Process for working up secondary components in the preparation of dinitrotoluene
View Patent ↗The present invention relates to a process for working up organic secondary components which are formed in the one-stage or two-stage nitration of toluene to dinitrotoluene. These organic secondary components are present in the acidic and alkaline waste water from the dinitrotoluene washing step and in the aqueous distillate from the sulfuric acid concentration step, together with small amounts of mononitrotoluene and dinitrotoluene. This process comprises a) combining the acidic and alkaline waste waters from the washing step and the aqueous distillate from the sulfuric acid concentration step such that the resulting mixture has a pH below 5, b) separating the aqueous and organic phases which form by phase separation, and c) recycling the organic phase from step b) into the nitration process.
1. A process for removing organic secondary components which are formed during the nitration of toluene to dinitrotoluene, and which are present in the acidic and alkaline waste water from the dinitrotoluene washing step and in the aqueous distillate from the sulfuric acid concentration step, together with small amounts of mononitrotoluene and dinitrotoluene, comprising:
a) combining (1) the acidic and alkaline waste waters resulting from the washing step of the nitration process, and (2) the aqueous distillate from the sulfuric acid concentration step such that the resultant mixture has pH below 5,
b) separating the resultant aqueous and organic phases by phase separation, and
c) recycling the organic phase from step b) into the nitration process.
2. The process of claim 1 , wherein a) combining of the aqueous waste waters is in a static mixer with a downstream venting facility.
3. The process of claim 1 , additionally comprising mixing the combined aqueous phases with mononitrotoluene.
4. The process of claim 1 , wherein the organic secondary components additionally comprise nitrocresols.
5. The process of claim 1 , wherein the organic secondary components additionally comprise picric acid.
6. The process of claim 1 , wherein the organic secondary components additionally comprise nitrobenzoic acids.
7. The process of claim 1 , wherein the nitration of toluene to dinitrotoluene is selected from the group consisting of a one-stage nitration process and a two-stage nitration process.