Granted Patent B2

US 7,204,861 · App. 10/859,479 · Granted Apr 17, 2007

Abstract

Claims (70)

1. A hair coloring composition comprising

i) at least one source of peroxymonocarbonate ions,

ii) at least one source of alkalizing agent, and

iii) at least one source of radical scavenger selected from the group consisting of:

A. selected from compounds according to the formula (I):

R 1 —Y 13 C(H)(R 3 )—R 4 —(C(H)(R 5 )—Y—R 6 ) n   (I):

wherein Y Is NR 2 , O, or S; n is 0 to 2; and wherein R 4 is monovalent or divalent and is selected from: (a) substituted or unsubstituted, straight or branched, alkyl, mono- or poly-unsaturated alkyl, heteroalkyl, aliphatic, heteroaliphatic, or heteroolefinic systems, (b) substituted or unsubstituted, mono- or poly-cyclic aliphatic, aryl, or heterocyclic systems, or (c) substituted or unsubstituted, mono-, poly-, or per-fluoro alkyl systems; the systems of (a), (b) and (C) comprising from about 1 to about 12 carbon atoms and about 0 to about 5 heteroatoms selected from the group consisting of O, S, N, P, and Si; and

wherein R 4 can be connected to R 3 or R 5 to create a 5, 6 or 7 membered ring; and

wherein R 1 , R 2 , R 3 , R 5 , and R 6 are monovalent and are selected independently from: (a), (b), (c) or H;

B. compounds according to the formula (II):

wherein R 1 , R 2 , R 3 , R 4 , R 5 are independently selected from H, COO-M+, Cl, Br, SO 3 -M+, NO 2 , OCH 3 , OH or a C 1 to C 10 primary or secondary alkyl and M is either H or alkali metal, or mixtures thereof; and

C. compounds selected from the group consisting of benzylamine, imidazole, di-tert-butylhydroxytoluene, hydroquinone, guanine, pyrazine, piperidine, morpholine, methylmorpholine, 2-methyoxyethylamine, and mixtures thereof,

wherein said composition has a pH of up to and including about 9.5.

2. A hair coloring composition according to claim 1 , wherein said source of peroxymonocarbonate ions comprises at least one source of hydrogen peroxide and at least one source of ions selected from the group consisting of carbonate ions, carbamate ions, hydrocarbonate ions and mixtures thereof.

3. A hair coloring composition according to claim 1 , wherein said source of alkalizing agent is a source of ammonium ions.

4. A hair coloring composition according to claim 1 , wherein said composition has a pH of from about 7.5 to about 9.5.

5. A hair coloring composition according to claim 2 , wherein said composition comprises

i. from about 0.1% to about 10% by weight of hydrogen peroxide

ii. from about 0.1 to about 10% by weight of said alkalizing agent

iii. from about 0.1 to about 15% by weight of said source of carbonate ions, carbamate ions, hydrogencarbonate ions, or mixtures thereof, and

iv. from about 0.1% to about 10% by weight of said radical scavenger.

6. A hair coloring composition according to claim 2 , wherein said composition comprises

i. from about 1% to about 7% by weight of hydrogen peroxide

ii. from about 0.5 to about 5% by weight of said alkalizing agent

iii. from about 1% to about 8% by weight of said source of carbonate ions, carbamate ions, hydrogencarbonate ions, or mixtures thereof

iv. from about 1% to about 7% by weight of said radical scavenger.

7. A hair coloring composition according to claim 2 , wherein said source of alkalizing agent is a source of ammonium ions, and wherein the weight ratio of said ammonium ion to said carbonate ion is from about 3:1 to about 1:10.

8. A hair coloring composition according to claim 2 , wherein the weight ratio of said radical scavenger to said carbonate ion is from about 2:1 to about 1:4.

9. A hair coloring composition according to claim 1 , wherein said radical scavenger is selected from the group consisting of alkanolamines, amino sugars, amino acids, esters of amino acids, and mixtures thereof.

10. A hair coloring composition according to claim 1 , wherein said radical scavenger is selected from the group consisting of monoethanolamine, 3-amino-1-propanol, 4-amino-1-butanol, 5-amino-1-pentanol, 1-amino-2-propanol, 1-amino-2-butanol, 1-amino-2-pentanol, 1-amino-3-pentanol, 1-amino4-pentanol, 3-amino-2-methylpropan-1-ol, 1-amino-2-methylpropan-2-ol, 3-aminopropane-1 ,2-diol, glucosamine, N-acetylglucosamine, glycine, glutamic acid, arginine, lysine, proline, glutamine, histidine, sarcosine, serine, tryptophan and potassium, sodium and ammonium salts thereof, and mixtures thereof.

11. A hair coloring composition according to claim 1 , wherein said radical scavenger is selected from glucosamine, glycine, glutamic acid, sarcosine, lysine, serine, 2-methoxyethylamine, morpholine, piperidine, ethylamine, 3-amino-1-propanol and mixtures thereof.

