Newtonian, ultrasonic-insensitive charge generating layer dispersion composition and a method for producing the composition
View Patent ↗This invention relates to electrophotographic elements containing a layer formed from coating compositions containing a mixture of polymeric binders, including a polyvinyl butyral and a polyester ionomer and a crystalline mixture of unsubstituted titanyl phthalocyanine pigment, titanyl phthalocyanine pigments or mixtures thereof dispersed in the mixture. More particularly the invention relates to electrophotographic elements containing photoconductive layers which are especially useful for forming a photoconductive layer that is very uniform and highly absorptive at relatively thin coverage with good inter layer adhesion. The electrophotographic elements produced using this coating composition are particularly suited for high quality applications such as providing copy images with very low grain.
1. A Newtonian, ultrasonic-insensitive charge generation dispersion composition comprising at least one finely-divided pigment, polyvinyl butyral containing moieties of butyral, vinyl alcohol and vinyl acetate wherein the polyvinyl butyral copolymer contains from about 75 to less than 88 mole percent butyral, from about 5 to about 20 mole percent vinyl alcohol and from about 0.5 to about 5 mole percent vinyl acetate and a polyester ionomer wherein the composition has a low shear viscosity (measured at 0.5 s-1) to high shear viscosity (measured at 1000 s-1) ratio from about 1 to about 3.0 and wherein the viscosity ratio is either retained or decreased after sonication.
2. The composition for claim 1 , wherein the pigment is present in the composition in an amount equal to from about 30 to about 80 weight percent based upon the weight of the total solid content of the coating composition.
3. The composition for claim 1 , wherein the average molecular weight of the polyvinyl butyral copolymer is from about 10,000 to about 170,000 Daltons.
4. The composition for claim 1 , wherein the polyvinyl butyral copolymer is present in the composition in an amount equal to from about 2 to about 40 weight percent based upon the weight of the total solid content of the composition.
5. The composition for claim 1 , wherein the pigment comprises at least one of the titanium phthalocyanine, titanyl fluorophthalocyanine and mixtures thereof.
6. The composition for claim 1 , wherein the polyester ionomer is present in the coating composition in an amount equal to from about 60 to about 98 weight percent based upon the weight of the total solid content of the coating composition.
7. The composition for claim 1 , wherein the polyester ionomer is selected from the group of polyester-ionomers having a structure according to formula I:
wherein: wherein R1 represents alkyl groups such as methyl, and t-butyl; R2 represents cyclohexyl, 1,4-dimethylenecyclohexane, 4,4′-benzophenone, 4,4′-di-phenylmethane, diphenylsulfone, 4,4′-isopropylidene bisphenylene, 4,4′-hexaflu-oroisopropylidene bisphenylene, 4,4′-cyclohexylidene bisphenylene, 4,4′-norborn-ylidene bispheylene, 4,4′-indnylidene bisphenylene, and 4,4′-fluorenylidenebis-phenylene; Ar represents an aromatic group containing an asymetric center, i.e., isophthalic acid 1,1,3-trimethy-3(4-carboxyphenyl)-5,5-indancarboxylate, and 3-methylphthalic anhydride, methylsuccinic acid, and 2-ethyl-1,6-hexanedioic acid;
M represents an alkali earth metals such as lithium, sodium or potassium or ammonium, trimethylammonium, triethylammonium, and hydroxylalkylammonium such as dihydroxyethylammonium, and trihydroxyethylammonium; n is an integer of from 2 to 12; X represents from 1 to 30 mole %; and Y represents from 0 to 100 mole %.
8. The composition of claim 7 , wherein the polyester ionomer is selected from the group consisting of:
poly{1,4-cyclohexylenedimethylene-co-2,2′-oxydiethylene
(46/54)isophthlate-co-5-sodiosulfoisophthlate (95/5)!;
poly{1,4-cyclohexylenedimethylene-co-2,2′-oxydiethylene
(46/54)isophthlate-co-5-sodiosulfoisophthlate (90/10)!;
poly{1,4-cyclohexylenedimethylene-co-2,2′-oxydiethylene
(46/54)isophthalate-co-5-sodiosulfoisophthalate (85/15)!;
poly{1,4-cyclohexylenedimethylene-co-2,2′-oxydiethylene
(46/54)isophthalate-co-5-sodiosulfoisophthalate (80/20)!;
poly{1,4-cyclohexylenedimethylene-co-2,2′-oxydiethylene
(46/54)isophthalate-co-5-sodiosulfoisophthalate (75/25)!;
poly{1,4-cyclohexylenedimethylene-co-2,2′-oxydiethylene
(46/54)isophthalate-co-5-lithiosulfoisophthalate (90/10)!;
poly{1,4-cyclohexylenedimethylene-co-2,2′-oxydiethylene
(46/54)isophthalate-co-
triphenylmethylphosphoniumsulfoisophthalate (90/10)!;
poly{1,4-cyclohexylenedimethylene-co-2,2′-oxydiethylene
(46/54)isophthalate-co-5-(4-sulfophenoxy)isophthlate (90/10)};
poly{1,4-cyclohexyloxydiethylene terephthalate-co-5-(4-
sulfophenoxy)isophthalate (70/30)}; and
poly{1,4-cyclohexylenedimethylene-co-2,2′-oxydiethylene
(46/54)isophthalate-co-4,4′-dicarboxyphenylmethylphenyl
phosphonium p-toluenesulfonate (90/10)!.