Process for preparing fused solid of europium halide
View Patent ↗Fused solid of an europium halide containing a less amount of europium oxyhalide impurities is prepared by a process in which a starting europium halide is heated to fuse in the presence of a halogen source and then cooled to give the fused solid.
1. A process for preparing fused solid of an europium bromide, wherein a powdery starting europium bromide is heated to fuse in the presence of a bromine source and then cooled to give the fused solid.
2. The process of claim 1 , wherein the bromine source is an ammonium bromide which is heated simultaneously when the starting europium bromide is heated.
3. The process of claim 2 , wherein the ammonium bromide is mixed with the starting europium bromide before they are heated.
4. The process of claim 2 , wherein the ammonium bromide is used in a weight ratio of 0.1/10 to 10/10 based on an amount of the starting europium bromide.
5. The process of claim 2 , wherein the starting europium bromide and ammonium bromide are dried separately or in the form of their mixture at a temperature of 50 to 400° C. and a pressure of 100 Pa or less before they are heated.
6. The process of claim 1 , wherein the heating of the starting europium bromide is performed under such conditions of a water vapor content of 5.0×10 −5 mol/L or less and an oxygen concentration of 1.0×10 −5 mol/L or less.
7. The process of claim 1 , wherein the heating of the starting europium bromide is performed in an inert gas atmosphere or in a reducing gas atmosphere.
8. The process of claim 1 , wherein the cooling of the fused europium bromide is performed under vacuum in an inert gas atmosphere or in a reducing gas atmosphere.
9. The process of claim 1 , wherein the bromide source is gaseous bromide or a gaseous hydrogen bromide.