Composition and methods for injection of sealants into air conditioning and refrigeration systems

1. A method for injecting sealant into an air conditioning or refrigeration system having a compressor, a high pressure side (“high side”), and a low pressure side (“low-side”), the method comprising the step of:

injecting the sealant in a quantity to provide sufficient lubrication to maintain proper operation of the compressor when the sealant is fully distributed in the system, while

injecting the sealant so as to maintain proper operation of the compressor before the sealant is fully distributed in the system,

wherein injecting the sealant so as to maintain proper operation of the compressor before the sealant is fully distributed comprises injecting the sealant at the high side of the system and distributing the sealant starting at the high side, wherein the injected sealant is injected at a rate of less than 6% per minute of lubricant within the system.

2. The method of claim 1 wherein the air conditioning or refrigeration system is a hermetically sealed air conditioning or refrigeration system.

3. A method for injecting sealant into an air conditioning or refrigeration system having a compressor, a high pressure side (“high side”), and a low pressure side (“lowside”), the method comprising the step of:

injecting the sealant in a quantity to provide sufficient lubrication to maintain proper operation of the compressor when the sealant is fully distributed in the system, while

injecting the sealant so as to maintain proper operation of the compressor before the sealant is fully distributed in the system,

wherein the sealant is injected into a non-operating system under vacuum, and other system contents, including refrigerant, are later injected into the system causing distribution of the previously injected sealant, wherein substantially 60% of total system refrigerant injected after the sealant.

4. A method for injecting sealant into an air conditioning or refrigeration system having a compressor, a high pressure side (“high side”), and a low pressure side (“lowside”), the method comprising the step of:

injecting the sealant in a quantity to provide sufficient lubrication to maintain proper operation of the compressor when the sealant is fuuly distributed in the system, while

injecting the sealant so as to maintain proper operation of the compressor before the sealant is fully distributed in the system,

wherein the sealant is part of a fluid mictuer further comprising a lubricant, and

wherein the lubricant is an oil, the compressor has a sump containing oil, and the minimum viscosity of the injected fluid mixture is η inj as determined by:

exp( x inj .ln η inj +x sump .ln η sump +C )≧ Fr .η sump

where,

ln is the natural logarithm and exp is the exponential,

x inj , is mole fraction of injected material in final sump mixture,

x sump is mole fraction of original sump oil in final sump mixture,

η inj , η sump are viscosities of the injected material and original sump oil respectively,

C is a constant dependent on the nature of the injected material and the sump oil, and

Fr is a desired fraction of original sump oil viscosity to be maintained.

5. The method of claim 4 wherein Fr=0.9.

6. The method of claim 4 wherein the air conditioning or refrigeration system is a hermetically sealed air conditioning or refrigeration system.

7. A method of introducing sealant into an air conditioning or refrigeration system having a compressor and evaporator, the method comprising the steps of:

a) connecting a vessel containing a sealant mixture comprising an organosilane between the compressor and the evaporator, and

b) while the system is running, allowing the sealant mixture to enter the system at a rate to prevent liquid slugging and to maintain sufficient concentrations of lubricant for proper operation of the compressor during the injection process,

allowing the sealant to enter the system in an amount to maintain sufficient compressor lubricant viscosity for continued proper operation of the compressor, and

allowing the sealant to enter in an amount that will allow continued proper operation of the air conditioning or refrigeration system,

wherein allowing the sealant mixture to enter the system comprises pressurizing the sealant mixture sufficiently above system low side operating pressure to cause the sealant mixture to enter the system from the vessel when the system is running,

wherein pressurizing the sealnt mixture comprises using the system pressure of the system in a non-running stste to pressurize the sealant mixture in the vessel,

wherein the method further comprises a step of allowing the sealant mixture to cool to near ambient temperature after the vessel is pressurized and while the vessel is fluidly connected to the system in the non-running state, and

wherein the method further comprises the step of fluidly disconnecting the pressurized vessel from the system after cooling, running the system until low side prssure drops, and fluidly connecting the vessel to the low side of the system and allowing the sealant to enter the system as provided in step b).

8. The method of claim 7 wherein the air conditioning or refrigeration system is a hermetically sealed air conditioning or refrigeration system.

9. A method of introducing sealant into an air conditioning or refrigeration system having a compressor and an evaporator, the method comprising the steps of:

c) turning off the system;

d) allowing system pressure to equalize;

e) connecting a vessel containing a sealant mixture comprising an organosilane between the compressor and the evaporator, and

f) while the system is running, allowing the sealant mixture to enter the system at a rate to prevent liquid slugging and to maintain sufficient concentrations of lubricant for proper operation of the compressor

wherein, the organosilane is a monomer capable of forming a solid polymer with itself or other chosen organosilanes in the presence of moisture, and is stable in the absence of moisture in the system, and does not substantially interfere with the normal operation of contents of the system in selected quantities, and

the method further comprising the steps of:

e) turning off the system when a selected amount of sealant mixture has entered the system for a period of time to allow system pressure to equalize, and

f) repeating step d)

g) repeating steps e) and f) until a total selected amount of sealant has entered the system.

10. A method for injecting sealant into an air conditioning or refrigeration system having a compressor, a high pressure side (“high side”), and a low pressure side (“low-side”), the method comprising the step of:

injecting the sealant in a quantity to provide sufficient lubrication to maintain proper operation of the compressor when the sealant is fully distributed in the system, while

injecting the sealant so as to maintain proper operation of the compressor before the sealant is fully distributed in the system,

wherein the sealnt is injected into a non-operating system under vacuum, and other system contents, including refrigerant, are later injected into the system causing distribution of the previously injected sealant, wherein approximately 60% of total system refrigerant injected after the sealant, and

wherein the method further comprises equalizing the system after injecting the approximately 60% of the refrigerant then turning on the system and adding remaining refrigerant.

