Toner supply roller
View Patent ↗A toner supply roller comprises a metallic core shaft and an electrically conductive elastic layer formed to surround the outer surface of the shaft. The conductive elastic layer is formed of open-cell polyurethane foam. The polyurethane foam is impregnated with an electrically conductive polymer and a binder.
1. A method of manufacturing a toner supply roller, comprising impregnating a rectangular block of polyurethane foam with an impregnating solution containing an electrically conductive polymer and a binder so as to permit the conductive polymer and the binder to be attached to cell walls of the polyurethane foam, followed by drying the impregnated polyurethane foam; inserting a core shaft into the block of dried polyurethane foam; and polishing the outer surface of the block of polyurethane foam so as to form a cylindrical circumferential surface to which the polyurethane constituting the polyurethane foam is exposed.
2. The method according to claim 1 , wherein the conductive polymer is selected from the group consisting of a polyaniline polymer, a polyaniline sulfonic acid polymer, a polypyrrol, a polyacetylene and a mixture thereof.
3. The method according to claim 1 , wherein the binder is selected from the group consisting of an acrylic resin, a polyacrylic acid ester resin, an acrylic acid-styrene copolymer resin, an acrylic acid-vinyl acetate copolymer resin, a polyvinyl alcohol, a polyacrylamide, a polyvinyl chloride resin, a urethane resin, a vinyl acetate resin, a butadiene resin, an epoxy resin, an alkyd resin, a melamine resin, a chloroprene rubber and a mixture thereof.
4. The method according to claim 1 , wherein the conductive polymer and the binder are attached to the cell walls of the polyurethane foam in a total amount of 5 to 18% by weight based on the amount of the polyurethane foam.
5. The method according to claim 4 , wherein the weight ratio of the binder to the conductive polymer falls within a range of 0.1 to 10.
6. A method of manufacturing a toner supply roller, comprising impregnating a block of polyurethane foam with an impregnating solution containing an electrically conductive polymer and a binder so as to permit the conductive polymer and the binder to be attached to cell walls of the polyurethane foam, followed by drying the impregnated polyurethane foam; inserting a core shaft into the block of dried polyurethane foam; and polishing the outer surface of the block of polyurethane foam so as to form a circumferential surface, wherein the electrically conductive polymer is selected from the group consisting of a polyaniline polymer, a polyaniline sulfonic acid polymer, a polypyrrol, a polyacetylene and a mixture thereof.
7. The method according to claim 6 , wherein the binder is selected from the group consisting of an acrylic resin, a polyacrylic acid ester resin, an acrylic acid-styrene copolymer resin, an acrylic acid-vinyl acetate copolymer resin, a polyvinyl alcohol, a polyacrylamide, a polyvinyl chloride resin, a urethane resin, a vinyl acetate resin, a butadiene resin, an epoxy resin, an alkyd resin, a melamine resin, a chloroprene rubber and a mixture thereof.
8. The method according to claim 6 , wherein the conductive polymer and the binder are attached to the cell walls of the polyurethane foam in a total amount of 5 to 18% by weight based on the amount of the polyurethane foam.
9. The method according to claim 8 , wherein the weight ratio of the binder to the conductive polymer falls within a range of 0.1 to 10.
10. The method according to claim 6 , wherein the polyurethane constituting the polyurethane foam is exposed to the circumferential surface.
11. The method according to claim 10 , wherein the binder is selected from the group consisting of an acrylic resin, a polyacrylic acid ester resin, an acrylic acid-styrene copolymer resin, an acrylic acid-vinyl acetate copolymer resin, a polyvinyl alcohol, a polyacrylamide, a polyvinyl chloride resin, a urethane resin, a vinyl acetate resin, a butadiene resin, an epoxy resin, an alkyd resin, a melamine resin, a chloroprene rubber and a mixture thereof.
12. The method according to claim 11 , wherein the conductive polymer and the binder are attached to the cell walls of the polyurethane foam in a total amount of 5 to 18% by weight based on the amount of the polyurethane foam.
13. The method according to claim 12 , wherein the weight ratio of the binder to the conductive polymer falls within a range of 0.1 to 10.