High melt flow fluoropolymer
View Patent ↗The present invention relates to a partially-crystalline copolymer comprising tetrafluoroethylene, hexafluoropropylene in an amount corresponding to a hexafluoropropylene index (HFPI) of from about 2.8 to 5.3, and preferably from about 0.2% to 3% by weight of perfluoro(alkyl vinyl ether), said copolymer being polymerized and isolated in the absence of added alkali metal salts, having a melt flow rate of within the range of about 30±3 g/10 min, and having no more than about 50 unstable endgroups/10 6 carbon atoms can be extruded at high speed onto conductor over a broad polymer melt temperature range to give insulated wire of high quality.
1. A partially-crystalline copolymer comprising tetrafluoroethylene, hexafluoropropylene in an amount corresponding to a hexafluoropropylene index (HFPI) of from about 2.8 to 5.3, said copolymer being polymerized and isolated in the absence of added alkali metal salt, having a melt flow rate of within the range of about 30±3 g/10 min, and having no more than about 50 unstable endgroups/10 6 carbon atoms.
2. The copolymer of claim 1 having a melt flow rate within the range of about 30±2 g/10 min.
3. The copolymer of claim 1 further comprising from about 0.2% to 3% by weight of perfluoro(alkyl vinyl ether).
4. The copolymer of claim 3 wherein said perfluoro(alkyl vinyl ether) is perfluoro(propyl vinyl ether).
5. The copolymer of claim 3 wherein said perfluoro(alkyl vinyl ether) is perfluoro(ethyl vinyl ether).
6. The copolymer of claim 1 having no more than about 20 unstable endgroups/10 6 carbon atoms.
7. The copolymer of claim 1 wherein said alkali metal salt is a potassium salt.