Photothermographic material and image forming method
View Patent ↗The present invention provides a photothermographic material having an image forming layer including at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder, on one surface of a support, and having at least one back layer and a back surface protective layer, on the other surface of the support, wherein a binder of the back surface protective layer contains a water-soluble polymer and a latex polymer having a glass transition temperature of −30° C. to 40° C.; and an image forming method using the same. The photothermographic material and the image forming method of the invention provide excellent coating property and excellent transportability during thermal development in a thermal developing apparatus.
1. A photothermographic material comprising an image forming layer containing at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder, on one surface of a support, and comprising at least one back layer and a back surface protective layer, on the other surface of the support, wherein a binder of the back surface protective layer contains a water-soluble polymer and a latex polymer having a glass transition temperature of −30° C. to 24° C. and the back surface protective layer comprises a fluorocarbon compound containing a fluoroalkyl group having two or more carbon atoms and 12 or less fluorine atoms.
2. The photothermographic material according to claim 1 comprising the latex polymer in an amount of 5% by weight to 50% by weight with respect to a total amount of the binder in the back surface protective layer.
3. The photothermographic material according to claim 2 comprising the latex polymer in an amount of 15% by weight to 40% by weight with respect to the total amount of the binder in the back surface protective layer.
4. The photothermographic material according to claim 1 , wherein the latex polymer has a glass transition temperature of −30° C. to 20° C.
5. The photothermographic material according to claim 1 , wherein the latex polymer is at least one polymer selected from acrylic polymers, styrene polymers, acrylic/styrene copolymers, styrene/butadiene copo lymers, vinyl chloride polymers, vinylidene chloride polymers and urethane polymers.
6. The photothermographic material according to claim 5 , wherein the latex polymer is an acrylic latex polymer.
7. The photothermographic material according to claim 1 , wherein the latex polymer has an I/O value of 0.1 to 1.0.
8. The photothermographic material according to claim 7 , wherein the latex polymer has an I/O value of 0.5 to 0.9.
9. The photothermographic material according to claim 1 , wherein the latex polymer comprises an anionic surfactant.
10. The photothermographic material according to claim 9 , wherein the anionic surfactant is at least one selected from salts of alkylbenzene sulfonic acid and diesters of sulfosuccinic acid.
11. The photothermographic material according to claim 1 , wherein the water-soluble polymer is gelatin.
12. The photothermographic material according to claim 1 , wherein the water-soluble polymer is at least one selected from polyvinyl alcohols and acrylic acid/ polyvinyl alcohol copolymers.
13. The photothermographic material according to claim 1 , wherein the fluorocarbon compound contains a fluoroalkyl group having 5 to 9 fluorine atoms.
14. An image forming method for a photothermographic material using a thermal developing apparatus, wherein the thermal developing apparatus comprises an imagewise exposure portion and a thermal development portion having a driving roller and a plate heater, and the photothermographic material according to claim 1 is imagewise exposed in the imagewise exposure portion and thermally developed in the thermal development portion by contacting a surface of the photothermographic material at a side at which the image forming layer is disposed with the driving roller, and by contacting a surface of the photothermographic material at a side at which the back layer is disposed with the plate heater.