Magnetic recording medium
View Patent ↗A magnetic recording medium comprising a non-magnetic support and a magnetic layer containing a binder and a ferromagnetic metal powder dispersed in the binder, wherein the binder contains a polyurethane resin obtained from a polyester polyol, a chain extender, and an organic diisocyanate, and the magnetic layer has a product Π of coercive force Hc (kA/m) in an in-plane, longitudinal direction and magnetic flux Øm (Tμm) in a range of from 400 to 800.
1. A magnetic recording medium comprising a non-magnetic support and a magnetic layer containing a binder and a ferromagnetic metal powder dispersed in the binder, wherein
the binder contains a polyurethane resin obtained from a polyester polyol, a chain extender, and an organic diisocyanate, and
the magnetic layer has a product Π of coercive force Hc (kA/m) in an in-plane, longitudinal direction and magnetic flux Øm (Tμm) in a range of from 400 to 800.
2. The magnetic recording medium according to claim 1 , wherein the polyurethane is (1) one in which the polyester polyol component contains an aliphatic dibasic acid component and 70 mol % or more, based on a total diol component content, of an alkyl-branched diol component having no cyclic structure and having an alkyl branch containing more than one carbon atoms or (2) one in which the polyester polyol component contains an aliphatic dibasic acid component, 70 mol % or more, based on a total diol component content, of an aliphatic alkyl-branched diol component having at least one alkyl branch containing more than one carbon atoms in total per molecule, and, as a chain extender, an aliphatic alkyl-branched diol having at least one alkyl branch containing more than two carbon atoms in total per molecule.
3. The magnetic recording medium according to claim 1 , wherein the ferromagnetic metal powder has a BET specific surface area of 50 to 90 m 2 /g and a saturation magnetization of 90 to 130 A·m 2 /kg.
4. The magnetic recording medium according to claim 1 , wherein the product Π is from 480 to 720.
5. The magnetic recording medium according to claim 1 , wherein the product Π is from 480 to 640.
6. The magnetic recording medium according to claim 1 , wherein the ferromagnetic metal powder has a BET specific surface area of 60 to 80 m 2 /g.
7. The magnetic recording medium according to claim 1 , wherein the ferromagnetic metal powder has a saturation magnetization of 100 to 120 A·m 2 /kg.
8. The magnetic recording medium according to claim 1 , wherein the ferromagnetic metal powder has a saturation magnetization of 100 to 110 A·m 2 /kg.
9. The magnetic recording medium according to claim 1 , wherein the polyurethane has a weight average molecular weight of 30,000 to 70,000.
10. The magnetic recording medium according to claim 1 , wherein the polyurethane has a weight average molecular weight of 40,000 to 60,000.
11. The magnetic recording medium according to claim 1 , wherein the polyurethane has a glass transition temperature of 500 to 150° C.
12. The magnetic recording medium according to claim 1 , wherein the polyurethane has a glass transition temperature of 700 to 120° C.
13. The magnetic recording medium according to claim 1 , wherein the polyurethane has a glass transition temperature of 80° to 100° C.
14. The magnetic recording medium according to claim 1 , wherein the polyurethane has a polar group.
15. The magnetic recording medium according to claim 14 , wherein the polar group is selected from —SO 3 M, —OSO 3 M, —COOM, —P═O(OM) 2 , —O—P═O(OM) 2 , —NR 2 , —N + R 2 R′COO − , wherein M represents a hydrogen atom, an alkali metal atom or an ammonium group; and R and R′ each independently represent an alkyl group having 1 to 12 carbon atoms.