Ormocer composites for golf ball components
View Patent ↗A golf ball comprising a core; a cover layer; and a barrier layer disposed between the core and the cover layer, the barrier layer being formed from a composition comprising an organically-modified ceramic material (also referred to as ormocers, ceramers, ormosils, and hybrids) which is a composite comprising organic and inorganic nano-building blocks linked most often via stable covalent bonds based on organically modified silicon oxides and/or functionalized organic oligomers/polymers.
1. A golf ball comprising:
a core;
a cover layer; and
a barrier layer disposed between the core and the cover layer, the barrier layer being formed from a composition comprising an organically-modified ceramic material formed from a multi-functional alkoxysilane comprising urethane (meth)acrylate and thio (methacrylate) groups;
wherein the barrier layer has a water vapor transmission rate of about 0.95 grams·mm/m 2 ·day or less.
2. The golf ball of claim 1 , wherein the multi-functional urethane- and thioether(meth)acrylate alkoxysilanes are present in an amount sufficient to form an Si—O—Si network by a hydrolysis or a poly-condensation reaction.
3. The golf ball of claim 1 , wherein the organically-modified ceramic materials have a surface area of 4 m 2 /g to about 600 m 2 /g.
4. The golf ball of claim 3 , wherein the surface area is about 10 m 2 /g to about 50 m 2 /g.
5. The golf ball of claim 1 , wherein the organically-modified ceramic materials have a mean particle size of about 10 nm to about 300 nm.
6. The golf ball of claim 1 , wherein the composition further comprises polyolefinic ionomers.
7. The golf ball of claim 1 , wherein the barrier layer has a water vapor transmission rate of about 0.45 grams·mm/m 2 ·day or less.
8. The golf ball of claim 1 , wherein the core comprises a center and an outer core layer, at least one of the center or outer core layer comprising a halogenated organosulfur compound.
9. The golf ball of claim 8 , wherein at least one of the center or the core layer comprises the organically-modified ceramic material.
10. The golf ball of claim 1 , wherein the cover comprises an inner cover layer and an outer cover layer.
11. The golf ball of claim 10 , wherein at least one of the inner or outer cover layers comprises organically-modified ceramic materials.
12. The golf ball of claim 10 , wherein at least one of the inner or outer cover layer has a thickness of about 0.05 inches or less.
13. The golf ball of claim 1 , wherein the core has an outer diameter about 1.55 inches or greater.
14. The golf ball of claim 13 , wherein the core has an outer diameter of between about 1.57 inches and about 1.62 inches.
15. The golf ball of claim 1 , wherein the barrier layer or the cover further comprises thick or thin films, fillers, fibers, flakes, particulates, windings, adhesives, coupling agents, compatibilizers, composites, short or long fibrous reinforcements, and inks formed of the hybrid material.
16. The golf ball of claim 1 , wherein the cover layer comprises polyurethane, polyurea, polyurethane-urea, or polyurea-urethane.
17. The golf ball of claim 1 , wherein the cover is formed of a castable reactive liquid material.
18. A golf ball comprising:
a core;
a layer disposed about the core, the layer being formed from a composition comprising an organically-modified ceramic material wherein the organically-modified ceramic materials are formed by the hydrolytic condensation of one or more silicon compounds, and the subsequent polymerization of organic monomers, wherein at least one silicon compound comprises vinyl ether radicals of the formula:
where R represents hydrogen, methyl, or ethyl;
and wherein the layer has a water vapor transmission rate of about 0.95 grams·mm/m 2 ·day or less.
19. The golf ball of claim 18 , wherein the organically-modified ceramic materials are applied by brushing, spraying, rolling, centrifugal, or doctor processes and subsequently cured by at least one of heat, photochemical induction, and thermal induction.
20. A golf ball comprising:
a core;
a cover layer; and
a barrier layer being formed from a composition comprising an organically-modified ceramic material, the barrier layer having a water vapor transmission rate of about 0.45 grams·mm/m 2 ·day or less.
21. The golf ball of claim 20 , wherein the core comprises a halogenated organosulfur compound.
22. The golf ball of claim 20 , wherein the organically-modified ceramic barrier layer comprises inorganic particles having a maximum outer diameter of about 75 μm or less.
23. The golf ball of claim 22 , wherein the organically-modified ceramic barrier layer comprising inorganic particles having a maximum outer diameter of about 5 μm or less.
24. The golf ball of claim 20 , wherein the organically-modified ceramic barrier layer has a film thickness of about 0.005 μm to about 30 μm.
25. The golf ball of claim 24 , wherein the organically-modified ceramic barrier layer has a film thickness of about 1 μm to about 5 μm.