High internal phase polyelectrolyte emulsions for the manufacture of superabsorbent polymers and superabsorbent polymers made therefrom
View Patent ↗The present invention refers to a high internal phase polyelectrolyte emulsions which are useful for the manufacture of superabsorbent polymers having two phases: i) a continuous oil phase and the ii) a dispersed aqueous phase containing the aqueous monomer solution prior to polymerization and the polyelectrolyte in water-soluble, or water-swellable or very slightly crosslinked form after polymerization, wherein the polymerization occurs in the dispersed aqueous phase and wherein the dispersed aqueous phase contains a high concentration of polyelectrolyte. The present invention also refers to a process for preparing such emulsions and for inverting these emulsions so as to form films or other patterns of the superabsorbent polymer. Absorbent structures containing SAP films or other patterns prepared by the present invention are also contemplated.
1. A high internal phase polyelectrolyte emulsion which is useful for the manufacture of a superabsorbent polymer, the emulsion having two phases: i) a continuous oil phase and ii) a dispersed aqueous phase containing polyelectrolyte, wherein the dispersed aqueous phase contains a concentration of polyelectrolyte which is from 10 to 50 weight percent, based on the weight of the total aqueous phase; and wherein the emulsion comprises a post-crosslinker, an inversion agent, and, optionally, a plasticizing agent.
2. The emulsion of claim 1 wherein the weight average molecular weight of the polyelectrolyte is at least about 1,500,000 g/mole.
3. The emulsion of claim 1 wherein the concentration of polyelectrolyte in the dispersed aqueous phase is from 20 to 40 weight percent.
4. The emulsion of claim 1 wherein the polyelectrolyte comprises polyacrylic acid, a salt of polyacrylic acid, or a mixture thereof.
5. The emulsion of claim 1 wherein the oil phase is a hydrophobic organic solvent.
6. The emulsion of claim 5 wherein the boiling point of the solvent is form about 60° C. to about 250° C.
7. The emulsion of claim 1 wherein the dispersity is not more than about 6.
8. The emulsion of claim 1 wherein the dispersity is not more than about 4.
9. The emulsion of claim 1 further comprising a surfactant, a dispersing agent, or a combination thereof.
10. The emulsion of claim 1 wherein the polyelectrolyte is a partially neutralized polyacrylic acid having a degree of neutralization of from about 60 to 70 mole percent.
11. The emulsion of claim 10 wherein the weight average molecular weight of the polyelectrolyte is at least about 1,500,000 g/mole.
12. The emulsion of claim 1 wherein the polymer is in the form of particles, and the particle size is in the range of from about 0.1 to about 100 microns.
13. The emulsion of claim 1 wherein the polymer is in the form of particles, and the particle size is in the range of from about 1 to about 30 microns.
14. The emulsion of claim 1 wherein the ratio of aqueous dispersed phase to continuous oil phase is from about 70:30 to about 99:1.
15. The emulsion of claim 1 wherein the ratio of aqueous dispersed phase to continuous oil phase is from about 75:25 to about 90:10.
16. A process for preparing superabsorbent structures comprising:
(a) spreading or coating an emulsion of claim 1 on a support material, wherein the emulsion is a water-in-oil emulsion comprising in its aqueous, dispersed phase a precursor polymer particle having a particle size of from about 0.1 to 100 microns, the emulsion further comprising a post-crosslinker, an inversion agent, and optionally, a plasticizing agent;
(b) allowing or inducing coalescence of the aqueous phase under conditions sufficient to allow the emulsion to form a homogeneous polymer gel structure, and
(c) drying and post-crosslinking the formed gel material at a temperature sufficient to dry and cure the material, and
(d) optionally, post-treating the material obtained in step (c) by post-heat treating the material, by surface modifying the material by surface post-crosslinking the material, or by any combination of these post-treatments.
17. A high internal phase polyelectrolyte emulsion which is useful for the manufacture of a superabsorbent polymer, the emulsion having two phases: i) a continuous oil phase comprising a hydrophobic organic solvent and ii) a dispersed aqueous phase containing polyelectrolyte, wherein the concentration of polyelectrolyte in the dispersed aqueous phase is from 20 to 40 weight percent, based on the weight of the total aqueous phase, wherein the polyelectrolyte is a partially neutralized polyacrylic acid having a degree of neutralization of from about 60 to about 70 mole percent, a weight average molecular weight of at least about 1,500,000 g/mole, and a dispersity of not more than about 6, wherein the ratio of aqueous dispersed phase to continuous oil phase is from about 70:30 to about 99:1 and wherein the emulsion comprises a post-crosslinker, an inversion agent, and, optionally, a plasticizing agent.