Biodegradable absorbent material
View Patent ↗An absorbent composition having a biodegradable absorbent polymer and a hydrophilic soft polymer surface modifying agent. The absorbent composition exhibits improved absorbency under load and gel bed permeability when subjected to an Absorbency Under Load Test and a Gel Bed Permeability Test, respectively. The absorbent composition can be made by combining a biodegradable absorbent polymer with an aqueous solution of a hydrophilic soft polymer and then drying the biodegradable absorbent polymer.
1. An absorbent composition comprising a biodegradable absorbent polymer and a surface modifying agent comprising a self-crosslinking hydrophilic soft polymer, wherein said biodegradable absorbent polymer is a superabsorbent material, wherein said hydrophilic soft polymer is a cationic polymer, and wherein said hydrophilic soft polymer comprises an alkoxysilane functionality.
2. The absorbent composition of claim 1 wherein said biodegradable absorbent polymer is selected from the group consisting of polysaccharide and poly amino acids.
3. The absorbent composition of claim 1 wherein said superabsorbent material is selected from the group consisting of polycarboxy polysaccharide and carboxymethyl cellulose.
4. The absorbent composition of claim 1 wherein said cationic polymer comprises functional groups selected from the group consisting of primary, secondary, and tertiary amine, imine, quaternary ammonium, and combinations thereof.
5. The absorbent composition of claim 1 wherein said cationic polymer is selected from the group consisting of salts of polyvinyl amine, polydiallyl dimethyl ammonium acryloyloxyethyl-trialkyl-substituted ammonium, acryloyloxypropyl-trialkyl-substituted ammonium, acrylamidoethyl-trialkyl-substituted ammonium, acrylamidopropyl-trialkyl-substituted ammonium and copolymers and mixtures thereof.
6. The absorbent composition of claim 1 wherein said cationic polymer includes about 0.1 to about 20-percent by mass ester units which include said alkoxysilane functionality.
7. The absorbent composition of claim 6 wherein said ester units are selected from the group consisting of acrylate ester, methacrylate ester, and combinations thereof.
8. The absorbent composition of claim 6 wherein said alkoxysilane functionality forms a silanol group upon exposure to water.
9. The absorbent composition of claim 8 wherein said silanol group condenses to form a crosslinked polymer upon exposure to water.
10. The absorbent composition of claim 1 having an AUL under 0.3 psi load value of 20 g/g or greater and a GBP under 0 psi swell pressure value of about 300×10 −9 cm 2 or greater.
11. The absorbent composition of claim 1 having an AUL under 0.3 psi load value of 20 g/g or greater and a GBP under 0.3 psi swell pressure value of about 20×10 −9 cm 2 or greater.
12. The absorbent composition of claim 11 further having a GBP under 0 psi swell pressure value of about 100×10 −9 cm 2 or greater.
13. The absorbent composition of claim 1 comprising said hydrophilic soft polymer in the amount of about 5-percent to about 15-percent by weight of said superabsorbent material.
14. An absorbent core comprising the absorbent composition of claim 1 .
15. An absorbent article comprising the absorbent composition of claim 1 .