Catalyst regeneration process
Used noble metal-containing titanium or vanadium zeolite catalysts, that have been employed in the epoxidation of olefins with hydrogen and oxygen, are regenerated by contacting the spent catalyst with water or an alcohol/water mixture at a temperature of 25° C. to 200° C.
1 . A method of regenerating a used noble metal-containing titanium or vanadium zeolite catalyst that has been used to catalyze the epoxidation of an olefin with hydrogen and oxygen, said method comprising contacting the used catalyst with water or a mixture of an alcohol and water at a temperature of 25° C. to 200° C. to reactivate the used catalyst.
2 . The method of claim 1 wherein the used catalyst comprises titanium silicalite and palladium.
3 . The method of claim 1 wherein the used catalyst comprises titanium silicalite, palladium, and one or more metals selected from the group consisting of gold and platinum.
4 . The method of claim 1 wherein the used catalyst comprises palladium-containing titanium or vanadium zeolite and palladium-free titanium or vanadium zeolite.
5 . The method of claim 1 wherein the alcohol is selected from the group consisting of C 1 -C 10 aliphatic alcohols and C 7 -C 12 aralkyl alcohols.
6 . The method of claim 1 wherein the alcohol is selected from the group consisting of methanol, ethanol, n-propyl alcohol, isopropyl alcohol, n-butanol, sec-butanol, iso-butanol, and t-butyl alcohol.
7 . The method of claim 1 wherein the alcohol is methanol.
8 . The method of claim 1 wherein the temperature is from 50° C. to 120° C.
9 . The method of claim 1 wherein the alcohol:water volume ratio is from 0.5 to 5.
10 . The method of claim 1 wherein the contacting is performed for 0.5 hours to 12 hours.
11 . The process of claim 1 wherein the olefin is a C 2 -C 6 olefin.
12 . The process of claim 1 wherein the olefin is propylene.
13 . A method of regenerating a used palladium-containing titanium silicalite catalyst which has been used to catalyze the epoxidation of propylene with hydrogen and oxygen, said method comprising contacting the used catalyst with a mixture of a C 1 -C 4 aliphatic alcohol and water at a temperature of 50° C. to 120° C. to reactivate the used catalyst.
14 . The method of claim 13 wherein the used catalyst comprises titanium silicalite, palladium, and one or more metals selected from the group consisting of gold and platinum.
15 . The method of claim 13 wherein the used catalyst comprises palladium-containing titanium silicalite and palladium-free titanium silicalite.
16 . The method of claim 13 wherein the alcohol is methanol.
17 . The method of claim 13 wherein the alcohol:water volume ratio is from about 0.5 to about 5.