Process to produce silica-filled elastomeric compounds
View Patent ↗The present invention provides a process for preparing a filled halobutyl elastomer, which includes mixing a halobutyl elastomer with at least one mineral filler and at least one phosphine modifier and optionally curing the filled elastomer with sulfur or other curative systems. Filled halobutyl elastomers prepared according to the present invention possess improved levels of filler dispersion which results in a reduction in the hardness of the compound and an increased tensile strength.
1. A process for preparing a filled halobutyl elastomer comprising admixing at least one halogenated isoolefin-conjugated diolefin-copolymer with at least one mineral filler, and at least one phosphine modifier
wherein the at least one halogenated isoolefin-conjugated diolefin-copolymer and the at least one phosphine modifier form an ionomer which interacts with polar surfaces of the at least one mineral filler.
2. The process according to claim 1 , wherein the halogenated isoolefin-conjugated diolefin-copolymer is a brominated butyl elastomer or a chlorinated butyl elastomer.
3. The process according to claim 1 , wherein the phosphine modifier has a neutral three-coordinate phosphorus center which possesses a lone pair of electrons centered on the neutral three-coordinate phosphorus rand having electronic and steric environment so that the phosphorus center is nucleophilic.
4. The process according to claim 3 , wherein the phosphine modifier is functionalized with one or more group selected from group consisting of a-hydroxy groups silyl ether groups and combinations thereof.
5. The process according to claim 3 , wherein the phosphine modifier is triphenyiphosphine.
6. The process according to claim 1 , wherein the mineral tiller is selected from the group consisting of regular or highly dispersible silica, silicates, clay, gypsum, alumina, titanium dioxide, talc and mixtures thereof.
7. The process according to claim 6 , wherein the mineral filler is silica or clay.
8. The process according to claim 2 , wherein the halogenated butyl elastomer is a brominated butyl elastomer.
9. The process according to claim 1 , wherein the amount of the phosphine modifier admixed is in the range of from 0.1 to 20 parts per hundred parts of elastomer.
10. The process according to claim 1 , further comprising curing the elastomer.
11. The process according to claim 1 , wherein the at least one halobutyl elastomer and at least one phosphine modifier are admixed prior to admixing at least one mineral filler.
12. A method of improving the tensile strength of a filled, cured elastomer composition comprising at least one halogenated isoolefin-conjugated diolefin-copolymer comprising admixing the halogenated isoolefin-conjugated diolefin-copolymer with at least one mineral filler and at least one phosphine modifier and curing the elastomer composition.
13. The process according to claim 1 , wherein the halogenated isoolefin-conjugated diolefin-copolymer is brominated isobutene-isoprene-copolymers.
14. A method for preparing a filled halobutyl elastomer comprising:
pretreating a halogenated isoolefin-conjugated diolefin-copolymer with at least on phosphine modifier to form a halogenated isoolefin-conjugated diolefin-copolymer-phosphine modifier ionomer; and
admixing at least one mineral filler with the ionomer.
15. A method for preparing a filled halobutyl elastomer comprising:
pretreating a halogenated isoolefin-conjugated diolefin-copolymer with at least on phosphine modifier to form a halogenated isoolefin-conjugated diolefin-copolymer-phosphine modifier ionomer; and
admixing at least one mineral filler with the ionomer; and
curing the admixture.