Golf balls comprising highly-neutralized acid polymers
View Patent ↗A golf ball comprising a core comprised of a polymer containing an acid group fully-neutralized by an organic acid or a salt, a cation source, or a suitable base thereof, the core having a first Shore D hardness, a compression of no greater than about 90, and a diameter of between about 1.00 inches and about 1.64 inches; and a cover layer comprising ionomeric copolymers and terpolymers, ionomer precursors, thermoplastics, thermoplastic elastomers, polybutadiene rubber, balata, grafted metallocene-catalyzed polymers, non-grafted metallocene-catalyzed polymers, single-site polymers, high-crystalline acid polymers and their ionomers, or cationic ionomers.
1. A golf ball comprising:
a core comprising a center and an outer core layer, the center comprising a thermoset polybutadiene rubber composition having a first hardness; and the outer core layer comprising a polymer comprised of an acid group fully-neutralized by an organic acid or a salt of the organic acid, and a cation source or a suitable base of the cation source; and having a second hardness; and
an inner cover layer and an outer cover layer comprising ionomeric copolymers and terpolymers, ionomer precursors, thermoplastics, thermoplastic elastomers, polybutadiene rubber, balata, grafted metallocene-catalyzed polymers, non-grafted metallocene-catalyzed polymers, single-site polymers, high-crystalline acid polymers and their ionomers, polyurethnnes, polyureas, polyurethane-ureas; polyurea-urethanes; or cationic ionomers;
wherein the first hardness is from about 50 Shore A to about 55 Shore D and first hardness is less than the second Shore D hardness by at least about 10 points.
2. The golf ball of claim 1 , wherein the cation source is selected from a group consisting of metal cations of lithium, sodium, potassium, magnesium, calcium, barium, lead, tin, zinc, or aluminum.
3. The golf ball of claim 1 , wherein the organic acid is selected from the group consisting of aliphatic organic acids, aromatic organic acids, saturated mono-functional organic acids, unsaturated mono-functional organic acids, and multi-unsaturated mono-functional organic acids.
4. The golf ball of claim 1 , wherein the salt of organic acids comprise the salts of barium, lithium, sodium, zinc, bismuth, chromium, cobalt, copper, potassium, strontium, titanium, tungsten, magnesium, cesium, iron, nickel, silver, aluminum, tin, calcium, stearic, behenic, erucic, oleic, linoelic, dimerized derivatives, and mixtures thereof.
5. The golf ball of claim 1 , wherein the center has a first elastic modulus and the outer core layer has a second elastic modulus, and the first elastic modulus is less than the second elastic modulus by at least 10%.
6. The golf ball of claim 1 , wherein the cover layer is formed from a non-castable material, or is castable, injection molded, or compression molded over the core.
7. The golf ball of claim 1 , wherein the polymer comprises jonomeric copolymers and terpolymers, ionomer precursors, thermoplastics, thermoplastic elastomers, polybutadiene rubber, balata, grafted metallocene-catalyzed polymers, non-grafted metallocene-catalyzed polymers, single-site polymers, high-crystalline acid polymers and their ionomers, cationic ionomers, and mixtures thereof.
8. The golf ball of claim 1 , wherein the core has a diameter of about 1.53 inches or greater.
9. The golf ball of claim 8 , wherein the core comprises two or more layers.
10. The golf ball of claim 1 , wherein at least one of the inner cover or outer cover comprises a polyurethane material, a polyurea material, a polyurethane-urea hybrid material, or a polyurea-urethane hybrid material.
11. The golf ball of claim 1 , wherein at least one of the inner cover or outer cover comprise a polymer comprising an acid group fully-neutralized by an organic acid or a salt, a cation source, or a suitable base thereof.
12. The golf ball of claim 1 , wherein the inner cover layer has material hardness of at least about 60 Shore D and the outer cover layer has a material hardness of no greater than about 60 Shore D.
13. The golf ball of claim 1 , wherein the outer cover layer has material hardness of at least about 60 Shore D and the inner cover layer has a material hardness of no greater than about 60 Shore D.
14. The golf ball of claim 1 , wherein the core compression is no greater than about 80.
15. The golf ball of claim 1 , wherein the core further comprises an organosulfur or the metal salt thereof.
16. A golf ball comprising:
a core comprising a center and an outer core layer, the center comprising a thermoset polybutadiene rubber composition having a first hardness and a first elastic modulus; and the outer core layer comprising a polymer comprised of an acid group fully-neutralized by an organic acid or a salt of the oraanic acid, and a cation source or a suitable base of the cation source; and having a second hardness and a second elastic modulus; and
a cover layer comprising an inner cover layer and an outer cover layer, at least one of the inner or outer cover layers comprising ionomeric copolymers and terpolymers, ionomer precursors, thermoplastics, thermoplastic elastomers, polybutadiene rubber, balata, grafted metallocene-catalyzed polymers, non-grafted metallocene-catalyzed polymers, single-site polymers, high-crystalline acid polymers and their ionomers, polyurethanes, polyureas, polyurethane-ureas; polyurea-urethanes; or cationic ionomers;
wherein the first hardness is from about 50 Shore A to about 55 Shore D and first hardness is less than the second Shore D hardness by at least about 10 points; and the first elastic modulus is less than the second elastic modulus by at least 10%.