Miscible polyimide blends
View Patent ↗Compositions made from a polyarylate or polyester carbonate containing greater than about 50 mole % resorcinol based ester linkages give miscible blends with polyimide resins. The blends of polyimides and resorcinol based polyesters or resorcinol based polyester carbonates also give miscible blends when combined with other aryl alky polyester resins.
1. A composition comprising a miscible polymer blend of one or more polyimide resins and a second resin selected from the group consisting of resorcinol based polyester carbonates, resorcinol based polyarylates and mixtures thereof, wherein the second resin has at least 50 mole % aryl ester linkages derived from resorcinol, based on the total mole % of linkages in the second resin.
2. The composition of claim 1 wherein the polyimide resin is selected from the group consisting of; polyetherimides, polyetherimide sulfones and mixtures thereof.
3. The composition of claim 1 wherein the polyimide is made from
(a) aryl dianhydrides selected from the group consisting of: bisphenol A dianhydride, oxydiphthalic anhydride, pyromellitic dianhydride, diphthalic anhydride, sulfonyl dianhydride, benzophenone dianhydride and mixtures thereof and,
(b) aryl diamines selected from the group consisting of meta phenylene diamine, para phenylene diamine, diamino diphenyl sulfone, oxydianiline, bis amino phenoxy benzene, bis aminophenoxy biphenyl, bis aminophenyl phenyl sulfone, diamino diphenyl sulfide and mixtures thereof.
4. The composition of claim 1 further comprising a phosphorus containing stabilizer.
5. The composition of claim 4 further comprising a stabilizer selected from the group consisting of phosphites, phosphonites and mixtures thereof.
6. The composition of claim 1 wherein the miscible polymer blend has a percent transmittance, as measured by ASTM D1003, of greater than or equal to 50%.
7. The composition of claim 1 wherein the miscible polymer blend has a glass transition temperature, as measured by ASTM D3418, of greater than or equal to 150° C.
8. The composition of claim 1 wherein the miscible polymer blend has an Izod, impact, as measured by ASTM D256, of greater than or equal to 100 J/m.
9. The composition of claim 1 further comprising one or more alky aryl polyester resins.
10. The composition of claim 9 wherein the aryl alky polyester resin is chosen from the group consisting of; polyethylene terephthalate, polybutylene terephthalate, polypropylene terephthalate, polyethylene naphthanoate, polybutylene naphthanoate, polypropylene naphthanoate, polycyclohexanedimethanol terephthalate and mixtures thereof.
11. A composition comprising a miscible polymer blend of:
a) 1-99% of a polyetherimide,
b) 99-1% of an aryl polyester resin containing at least 50 mole % resorcinol linkages based on the total mole % of linkages in the aryl polyester resin,
c) 0-30% of an aryl alkyl polyester
d) 0-2% of a phosphorus containing stabilizer.
12. A composition of claim 11 comprising a miscible polymer blend of;
a) 50-99% by weight of one or more polyetherimide resins,
b) 1-50% by weight of one or more aryl polyester carbonate resin containing at least 50 mole % resorcinol linkages based on the total mole % of linkages in the aryl polyester resin,
c) 0-30% by weight of one or more aryl alkyl polyester resins,
d) 2-2% by weight of one or more phosphorus containing stabilizers.
13. The composition of claim 1 wherein the resorcinol based polyarylate has the structure shown below:
wherein R is at least one of C 1-12 alkyl, C 6 -C 24 aryl, alkyl aryl or halogen, n is 0-3 and m is at least about 8.
14. The composition of claim 1 wherein the resorcinol based polyester carbonate resin is a copolymer containing carbonate linkages having the structure shown below:
wherein R is at least one of C 1-12 alkyl, C 6 -C 24 aryl, alkyl aryl or halogen, n is 0-3, R 5 is at least one divalent organic radical, m is about 4-150 and p is about 2-200.
15. The composition of claim 14 wherein R 5 is derived from a bisphenol compound.
16. The composition of claim 1 further comprising an ester based mold release agent.
17. The composition of claim 16 wherein the ester based mold release agent has a molecular weight of greater than or equal to 200.
18. The composition of claim 1 further comprising a flame retardant agent selected form the group consisting of: bromine or chlorine containing compounds, sulfonate salts, organo-phosphates, fluorinated polymers or mixtures thereof.
19. An article made from the composition of claim 1 .
20. An article of claim 19 which is transparent with a % transmittance, as measured by ASTM D1003, of greater than or equal to 50%.
21. The composition of claim 1 , wherein the one or more polyimide resins and second resin each have a weight averaged molecular weight (Mw) of at least 10,000.