Organic electroluminescent device and method of manufacturing the same
View Patent ↗An organic electroluminescent device which has a low moisture permeability and an oxygen permeability. The organic electroluminescent device includes a substrate, an organic light-emitting unit having a sequentially stacked structure of a first electrode, an organic film, and a second electrode formed on a surface of the substrate, and an organic-inorganic composite film made of a dehydrated polycondensate of a hydrolyzed product of trialkoxy metal formed on an upper surface of the second electrode of the organic light-emitting unit. The organic-inorganic composite film simplifies a manufacture process and has high visible light transmittance. Therefore, the organic-inorganic composite film can be used as an intermediate layer of a front emission type organic electroluminescent device. Also, the organic-inorganic composite film has excellent prevention function of the entry of moisture and/or oxygen. Therefore, the encapsulation of the device is ensured even when a sealing substrate is not separately used, thereby decreasing the total thickness of the device and increasing the life span of the device.
1. An organic electroluminescent device, comprising:
a substrate;
an organic light-emitting unit comprising a first electrode, an organic film, and a second electrode, said organic light-emitting unit formed on the substrate; and
an organic-inorganic composite film comprising a dehydrated polycondensate of a hydrolyzed product of a composition comprising trialkoxy metal formed on an upper surface of the second electrode of the organic light-emitting unit.
2. The organic electroluminescent device of claim 1 , wherein the trialkoxy metal is represented by Formula 1:
wherein M 1 is selected from the group consisting of silicon, titanium, tin, and zirconium, and
R 1 , R 2 , R 3 and R 4 are independently selected from the group consisting of an alkyl group of C1-C20, a substituted alkyl group of Cl-C20, an aryl group of C6-C20, and a substituted aryl group of C6-C20.
3. The organic electroluminescent device of claim 1 , wherein the composition further comprises at least one selected from the group consisting of metal alkoxide represented by Formula 2 and fluoroalkylsilane represented by Formula 3:
wherein M 2 is selected from the group consisting of silicon, titanium, tin, and zirconium, and
R 5 , R 6 , R 7 and R 8 are independently selected from the group consisting of an alkyl group of C1-C20, a substituted alkyl group of C1-C20, an aryl group of C6-C20, and a substituted aryl group of C6-C20; and
wherein R 9 is a fluorinated alkyl group of C1-C20, R 10 and R 11 are independently an alkoxy group of C1-C20 or a fluorinated alkyl group of C1-C20, and R12 is an alkyl group of C1-C20.
4. The organic electroluminescent device of claim 3 , wherein the trialkoxy metal is selected from the group consisting of glycidoxypropyltrimethoxysilane and methacryloxypropyltrimethoxysilane.
5. The organic electroluminescent device of claim 3 , wherein said metal alkoxide is selected from the group consisting of tetraethyl orthosilicate and tetramethyl orthosilicate.
6. The organic electroluminescent device of claim 3 , wherein the fluoroalkylsilane is selected from the group consisting of heptadecafluorodecyltriethoxysilane, heptadecafluorodecyltrimethoxysilane, heptadecafluorodecyltriisopropoxysilane, heptadecafluorodecyltributoxysilane, di-(heptadecafluorodecyl)diethoxysilane, and tris-(heptadecafluorodecyl)ethoxysilane.
7. The organic electroluminescent device of claim 1 , further comprising a passivation layer between the second electrode and the organic-inorganic composite film.
8. The organic electroluminescent device of claim 1 , further comprising a sealing substrate on an upper surface of the organic-inorganic composite film.
9. The organic electroluminescent device of claim 7 , wherein a thickness of the organic-inorganic composite film is in a range of 1 to 100 μm.
10. A method of manufacturing an organic electroluminescent device, comprising:
preparing a substrate;
preparing an organic light-emitting unit formed on the substrate, said organic-light emitting unit comprising a first electrode, an organic film, and a second electrode;
coating a composition containing trialkoxy metal and a polar solvent on an upper surface of the second electrode; and
curing the composition to form an organic-inorganic composite film comprising a dehydrated polycondensate of a hydrolyzed product of the composition.
11. The method of claim 10 , wherein the trialkoxy metal is represented by Formula 1:
wherein M 1 is selected from the group consisting of silicon, titanium tin, and zirconium, and
R 1 , R 2 , R 3 and R 4 are independently selected from the group consisting of an alkyl group of C1-C20, a substituted alkyl group of C1-C20, an aryl group of C6-C20, and a substituted aryl group of C6-C20.
12. The method of claim 11 , wherein the trialkoxy metal is selected from the group consisting of glycidoxypropyltrimethoxysilane and methacryloxypropyltrimethoxysilane.
13. The method of claim 10 , wherein the composition further comprises at least one selected from the group consisting of metal alkoxide represented by Formula 2 and fluoroalkylsilane represented by Formula 3:
wherein M 2 is selected from the group consisting of silicon, titanium, tin, and zirconium, and
R 5 , R 6 , R 7 and R 8 are independently an alkyl group of C1-C20 or an aryl group of C6-C20; and
wherein R 9 is a fluorinated alkyl group of C1-C20, R 10 and R 11 are independently an alkoxy group of C1-C20 or a fluorinated alkyl group of C1-C20, and R 12 is an alkyl group of C1-C20.
14. The method of claim 13 , wherein said metal alkoxide is selected from the group consisting of tetraethyl orthosilicate and tetramethyl orthosilicate.
15. The method 13 , wherein the fluoroalkylsilane is selected from the group consisting of heptadecafluorodecyltriethoxysilane, heptadecafluorodecyltrimethoxysilane, heptadecafluorodecyltriisopropoxysilane, heptadecafluorodecyltributoxysilane, di-(heptadecafluorodecyl)diethoxysilane, and tris-(heptadecafluorodecyl)ethoxysilane.
16. The method of claim 11 , wherein the composition further comprises 0.1 to 0.9 mole of a catalyst for facilitating a hydrolysis reaction based on 1 mole of the trialkoxy metal of Formula 1.
17. The method of claim 13 , wherein the polar solvent is at least one selected from the group consisting of methanol, ethanol, butanol, isopropanol, and methylethylketone, and the content of the polar solvent is in a range of 100 to 1,000 parts by weight, based on 100 parts by weight of the trialkoxy metal of Formula 1.
18. The method of claim 10 , further comprising forming a passivation layer on the upper surface of the second electrode prior to forming the organic-inorganic composite film.
19. The method of claim 10 , further comprising forming a sealing substrate on an upper surface of the organic-inorganic composite film.
20. The organic electroluminescent device produced by the method of claim 10 .
21. The organic electroluminescent device of claim 1 , wherein the organic-inorganic composite film is formed directly on the upper surface of the second electrode of the organic light-emitting unit.