Elastomer compositions for use in a hydrocarbon resistant hose
View Patent ↗A heat tolerant, pressure resistant elastomeric composition comprising a blend of a first ethylene-vinyl ester copolymer and a second copolymer selected from the group consisting of chlorosulfonated polyethylene (CSM), chlorinated polyethylene (CPE), polychloroprene (CR), ethylene-acrylic elastomer (AEM), alkyl-acrylate copolymer (ACM), polyvinyl acetate (PVA), nitrile-butadiene rubber (NBR), hydrogenated nitrile-butadiene rubber (HNBR), and mixtures thereof, a hose manufactured therefrom; and a method for preparing the hose are described.
1. A heat tolerant, pressure and hydrocarbon resistant, elastomeric, automotive hose composition exhibiting improved hydrocarbon fluid impermeability, said composition comprising:
a blend of a first copolymer and a second copolymer wherein said first copolymer is an ethylene-vinyl ester of a C 2 to C 6 lower carboxlyic acid; and a said second copolymer is an ethylene-acrylic elastomer (AEM), an alkyl-acrylate copolymer (ACM) or a mixture thereof.
2. The composition of claim 1 , wherein said first copolymer is an ethylene-vinyl acetate copolymer and said second copolymer is an ethylene-acrylate elastomer, an alkyl acrylate copolymer, or a mixture thereof.
3. The composition of claim 2 , wherein said ethylene-vinyl acetate copolymer contains about 40 to 80 weight percent vinyl acetate.
4. The composition of claim 2 , wherein said ethylene-vinyl acetate copolymer contains about 50 to 80 weight percent vinyl acetate.
5. The composition of claim 2 , wherein said second copolymer is an ethylene-acrylic elastomer.
6. The composition of claim 5 , wherein said blend contains about 10 to 90 weight percent vinyl acetate copolymer and about 90 to 10 weight percent ethylene-acrylic elastomer.
7. The composition of claim 1 further comprising 0 to about 75% by weight of an elastomeric polymer selected from the group consisting of chlorinated polyolefin, chlorosulfonated polyolefin, polychloroprene, polyvinyl acetate, acrylonitrile-butadiene rubber, hydrogenated acrylonitrile-butadiene rubber, ethylene-propylene diene terpolymer, styrene-butadiene rubber, ethylene-propylene rubber, butyl rubber, cis-polybutadiene, cis-polyisoprene, polyurethane and combinations thereof.
8. The composition of claim 1 further comprising about 25 to 75% by weight of one or more additives selected from the group consisting of process aids, fillers, plasticizers, metal oxides, metal hydroxides, peroxides, coagents, antioxidants and combinations thereof.
9. The composition of claim 8 , wherein said one or more additives comprises:
about 0 to 8% by weight one or more processing aids selected from the group consisting of stearic acid, stearates, 1-octanedecanamine, polyethylene, amines, oils, organic esters, organic phosphate esters and combinations thereof,
about 20 to 60% by weight one or more fillers selected from the group consisting of carbon black, graphite, silicone dioxide, fumed silica, precipitated silica, diatomaceous earth, magnesium carbonate, calcium carbonate, magnesium silicate, aluminum silicate, titanium dioxide, talc, mica, aluminum sulfate, calcium sulfate, wollastonite, molybdenum disulfide, clay, calcium carbonate and combinations thereof
about 3 to 15% by weight one or more plasticizers selected from the group consisting of hydrocarbons, glycols, aldehydes, ethers, esters, ether-ester, trioctyl trimellitate and combinations thereof,
about 0 to 10% by weight one or more metal oxides and/or hydroxides selected from the group consisting of zinc oxide, zinc hydroxide, magnesium oxide, magnesium hydroxide, calcium oxide, calcium hydroxide, aluminum hydroxide and combinations thereof,
about 0.5 to 4% by weight one or more peroxides selected from the group consisting of 2,5-dimethyl-2,5-di(t-butylperoxy)hexyne-3; 2,5-dimethyl-2,5-di(t-butylperoxy)hexane; α, α′-bis(t-bis(t-butylperoxy)-p-diisopropylbenzene; dicumyl peroxide; di-t-butyl peroxide; 1,1-bis(t-butylperoxy)3,3,5-trimethylcyclohexane; 2,4-dichlorobenzoyl peroxide; benzoyl peroxide; p-chlorobenzoyl peroxide; 4,4-bis(t-butylperoxy)valerate; t-butylcumyl peroxide; di-t-amyl peroxide; t-butyl hydroperoxide and combinations thereof;
about 0.25 to 5% by weight one or more coagents selected from the group consisting of maleimides, triallyl cyanurate, triallyl isocyanurate, diallyl terepbthalate, 1,2-vinyl polybutadiene, di- and tri-functional methacrylates, diacrylates, metal ion versions thereof and combinations thereof; and
about 0 to 3% by weight one or more antioxidants selected from the group consisting of phenols, hydrocinnamates, hydroquinones, hydroquinolines, diphenylamines, mercaptobenzimidazoles and combinations thereof.
10. The composition of claim 9 , wherein said composition comprises:
about 10 to 90% by weight of an ethylene-vinyl acetate copolyrner containing about 50 to 80% vinyl acetate;
about 90 to 10% by weight of an ethylene-acrylic elastomer;
about 0 to 75% by weight of an elastomeric polymer selected from the group consisting of chlorinated polyolefin, chlorosulfonated polyolefin, polychloroprene, polyvinyl acetate, acrylonitrile-butadiene rubber, hydrogenated acrylonitrile-butadiene rubber, ethylene-propylene diene terpolymer, styrene-butadiene rubber, ethylene-propylene rubber, butyl rubber, cis-polybutadiene, cis-polyisoprene, polyurethane, and combinations thereof:
about 0.2 to 0.7% by weight stearic acid;
about 23 to 38% by weight carbon black;
about 2 to 5% by weight silicon dioxide;
about 3 to 7% by weight trioctyl trimellitate;
about 0.5 to 7% by weight adipate type plasticizer;
about 0 to 8% by weight magnesium oxide;
about 0.1 to 0.75% by weight 1-octanedecanamine;
about 0.1 to 0.75% organic phosphate ester;
about 0.5 to 4% by weight organic peroxide;
about 0.25 to 1% by weight triallyl cyanurate;
about 0.25 to 1% by weight N,N′, n-phenylenedimaleimide;
about 0.25 to 2% by weight antioxidant selected from the group consisting of phenols, hydrocinnamates, diphenylamines, hydroquinones, hydroquinolines and mixtures thereof.