Radiation image storage panel
View Patent ↗A radiation image storage panel having a phosphor layer formed by a gas phase-accumulation method, in which the phosphor layer is made of an europium activated alkali metal halide stimulable phosphor (in which the alkali metal atom is Rb and/or Cs and the halogen is Cl, Br and/or I), and the phosphor layer gives off a stimulated emission whose afterglow at 0.24 millisecond observed after excitation with a stimulating light has an intensity of 1/10 2.1 or less of a maximum intensity of the stimulated emission (the stimulated emission and afterglow is observed after the phosphor layer is exposed to radiation and then excited with the stimulating light).
1. A radiation image storage panel comprising a phosphor layer formed by a gas phase-deposition method, wherein the phosphor layer comprises an europium activated alkali metal halide stimulable phosphor in which the alkali metal atom is selected from the group consisting of Rb and Cs and the halogen is selected from the group consisting of Cl, Br and I, and wherein the phosphor layer gives off a stimulated emission whose afterglow at 0.24 millisecond observed after excitation with a stimulating light has an intensity of 1/10 2.1 or less of a maximum intensity of the stimulated emission, the stimulated emission and afterglow being observed after the phosphor layer is exposed to radiation and then excited with the stimulating light.
2. The radiation image storage panel of claim 1 , wherein the afterglow of 0.24 millisecond after theexcitation has an intensity of 1/10 2.5 or less of the maximum intensity of the stimulated emission.
3. The radiation image storage panel of claim 1 , wherein the phosphor layer comprises columnar crystals of the europium activated alkali metal halide stimulable phosphor.
4. The radiation image storage panel of claim 1 , wherein the phosphor layer gives an ultraviolet light-excited emission spectrum in which a ratio of intensities of emission peaks observed in the vicinity of 440 nm and in the vicinity of 490 nm in terms of I(440/490) satisfies the condition of:
I(440/490)≧10.
5. The radiation image storage panel of claim 4 , wherein the phosphor layer gives an ultraviolet light-excited emission spectrum in which the ratio I(440/490) satisfies the condition of:
I(440/490)≧14.
6. The radiation image storage panel of claim 1 , wherein the europium activated alkali metal halide stimulable phosphor is represented by the following formula (I):
M I X·aM II X′ 2 ·bM III X″ 3 :zEu (1)
[in which M 1 is at least one alkali metal selected from the group consisting of Rb and Cs; M II is at least one alkaline earth metal or divalent metal selected from the group consisting of Be, Mg, Ca, Sr, Ba, Ni, Cu, Zn, and Cd; M III is at least one rare earth element or trivalent metal selected from the group consisting of Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Al, Ga, and In; each of X, X′ and X″ independently is at least one halogen selected from the group consisting of Cl, Br and I; and a, b and z are numbers satisfying the conditions of 0a≦<0.5, 0≦b<0.5 and 1×10 −5 ≦z<1.0].
7. The radiation image storage panel of claim 6 , wherein M I and X in the formula (I) are Cs and Br, respectively.