Latex binder for nonwoven fibers and article made therewith
View Patent ↗The invention relates to a latex that may be utilized as a binder for nonwoven applications to form a permeable sublayer of personal hygiene articles. The latex is prepared by a process including the steps of (1) polymerizing a monomer mixture comprising styrene, itaconic acid, surfactant and water soluble free radical initiator to form a seed; (2) sequentially adding equal increments of a monomer mixture of styrene, butadiene and acrylic acid to the seed under emulsion polymerization conditions to form a styrene-butadiene-acrylic acid copolymer; and then (3) neutralizing the styrene-butadiene-acrylic acid copolymer to a pH of about 4.5 to 7 to form the latex.
1. A process for forming a polymer, the process comprising:
(i) adding a first monomer charge and a chain transfer agent to an aqueous system, where the first monomer charge includes styrene and butadiene;
(ii) initiating polymerization of the first monomer charge;
(iii) adding a second monomer charge and additional chain transfer agent to the aqueous system when 40 to 95% of the first monomer charge is converted, where the second monomer charge includes styrene, butadiene, and acrylic acid;
(iv) allowing the second monomer charge to polymerize; and
(v) neutralizing the aqueous system after 99% of the first and second monomer charge are converted.
2. The process of claim 1 , where the aqueous system to which the first monomer charge is added includes a polymeric seed.
3. The process of claim 2 , where the polymeric seed is formed by combining an initiator, styrene, and itaconic acid.
4. The process of claim 1 , where the first monomer charge includes functional monomer.
5. The process of claim 4 , where the second monomer charge includes functional monomer.
6. The process of claim 5 , where the functional monomer is selected from the group consisting of acrylates, acrylamides, acids, and mixtures thereof.
7. The process of claim 6 , where the functional monomer is selected from the group consisting of hydroxyethylacrylate, acrylamide, methacrylic acid, and N-methlolacrylamide, and mixtures thereof.
8. The process of claim 1 , where said step of adding the second monomer charge includes adding the second monomer charge in equal increments.
9. A process for forming a copolymer, the process comprising:
(i) forming a first segment of the copolymer by polymerizing a first charge of monomer including styrene and butadiene in the presence of a chain transfer agent; and
(ii) after converting from 40-95% of the first charge of monomer, forming an additional copolymer segment by polymerizing an additional charge of monomer including styrene, butadiene, and acrylic acid.
10. The process of claim 9 , where said step of forming the first segment occurs in the presence of a polymeric seed.
11. The process of claim 9 , where the first and additional monomer charge include functional monomer.
12. The process of claim 11 , where the functional monomer is selected from the group consisting of acrylates, acrylamides, acids, and mixtures thereof.
13. The process of claim 12 , where the functional monomer is selected from the group consisting of hydroxyethylacrylate, acrylamide, methacrylic acid, and N-methlolacrylamide, and mixtures thereof.
14. The process of claim 9 , where said step of forming an additional copolymer segment includes polymerizing additional monomer added by equal increment.
15. A process for forming a polymeric particle within an emulsion, the process comprising:
(i) forming a polymeric seed particle within an aqueous system;
(ii) adding a first monomer charge and a chain transfer agent to the aqueous system, where the first monomer charge includes styrene and butadiene;
(iii) initiating polymerization of the first monomer charge to thereby form polymeric particles that include styrene and butadiene repeat units;
(iv) adding a second monomer charge and additional chain transfer agent to the aqueous system when 40 to 95% of the first monomer charge is converted to the polymeric particles, where the second monomer charge includes styrene, butadiene, and acrylic acid;
(v) allowing the second monomer charge to polymerize and thereby increase the molecular weight of the first polymeric particles with repeat units that include styrene, butadiene, and acrylic acid; and
(vi) neutralizing the aqueous system after 99% of the first and second monomer charge is converted to polymeric particles.