11. A method of introducing sealant into an air conditioning or refrigeration system having a compressor and an evaporator, the method comprising the steps of:

a) turing off the system;

b) allowing system pressure to equalize;

c) connecting a vessel containing a sealant mixture comprising an organosilane between the compressor and the evaporator, and

d) while the system is running, allowing the sealant mixture to enter the system at a rate to prevent liquid slugging and to maintain sufficient concentrations of lubricant for proper operation of the compressor

wherein, the organosilane is a monomer capable of forming a solid polymer with itself or other chosen organosilanes in the presence of moisture, and is stable in the absence of moisture in the system, and does not substantially interfere with the normal operation of contents of the system in selected quantities, and

wherein the compressor has a sump containing oil and the minimum viscosity for a particular lubricant/sealant mixture is η inj as determined by:

exp( x inj .ln η inj +x sump .ln η sump +C )≧ Fr .η sump

where,

ln is the natural logarithm and exp is the exponential,

x inj , is mole fraction of injected material in final sump mixture,

x sump is mole fraction of original sump oil in final sump mixture,

η inj , η sump are viscosities of the injected mixture and original sump oil respectively,

C is a constant dependent on the nature of the injected material and the sump oil, and

Fr is a desired fraction of original sump oil viscosity to be maintained.

12. The method of claim 11 wherein Fr=0.9.

13. The method of claim 11 wherein if the calculated viscosity is below 7 cst., then the minimum viscosity is 7 cst.

14. The method of claim 11 wherein the air conditioning or refrigeration system is a hermetically sealed air conditioning or refrigeration system.

15. A method of introducing sealant into an air conditioning or refrigeration system having a compressor and an evaporator, the method comprising the steps of:

a) turning off the system;

b) allowing system pressure to equalize;

c) connecting a vessel containing a sealant mixture comprising an organosilane between the compressor and the evaporator, and

d) while the system is running, allowing the sealant mixture to ente the system at a rate to prevent liquid slugging and to maintain sufficient concentration of lubricant for proper operation of the compressor

wherein, the organosilane is a monomer capable of forming a solid polymer with itself or other chosen organosilanes in the presence of moisture, and is stable in the absence of moisture in the system, and does not substantially interfere with the normal operation of contents of the system in selected quantities,

wherein the sealant mixture has a viscosity above 7 cst. when measured at 40° C., and

wherein the step of allowing the sealant to enter the system further oomprises allowing the sealant to enter through an orifioe having an opening within a range of from 0.0200.06 inohes diameter.

16. The method of claim 15 wherein the air conditioning or refrigeration system is a hermetically sealed air conditioning or refrigeration system.

17. A method of introducing sealant into an air conditioning or refrigeration system having a compressor and an evaporator, the method comprising the steps of:

a) turing off the system;

b) allowing system pressure to equalize;

c) connecting a vessel containing a sealant mixture comprising an organosilane between the compressor and the evaporator, and

d) while the system is running, allowing the sealant mixture to enter the system at a rate to prevent liquid slugging and to maintain sufficient concentrations of lubricant for proper operation of the compressor

wherein, the organosilane is a monomer capable of forming a solid polymer with itself or other chosen organosilanes in the presence of moisture, and is stable in the absence of moisture in the system, and does not substantially interfere with the normal operation of contents of the system in selected quantities, and

wherein, the step of connecting the vessel further comprises providing fluid connection between the vessel and the system, and the method further comprises allowing sufficient time for the sealant mixture to achieve ambient temperature before running the system after fluid connection, wherein the step of connecting the vessel to the system coomprises coonnecting a hose assembly between the vessel and a low pressure side service port of the system, and

wherein the hose assembly further comprises a first fitting for connection to the vessel and a second fitting for connection to the port.

18. The method of claim 17 , wherein the step of providing fluid connection between the vessel and the system, and the step of allowing sealant mixture to enter the system, comprise opening a valve in the second fitting.

19. The method of claim 18 , wherein the vessel is a sealed canister, and wherein the step of providing a fluid connection between the canister and the system further comprises tapping the canister before opening the valve in the second fitting.

20. The method of claim 19 , wherein the second fitting is a cantapper.

21. The method of claim 17 wherein the air conditioning or refrigeration system is a hermetically sealed air conditioning or refrigeration system.

22. A device for introducing sealant into a hermetically sealed air conditioning or refrigeration system, the device comprising:

a sealed vessel, and

b. in the sealed vessel, an organosilane mixture of an organosilane and a miscible material, the mixture having a viscosity above 7 cst. when measured at 40° C.,

wherein the organosilane is a monomer or oligomer capable of forming a solid polymer with itself or other chosen organosilanes in the presence of moisture, and is stable in the absence of moisture in the system, and does not substantially interfere with the normal operation of contents of the system in selected quantities, and

the device further comprising: a hose assembly having a first fitting for sealed fluid connection to a low side port of the system, and having a sealed fluid connection to the sealed vessel, and a metering device for controlling fluid flow from the sealed vessel through the hose assembly,

wherein the fluid connection to the sealed vessel is a second fitting,

wherein the second fitting comprises a manually operable valve for providing fluid connection between the hose assembly and the sealed vessel,

wherein the second ditting further comprises a can-tapper for opening the sealed vessel, and

wherein a filter is placed between the fitting connecting to the system and the metering device.

23. The device of claim 22 wherein the metering device is an orifice having an opening with a maximum diameter of 0.06 inches.