherein the ester compound represented by Formula (I) is included in the first layer, which is soluble in an alkaline developer.
13. The infrared laser-compatible positive-type image recording material according to claim 11 , wherein at least one layer of the first and second layers includes a photothermal converting substance.
14. The infrared laser-compatible positive-type image recording material according to claim 11 , wherein the electron-withdrawing substituent is selected from a halogen atom, and cyano, nitro, carboxyl, substituted carbonyl (R 4 —C(═O)—), and substituted sulfonyl (R 5 —S(═O) 2 —) groups.
15. The infrared laser-compatible positive-type image recording material according to claim 11 , wherein the ester compound represented by Formula (I) is a compound further represented by the following Formula (II),
wherein, R 1 represents a hydrocarbon group having one or more electron-withdrawing substituents and a pKa of R 1 OH in a range of 3 to 10; and
wherein R 3 to R 5 each represent a hydrogen atom or a hydrocarbon group.
16. The infrared laser-compatible positive-type image recording material according to claim 11 , wherein the ester compound represented by Formula (I) is a compound further represented by the following Formula (III),
wherein, R 1 represents a hydrocarbon group having one or more electron-withdrawing substituents and a pKa of R 1 OH in a range of 3 to 10; and
wherein Q 1 represents a hydrocarbon group or a substituted oxy, substituted amino, or substituted thio group.
17. The infrared laser-compatible positive-type image recording material according to claim 15 , wherein the ester compound represented by Formula (I) is a compound further represented by the following Formula (IV),
wherein R 3 R 5 each represent a hydrogen atom or a hydrocarbon group; and Ar 1 represents an aryl group having one or more electron-withdrawing substituents and a pKa of Ar 1 OH in a range of 3to 10.
18. The infrared laser-compatible positive-type image recording material according to claim 16 , wherein the ester compound represented by Formula (I) is a compound further represented by the following Formula (V),
wherein Q 1 represents a hydrocarbon group or a substituted oxy, substituted amino, or substituted thio group; and Ar 1 represents an aryl group having one or more electron-withdrawing substituents and a pKa of Ar 1 OH in a range of 3 to 10.