12. A hair coloring kit comprising

a) an individually packaged oxidizing component comprising at least one source of hydrogen peroxide

b) an individually packaged coloring component comprising:

i. at least one source of radical scavenger selected from the group consisting of:

A. selected from compounds according to the formula (I):

R 1 —Y—C(H)(R 3)—R 4 —(C(H)(R 5 )—Y—R 6 ) n   (I):

wherein Y is NR 2 , O, or S; n is 0 to 2; and wherein R 4 is monovalent or divalent and is selected from: (a) substituted or unsubstituted, straight or branched, alkyl, mono- or poly-unsaturated alkyl, heteroalkyl, aliphatic, heteroaliphatic, or heteroolefinic systems, (b) substituted or unsubstituted, mono- or poly-cyclic aliphatic, aryl, or heterocyclic systems, or (C) substituted or unsubstituted, mono-, poly., or per-fluoro alkyl systems; the systems of (a), (b) and (c) comprising from about 1 to about 12 carbon atoms and about 0 to about 5 heteroatoms selected from the group consisting of O, S, N, P, and Si; and

wherein R 4 can be connected to R 3 or R 5 to create a 5, 6 or 7 membered ring; and

wherein R 1 , R 2 , R 3 , R 5 , and R 6 are monovalent and are selected independently from: (a), (b), (c) or H;

B. compounds according to the formula (II):

wherein R 1 , R 2 , R 3 , R 4 , R 5 are independently selected from H, COO-M+, Cl, Br, SO 3 -M+, NO 2 , OCH 3 , OH or a C 1 to C 10 primary or secondary alkyl and M is either H or alkali metal, or mixtures thereof; and

C. compounds selected from the group consisting of benzylamine, imidazole, di-tert-butylhydroxytoluene, hydroquinone, guanine, pyrazine, piperidine, morpholine, methylmorpholine, 2-methyoxyethylamine and mixtures thereof,

ii. at least one source of ions selected from the group consisting of carbonate ions, carbamate ions, and hydrocarbonate ions; and

iii. at least one alkalizing agent.

13. A method of treating hair comprising the step of applying to said hair for a time period a composition comprising:

i. at least one source of peroxymonocarbonate ions;

ii. at least one alkalizing agent; and

iii. at least one source of radical scavenger selected from the group consisting of:

A. selected from compounds according to the formula (I):

R 1 —Y—C(H)(R 3 )—R 4 —(C(H)(R 5 )—Y—R 6 ) n   (I):

wherein Y is NR 2 , O, or S; n is 0 to 2; and wherein R 4 is monovalent or divalent and is selected from: (a) substituted or unsubstituted, straight or branched, alkyl, mono- or poly-unsaturated alkyl, heteroalkyl, aliphatic, heteroaliphatic, or heteroolefinic systems, (b) substituted or unsubstituted, mono- or poly-cyclic aliphatic, aryl, or heterocyclic systems, or (C) substituted or unsubstituted, mono-, poly-, or per-fluoro alkyl systems; the systems of (a), (b) and (c) comprising from about 1 to about 12 carbon atoms and about 0 to about 5 heteroatoms selected from the group consisting of O, S, N, P, and Si; and

wherein R 4 can be connected to R 3 or R 5 to create a 5, 6 or 7 membered ring; and

wherein R 1 , R 2 , R 3 , R 5 , and R 6 are monovalent and are selected independently from: (a), (b), (c) or H;

B. compounds according to the formula (II):

wherein R 1 , R 2 , R 3 , R 4 , R 5 are independently selected from H, COO-M+, Cl, Br, SO 3 -M+, NO 2 , OCH 3 , OH or a C 1 to C 10 primary or secondary alkyl and M is either H or alkali metal, or mixtures thereof; and

C. compounds selected from the group consisting of benzylamine, imidazole, di-tert-butylhydroxytoluene, hydroquinone, guanine, pyrazine, piperidine, morpholine, methylmorpholine, 2-methyoxyethylamine, and mixtures thereof,

wherein said composition has a pH of up to about 9.5 for at least about 50% of the time period said composition is applied and retained on the hair.

14. A method of treating hair comprising the steps of

(a) applying a composition comprising at least one source of radical scavenger selected from the group consisting of; and

A. selected from compounds according to the formula (I):

R 1 —Y—C(H)(R 3 )—R 4 —(C(H)(R 5 )—Y—R 6 ) n   (I):

wherein Y is NR 2 , O, or S; n is 0 to 2; and wherein R 4 is monovalent or divalent and is selected from: (a) substituted or unsubstituted, straight or branched, alkyl, mono- or poly-unsaturated alkyl, heteroalkyl, aliphatic, heteroaliphatic, or heteroolefinic systems, (b) substituted or unsubstituted, mono- or poly-cyclic aliphatic, aryl, or heterocyclic systems, or (c) substituted or unsubstituted, mono-, poly-, or per-fluoro alkyl systems; the systems of (a), (b) and (c) comprising from about 1 to about 12 carbon atoms and about 0 to about 5 heteroatoms selected from the group consisting of O, S, N, P, and Si; and

wherein R 4 can be connected to R 3 or R 5 to create a 5, 6 or 7 membered ring; and

wherein R 1 , R 2 , R 3 , R 5 , and R 6 are monovalent and are selected independently from: (a), (b), (c) or H;

B. compounds according to the formula (II):

wherein R 1 , R 2 , R 3 , R 4 , R 5 are independently selected from H, COO-M+, Cl, Br, SO 3 -M+, NO 2 , OCH 3 , OH or a C 1 to C 10 primary or secondary alkyl and M is either H or alkali metal, or mixtures thereof, and

C. compounds selected from the group consisting of benzylamine, irnidazole, di-tert-butylhydroxytoluene, hydroquinone, guanine, pyrazine, piperidine, morpholine, methylmorpholine, 2-methyoxyethylamine, and mixtures thereof,

(b) separately applying an oxidizing hair coloring composition comprising at least one source of peroxymonocarbonate ion and at least one source of alkalizing agent;

wherein said steps (a) and (b) are interchangeable.

Assignments (8)