Process for an addition reaction of organic silicon compounds having SiH groups with compounds having olefinic double bonds

1. A process for preparing polyorgansiloxanes and polyorganosilanes by an addition reaction which comprises reacting

at least one siloxane and/or at least one silane, each of which contain at least one H—Si group, with at least one compound having olefinic double bonds in the presence of a platinum (0) catalyst comprising a platinum (0) -compound complexed with at least one unsaturated hydrocarbon having 2 to 6 carbon atoms dissolved in a solvent,

wherein the at least one unsaturated hydrocarbon is selected from the group consisting of ethane, propene, butenes, pentenes, hexenes and cyclohexene

wherein said platinum (0) catalyst is obtained by dissolving the platinum (0) -compound in a solvent and then adding the unsaturated hydrocarbon(s).

2. The process as claimed in claim 1 , wherein the platinum (0) -compound is a platinum (0) complex of siloxanes, silanes, organopolysiloxanes and/or organosilanes with unsaturated hydrocarbon radicals.

3. The process as claimed in claim 1 wherein the platinum (0) -compound is of the formula [H 2 C═CH—Si(CH 3 ) 2 —O—Si(CH 3 ) 2 —CH═CH 2 ] 3 Pt 2 .

4. The process as claimed in claim 1 , wherein the solvent for the platinum (0) catalyst is an aromatic hydrocarbon and the Pt (0) content of the solution is from about 0.1 to about 10% by weight.

5. The process as claimed in claim 1 , wherein the at least one unsaturated hydrocarbon is ethane, propene or butene.

6. The process as claimed in claim 1 , wherein at least one of the unsaturated hydrocarbons is added to the solution of the catalyst at temperature in the range from about 0° C. to about 30° C.

7. The process as claimed in claim 1 , wherein the amount of catalyst is from about 10 −2 to about 10 −8 mol per mole of SiH groups in the silane or siloxane.

8. The process as claimed in claim 7 , wherein the amount of catalyst is about 10 −3 to 10 −6 mol per mol of SiH groups in the silane or siloxane.

9. The process as claimed in claim 1 , wherein the hydrosilylation is carried out at temperatures in the range from about 20 to about 150° C.

10. The process as claimed in claim 1 , wherein the siloxane and/or silane is

monomeric silanes;

cyclic silanes;

linear or branched oligomeric or polymeric siloxanes; or

compounds of the general formula.

11. The process as claimed in claim 10 , wherein the siloxane and/or silane is a compound of the formula

R 3 SiH;

R 2 SiH2;

R 3 SiH3;

R 3 SiO—(R 2 SiO—) a (RSi(H)O—) b SiR 3 ; or

HR 2 SiO—(R 2 SiO—) c (RSi(H)O—) d SiR 2 H;

in which

R are identical or different and is an alkyl group having 1 to 8 carbon atoms;

a substituted alkyl group having 1 to 8 carbon atoms; an aryl group, an aralkyl group, an alkoxy group or an alkoxyalkyl group;

a is ≧0;

b is ≧1;

c is ≧0; and

d is ≧0.

12. The process according to claim 10 wherein at least one R group is selected from the group consisting of 3-chloropropyl, 1-chloromethyl, 3-cyanopropyl, phenyl, benzyl, ethyoxy and ethoxypropyl.

13. The process as claimed in claim 1 , wherein at least one compound having olefinic double bonds is a compound of the formulae

(CH 2 ═CH—CH 2 —O—(CH 2 —CH 2 O—) x —CH 2 —CH(R′)O—) y (SO) z —R″;

CH 2 ═CH—O—(CH 2 —CH 2 O—) x —CH 2 —CH(R′)O—) y —R″;

CH 2 ═CH—CH 2 —R IV ; or

CH 2 ═CH—(O) x′ —R IV ;

in which

x=0 to 100,

x′=0 or 1,

y=0 to 100,

z=0 to 100,

R′ is an optionally substituted alkyl group having 1 to 4 carbon atoms and

R″ is a hydrogen radical or an alkyl group having 1 to 4 carbon atoms; the group —C(O)—R″′ in which R″′ is alkyl radical; the group —CH 2 —O—R′; an alkylaryl group, the group —C(O)NH—R′,

R IV is an optionally substituted hydrocarbon radical having 7 to 47, carbon atoms, and

SO is the radical C 6 H 5 —CH(-)—CH 2 —O—.

14. The process as claimed in claim 10 , wherein the at least one unsaturated hydrocarbon is ethane, propene or butene,

in which

e is ≧0

f is ≧1 and

g is ≧1,

R are identical or different groups which do not hinder the addition reaction.