IP Library Granted Patent US 7,482,036
Granted Patent B2
US 7,482,036 · App. 10/844,702 · Granted Jan 27, 2009

Lens coating curing methods

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Quick Facts
Patent No.
US 7,482,036
App. No.
10/844,702
Granted
Jan 27, 2009
Kind
B2
Abstract

A method that includes providing a lens having a first side, a second side, and an anti-reflective or mirror coating on the first side; depositing a heat-curable coating on the second side of the lens; and heating the heat-curable coating without damaging the anti-reflective or mirror coating. Another method that includes providing a non-pure polycarbonate lens having a first side, a second side, and a first coating on the first side; depositing a heat-curable coating on the second side of the lens; and heating the heat-curable coating without damaging the first coating. Other methods are also disclosed.

Claims (45)

1. A method comprising:

providing a lens having a first side, a second side, and a first coating on the first side;

depositing a heat-curable coating on the second side of the lens; and

heating the heat-curable coating during a period of time without damaging the first coating, wherein the lens is cooled during the heating of the heat-curable coating for at least a portion of said period of time to prevent the first coating from being damaged by the heating.

2. The method according to claim 1 , wherein the first coating is an anti-reflective or mirror coating.

3. The method according to claim 2 , wherein the mirror coating comprises one or more layers of dielectric oxides.

4. The method according to claim 2 , wherein the anti-reflective coating is a mono-or multilayer film of dielectric material.

5. The method according to claim 4 , wherein the dielectric material is selected from the group consisting of: SiO, SiO2, Si3N4, TiO2, ZrO2, Al2O3, MgF2, Ta2O5 and mixtures thereof.

6. The method according to claim 3 , wherein the dielectric oxides are selected from the group consisting of: SiO, SiO2, TiO, and ZrO2.

7. The method according to claim 1 , wherein the first coating is a hard coating.

8. A method according to claim 7 , wherein the hard coating or layer comprises hydrolyzates of polyalkoxysilanes.

9. The method according to claim 8 , wherein the hydrolyzates of polyalkoxysilanes are selected from the group consisting of epoxytrialkoxysilanes and epoxydialkoxysilanes.

10. The method according to claim 8 , wherein the hard coating or layer comprises fillers selected from the group consisting of: SiO2, TiO2, Sb2O5, Al2O3 and Fe2O3.

11. The method according to claim 1 , wherein the lens includes a second coating applied to the first coating.

12. The method according to claim 11 , wherein the first coating is a hard coating and the second coating is an anti-reflective or mirror coating.

13. The method according to claim 12 , wherein the hard coating includes a primer layer and a hard layer.

14. The method according to claim 13 , wherein the primer coating or layer is an impact-resistant primer coating chosen from (meth)acrylic based coatings and polyurethane based coatings.

15. The method according to claim 14 , wherein the primer coating or layer is made from a latex composition selected from the group consisting of: poly(meth)acrylic latexes, polyurethane latexes and polyester latexes.

16. The method according to claim 11 , wherein the first coating is a primer coating and the second coating is a hard coating.

17. The method according to claim 11 , wherein the heating results in heat curing the heat-curable coating such that neither the first coating nor the second coating is damaged by the heat curing.

18. The method according to claim 1 , wherein the heating results in heat curing the heat-curable coating without damaging the first coating.

19. The method according to claim 1 , wherein the heating (a) results in heat curing the heat-curable coating without damaging the first coating, and (b) takes no more than one hour.

20. The method according to claim 1 , wherein the heating (a) results in heat curing the heat-curable coating without damaging the first coating, and (b) takes no more than 30 minutes.

21. A method according to claim 1 , wherein the heating (a) results in heat curing the heat-curable coating without damaging the first coating, and (b) takes no more than 5 minutes.

22. The method according to claim 1 , further comprising:

depositing a second-side sol-gel anti-reflective coating on the heat-curable coating; and

wherein the heating comprises heat curing the second-side anti-reflective coating and the heat-curable coating without damaging the first coating.

23. The method according to claim 22 , wherein the heat-curable coating is a hard coating and wherein a ultra-violet (UV) curable primer coating is disposed between the second side and the hard coating.

24. The method according to claim 1 , wherein the heat-curable coating is a heat-curable hard coating.

25. The method according to claim 1 , wherein the heat-curable coating is a heat-curable anti-reflective coating.

26. The method according to claim 25 , wherein the anti-reflective coating is a sol-gel anti-reflective coating that includes at least two layers with different refractive indices.

27. The method according to claim 1 , further comprising surfacing the lens to a prescription power.

28. The method according to claim 1 , wherein the heating comprises convective heating.

29. The method according to claim 1 , wherein the heating comprises intermittently applying heat to the heat-curable coating.

30. The method according to claim 29 , wherein the lens is positioned on a circular conveyor belt during the heating and the cooling.

31. The method according to claim 1 , wherein the cooling comprises conductive cooling.

32. The method according to claim 31 , wherein cooling includes cooling the lens using a liquid.

33. The method according to claim 32 , wherein cooling includes cooling the lens using a water-cooled lens holding device.

34. The method according to claim 33 , wherein the water-cooled lens holding device includes a curved lens holding surface and a cooling liquid forming a layer between the first side of the lens and the curved lens holding surface.

35. The method according to claim 1 , wherein the heating results in heat curing the heat-curable coating without damaging the first coating and cooling includes cooling the lens using a liquid such that the temperature of the first coating does not reach or exceed 50° C. during the heat curing.

36. The method according to claim 35 , wherein the heat curing includes heating the heat-curable coating on the second side of the lens to a surface temperature of at least 100° C., preferably 150-170° C.

37. The method according to claim 35 , wherein the heat curing includes heating the heat-curable coating on the second side of the lens to a surface temperature of 150-170° C.

38. The method according to claim 1 , wherein the cooling comprises convective cooling.

39. The method according to claim 1 , wherein the portion of the period of time is less than the period of time.

40. The method according to claim 1 , wherein the portion of the period of time is the same as the period of time.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 6, 2018
From: ESSILOR INTERNATIONAL (COMPAGNIE GÉNÉRALE D'OPTIQUE)
To: ESSILOR INTERNATIONAL
Reel/Frame 045853/0275 →